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Formamide, N,N-dimethyl-

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-239.4 ± 1.2kJ/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Deltafliquid-239.0kJ/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1941.6 ± 1.2kJ/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Deltacliquid-1941.9kJ/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
146.05298.15Grolier, Roux-Desgranges, et al., 1993DH
148.16298.15Kolker, Kulikov, et al., 1992T = 283 to 323 K.; DH
149.28308.Kulikov, Krestov, et al., 1989DH
150.0298.15Petrov, Peshekhodov, et al., 1989T = 258.15, 278.15, 298.15, 318.15 K.; DH
148.36298.15Zegers and Somsen, 1984DH
150.5298.15Vorob'ev and Yakovlev, 1982T = 297.15 to 299.15 K. Cp given as 2.059 J/g*K.; DH
150.8298.15de Visser and Somsen, 1979DH
120.5298.Marchidan and Ciopec, 1978T = 298 to 427 K. Mean value over range.; DH
148.298.15De Visser, Perron, et al., 1977DH
148.298.De Visser, Perron, et al., 1977One temperature only.; DH
150.8298.15De Visser, Perron, et al., 1977, 2DH
146.298.15Bonner and Cerutti, 1976DH
152.0298.15de Visser and Somsen, 1974DH
156.69298.Geller, 1961T = 273 to 323 K.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil426. ± 1.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus212.7KN/ADreisbach, 1955Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc649.6KN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
rhoc3.82mol/lN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.08 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap46.7 ± 0.5kJ/molCGCPanneerselvam, Antony, et al., 2009Based on data from 463. - 513. K.; AC
Deltavap46.9kJ/molABarone, Castronuovo, et al., 1985See also Majer and Svoboda, 1985.; AC
Deltavap47.57kJ/molEGeller, 1961, 2ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
43.1361.N/AMuñoz, Montón, et al., 2005Based on data from 346. - 425. K.; AC
41.8392.N/ABlanco, Beltrán, et al., 1997Based on data from 377. - 426. K.; AC
43.6353.N/AMarzal, Gabaldon, et al., 1995Based on data from 338. - 425. K.; AC
49.2316.AStephenson and Malanowski, 1987Based on data from 301. - 426. K.; AC
42.5370.N/ABludilina, Baev, et al., 1979Based on data from 318. - 423. K.; AC
56.7346.N/AMyasinkova, Schmelev, et al., 1974Based on data from 331. - 425. K. See also Boublik, Fried, et al., 1984.; AC
46.7318.N/AGopal and Rizvi, 1968Based on data from 303. - 363. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
303. - 363.3.930681337.716-82.648Gopal and Rizvi, 1968, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
8.950212.85N/AKaryakin, Rabinovich, et al., 1978DH
8.95212.9ACSmirnova, Tsvetkova, et al., 2007AC
8.95212.9N/ADomalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
41.8212.85Karyakin, Rabinovich, et al., 1978DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M
25.343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Formamide, N,N-dimethyl- = (C6H5NO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H5NO2- + C3H7NO = (C6H5NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar16. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar23. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- bullet Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar10. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
10.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- bullet Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar19. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6F4O2- + Formamide, N,N-dimethyl- = (C6F4O2- bullet Formamide, N,N-dimethyl-)

By formula: C6F4O2- + C3H7NO = (C6F4O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar11. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
11.343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Formamide, N,N-dimethyl- = (p-Benzoquinone anion bullet Formamide, N,N-dimethyl-)

By formula: C6H4O2- + C3H7NO = (C6H4O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar18. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

Potassium ion (1+) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: K+ + C3H7NO = (K+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molCIDTKlassen, Anderson, et al., 1996RCD
Deltar130.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KHPMSSunner, 1984gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar19. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.343.PHPMSChowdhury, 1987gas phase; M

C7H4F3NO2- + Formamide, N,N-dimethyl- = (C7H4F3NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4F3NO2- + C3H7NO = (C7H4F3NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar156. ± 4.kJ/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
126.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

C3H6NO- + Hydrogen cation = Formamide, N,N-dimethyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Deltar1670. ± 17.kJ/molG+TSDePuy, Grabowski, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar1640. ± 17.kJ/molIMRBDePuy, Grabowski, et al., 1985gas phase; B

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

(Potassium ion (1+) bullet 2Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 3Formamide, N,N-dimethyl-)

