Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Hexadecylcyclohexane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-460.5 ± 3.7kJ/molCcbProsen, Johnson, et al., 1946 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltacliquid-14485.3 ± 3.5kJ/molCcbProsen, Johnson, et al., 1946Corresponding «DELTA»fliquid = -460.24 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus306.9KN/AMatsumoto, 1951Uncertainty assigned by TRC = 2. K; TRC
Tfus308.8KN/ALarsen, Thorpe, et al., 1942Uncertainty assigned by TRC = 1. K; TRC
Tfus305.2KN/APetrov and Chel'tsova, 1942Uncertainty assigned by TRC = 2. K; freezing point; TRC
Tfus304.15KN/APetrov and Chel'tsova, 1942Uncertainty assigned by TRC = 2. K; melting point; TRC
Tfus305.7KN/ASchmidt, 1942Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Deltavap109.3kJ/molN/AReid, 1972AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
79.6522.Dykyj, Svoboda, et al., 1999Based on data from 507. - 689. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101210.2272.Kusmierz, Malinski, et al., 1985Column length: 22. m; Column diameter: 0.3 mm
CapillaryApiezon L190.2285.7Kusmierz, Malinski, et al., 1985He; Column length: 20. m; Column diameter: 0.3 mm
CapillarySE-52210.2280.1Kusmierz, Malinski, et al., 1985He; Column length: 40. m; Column diameter: 0.3 mm

Kovats' RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-5MS2279.Kenig, Simons, et al., 200530. m/0.25 mm/0.25 «mu»m, He; Program: 60C(1.5min) => 20C/min => 130C => 4C/min => 315C (90min)

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M170.2304.2Kusmierz, Malinski, et al., 1985He; Column length: 30. m; Column diameter: 0.25 mm

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D., Heats of formation and combustion of the normal alkylcyclopentanes and cyclohexanes and the increment per CH2 group for several homologous series of hydrocarbons, J. Res. NBS, 1946, 37, 51-56. [all data]

Matsumoto, 1951
Matsumoto, T., Dehydrogenation of Acetylcyclohexane with Selenium, Nippon Kagaku Zasshi, 1951, 72, 68. [all data]

Larsen, Thorpe, et al., 1942
Larsen, R.G.; Thorpe, R.E.; Armfield, F.A., Oxidation Characteristics of Pure Hydrocarbons, Ind. Eng. Chem., 1942, 34, 183. [all data]

Petrov and Chel'tsova, 1942
Petrov, A.D.; Chel'tsova, M.A., Synthesis and Properties of Hydrocarbons of the Aromatic and Naphthenic Series of the Composition C19-C26. II., J. Gen. Chem. USSR (Engl. Transl.), 1942, 12, 87-94. [all data]

Schmidt, 1942
Schmidt, A.W., Physical properties of aliphatic compounds, Ber. Dtsch. Chem. Ges. B, 1942, 75, 1399. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Kusmierz, Malinski, et al., 1985
Kusmierz, J.; Malinski, E.; Czerwiec, W.; Szafranek, J., Kováts retention indices of high-molecular-weight monomethyl-, cyclopentyl-, cyclohexyl- and phenylalkanes, J. Chromatogr., 1985, 331, 219-228, https://doi.org/10.1016/0021-9673(85)80027-3 . [all data]

Kenig, Simons, et al., 2005
Kenig, F.; Simons, D.-J.H.; Crich, D.; Cowen, J.P.; Ventura, G.T.; Rehbein-Khalily, T., Structure and distribution of branched aliphatic alkanes with quaternary carbon atoms in Cenomanian and Turonian black shales of Pasquia Hills (Saskatchewan, Canada), Org. Geochem., 2005, 36, 1, 117-138, https://doi.org/10.1016/j.orggeochem.2004.06.014 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References