By formula: (K+ bullet 2C3H7NO) + C3H7NO = (K+ bullet 3C3H7NO)

Quantity Value Units Method Reference Comment
Deltar63.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) bullet 3Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 4Formamide, N,N-dimethyl-)

By formula: (K+ bullet 3C3H7NO) + C3H7NO = (K+ bullet 4C3H7NO)

Quantity Value Units Method Reference Comment
Deltar54.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) bullet Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 2Formamide, N,N-dimethyl-)

By formula: (K+ bullet C3H7NO) + C3H7NO = (K+ bullet 2C3H7NO)

Quantity Value Units Method Reference Comment
Deltar88.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KHPMSSunner, 1984gas phase; M

Gas phase ion energetics data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C3H7NO+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.13eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)887.5kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity856.6kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Reference Comment
0.01362Desfrancois, Periquet, et al., 1999B

Ionization energy determinations

IE (eV) Method Reference Comment
9.45 ± 0.05EIBaldwin, Loudon, et al., 1977LLK
9.14PEBrundle, Turner, et al., 1969RDSH
9.12 ± 0.02PIWatanabe, Nakayama, et al., 1962RDSH
9.14PEBieri, Asbrink, et al., 1982Vertical value; LBLHLM
9.25PEHenriksen, Isaksson, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+14.50?EILoudon and Webb, 1977LLK
CHO+14.3 ± 0.1?EIGowenlock, Jones, et al., 1961RDSH
C2H6N+11.60?EILoudon and Webb, 1977LLK
C2H6N+11.6 ± 0.1?EIGowenlock, Jones, et al., 1961RDSH
C3H6NO+11.35?EILoudon and Webb, 1977LLK

De-protonation reactions

C3H6NO- + Hydrogen cation = Formamide, N,N-dimethyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Deltar1670. ± 17.kJ/molG+TSDePuy, Grabowski, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar1640. ± 17.kJ/molIMRBDePuy, Grabowski, et al., 1985gas phase; B

Ion clustering data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6F4O2- + Formamide, N,N-dimethyl- = (C6F4O2- bullet Formamide, N,N-dimethyl-)

By formula: C6F4O2- + C3H7NO = (C6F4O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar11. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
11.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar23. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- bullet Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar10. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
10.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- bullet Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar19. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Formamide, N,N-dimethyl- = (p-Benzoquinone anion bullet Formamide, N,N-dimethyl-)

By formula: C6H4O2- + C3H7NO = (C6H4O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar18. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Formamide, N,N-dimethyl- = (C6H5NO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H5NO2- + C3H7NO = (C6H5NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C7H4F3NO2- + Formamide, N,N-dimethyl- = (C7H4F3NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4F3NO2- + C3H7NO = (C7H4F3NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar19. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar16. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M
25.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- bullet Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

Potassium ion (1+) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: K+ + C3H7NO = (K+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molCIDTKlassen, Anderson, et al., 1996RCD
Deltar130.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) bullet Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 2Formamide, N,N-dimethyl-)

By formula: (K+ bullet C3H7NO) + C3H7NO = (K+ bullet 2C3H7NO)

Quantity Value Units Method Reference Comment
Deltar88.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) bullet 2Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 3Formamide, N,N-dimethyl-)

By formula: (K+ bullet 2C3H7NO) + C3H7NO = (K+ bullet 3C3H7NO)

Quantity Value Units Method Reference Comment
Deltar63.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) bullet 3Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) bullet 4Formamide, N,N-dimethyl-)

By formula: (K+ bullet 3C3H7NO) + C3H7NO = (K+ bullet 4C3H7NO)

Quantity Value Units Method Reference Comment
Deltar54.kJ/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KHPMSSunner, 1984gas phase; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar156. ± 4.kJ/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
126.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118531

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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1.) Enter the desired X axis range (e.g., 100, 200)
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Additional Data

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Source Hunt and Simpson, 1953
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 2819
Instrument n.i.g.
Melting point -60.4
Boiling point 153

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'eva, Zhil'tsova, et al., 1972
Vasil'eva, T.F.; Zhil'tsova, E.N.; Vvedenskii, A.A., Enthalpies of combustion of NN-dimethylformamide and NN-dimethylacetamide, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 315. [all data]

Medard and Thomas, 1957
Medard, L.; Thomas, M., Chaleur de combustion de onze substances explosives ou apparentees a des explosifs, Mem. Poudres, 1957, 39, 195-208. [all data]

Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide, J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]

Kolker, Kulikov, et al., 1992
Kolker, A.M.; Kulikov, M.V.; Krestov, Al.G., Volumes and heat capacities of binary non-aqueous mixtures. Part 2. The systems acetonitrile-N,N-dimethylformamide and acetonitrile-hexamethylphosphoric triamide, Thermochim. Acta, 1992, 211, 73-84. [all data]

Kulikov, Krestov, et al., 1989
Kulikov, M.V.; Krestov, A.G.; Safonova, L.P.; Kolker, A.M., Excess thermodynamic functions in the systems water + N-methylformamide, and water + N,N-dimethylformamide, Sbornik Nauch Trud., Termodin. rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A., Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Zegers and Somsen, 1984
Zegers, H.C.; Somsen, G., Partial molar volumes and heat capacities in (dimethylformamide + an n-alkanol), J. Chem. Thermodynam., 1984, 16, 225-235. [all data]

Vorob'ev and Yakovlev, 1982
Vorob'ev, A.F.; Yakovlev, P.N., The specific heats of dimethylformamide-water and hexamethylphosphoramide-water mixtures, Zhur. Fiz. Khim., 1982, 56, 1933-1936. [all data]

de Visser and Somsen, 1979
de Visser, C.; Somsen, G., Thermochemical behavior of mixtures of N,N-dimethylformamide with dimethylsulfoxide, acetonitrile, and N-methylformamide: volumes and heat capacities, J. Solution Chem., 1979, 8, 593-600. [all data]

Marchidan and Ciopec, 1978
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De Visser, Perron, et al., 1977
De Visser, C.; Perron, G.; Desnoyers, J.E., Volumes and heat capacities of ternary aqueous systems at 25°C. Mixtures of urea, tert-butyl alcohol, N,N-dimethylformamide, and water, J. Amer. Chem. Soc., 1977, 99, 5894-5900. [all data]

De Visser, Perron, et al., 1977, 2
De Visser, C.; Perron, G.; Desnoyers, J.E.; Heuvelsland, W.J.M.; Somsen, G., Volumes and heat capacities of mixtures of N,N-dimethylformamide and water at 298.15 K, J. Chem. Eng. Data, 1977, 22, 74-79. [all data]

Bonner and Cerutti, 1976
Bonner, O.D.; Cerutti, P.J., The partial molar heat capacities of some solutes in water and deuterium oxide, J. Chem. Thermodynam., 1976, 8, 105-111. [all data]

de Visser and Somsen, 1974
de Visser, C.; Somsen, G., Molar heat capacities of binary mixtures of water and some amides at 298.15 K, Z. Physik. Chem. [N.F.], 1974, 92, 159-162. [all data]

Geller, 1961
Geller, B.E., Some physicochemical properties of dimethylformamide, Zhur. Fiz. Khim., 1961, 35, 2210-2216. [all data]

Dreisbach, 1955
Dreisbach, R.R., Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]

Teja and Anselme, 1990
Teja, A.S.; Anselme, M.J., The critical properties of thermally stable and unstable fluids. I. 1985 results, AIChE Symp. Ser., 1990, 86, 279, 115-21. [all data]

Panneerselvam, Antony, et al., 2009
Panneerselvam, K.; Antony, M.P.; Srinivasan, T.G.; Vasudeva Rao, P.R., Enthalpies of vaporization of N,N-dialkyl monamides at 298.15K, Thermochimica Acta, 2009, 495, 1-2, 1-4, https://doi.org/10.1016/j.tca.2009.05.007 . [all data]

Barone, Castronuovo, et al., 1985
Barone, G.; Castronuovo, G.; Della Gatta, G.; Elia, V.; Iannone, A., Enthalpies of vaporization of seven alkylamides, Fluid Phase Equilibria, 1985, 21, 1-2, 157-164, https://doi.org/10.1016/0378-3812(85)90066-4 . [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Geller, 1961, 2
Geller, B.E., Properties of the dimethylformamide water system. I. Thermochemical properties, Russ. J. Phys. Chem. (Engl. Transl.), 1961, 35, 542-564. [all data]

Muñoz, Montón, et al., 2005
Muñoz, R.; Montón, J.B.; Burguet, M.C.; de la Torre, J., Phase equilibria in the systems isobutyl alcohol+N,N-dimethylformamide, isobutyl acetate+N,N-dimethylformamide and isobutyl alcohol+isobutyl acetate+N,N-dimethylformamide at 101.3kPa, Fluid Phase Equilibria, 2005, 232, 1-2, 62-69, https://doi.org/10.1016/j.fluid.2005.03.014 . [all data]

Blanco, Beltrán, et al., 1997
Blanco, Beatriz; Beltrán, Sagrario; Cabezas, José Luis; Coca, José, Phase Equilibria of Binary Systems Formed by Hydrocarbons from Petroleum Fractions and the Solvents N -Methylpyrrolidone and N , N -Dimethylformamide. 1. Isobaric Vapor-Liquid Equilibria, J. Chem. Eng. Data, 1997, 42, 5, 938-942, https://doi.org/10.1021/je970059u . [all data]

Marzal, Gabaldon, et al., 1995
Marzal, Paula; Gabaldon, Carmen; Seco, Aurora; Monton, Juan B., Isobaric Vapor-Liquid Equilibria of 1-Butanol + N,N-Dimethylformamide and 1-Pentanol + N,N-Dimethylformamide Systems at 50.00 and 100.00 kPa, J. Chem. Eng. Data, 1995, 40, 3, 589-592, https://doi.org/10.1021/je00019a010 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Bludilina, Baev, et al., 1979
Bludilina, V.I.; Baev, A.K.; Matveev, V.K.; Gaidym, I.L.; Shcherbina, E.I., Zh. Fiz. Khim., 1979, 53, 1052. [all data]

Myasinkova, Schmelev, et al., 1974
Myasinkova, L.F.; Schmelev, V.A.; Vaisman, I.L.; Bushinskii, V.I.; Novokhatka, D.A., Zh. Prikl. Khim. (Leningrad), 1974, 47, 2604. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Gopal and Rizvi, 1968
Gopal, R.; Rizvi, S.A., J. Indian Chem. Soc., 1968, 45, 1, 13. [all data]

Gopal and Rizvi, 1968, 2
Gopal, R.; Rizvi, S.A., Vapour Pressures of Some Mono- and Di-Alkyl Substituted Aliphatic Amides at Different Temperatures, J. Indian Chem. Soc., 1968, 45, 1, 13-16. [all data]

Karyakin, Rabinovich, et al., 1978
Karyakin, N.V.; Rabinovich, I.B.; Pal'tseva, N.G., Thermodynamics of the reactions of aromatic diamines with dianhydrides of tetracarboxylic acids, Vysokomol. Soedin, Ser., 1978, A 20(9), 2025-2029. [all data]

Smirnova, Tsvetkova, et al., 2007
Smirnova, N.N.; Tsvetkova, L.Ya.; Bykova, T.A.; Marcus, Yizhak, Thermodynamic properties of N,N-dimethylformamide and N,N-dimethylacetamide, The Journal of Chemical Thermodynamics, 2007, 39, 11, 1508-1513, https://doi.org/10.1016/j.jct.2007.02.009 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Klassen, Anderson, et al., 1996
Klassen, J.S.; Anderson, S.G.; Blades, A.T.; Kebarle, P., Reaction Enthalpies for M+L = M+ + L, Where M+ = Na+ and K+ and L = Acetamide, N-Methylacetamide, N,N-Dimethylacetamide, Glycine, and Glycylglycine, from Determinations of the Collision-Induced Dissociation Thresholds, J. Phys. Chem., 1996, 100, 33, 14218, https://doi.org/10.1021/jp9608382 . [all data]

Sunner, 1984
Sunner, J. Kebarle, Ion - Solvent Molecule Interactions in the Gas Phase. The Potassium Ion and Me2SO, DMA, DMF, and Acetone, J. Am. Chem. Soc., 1984, 106, 21, 6135, https://doi.org/10.1021/ja00333a002 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

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DePuy, C.H.; Grabowski, J.J.; Bierbaum, V.M.; Ingemann, S.; Nibbering, N.M.M., Gas-phase reactions of anions with methyl formate and N,N-dimethylformamide, J. Am. Chem. Soc., 1985, 107, 1093. [all data]

Staley and Beauchamp, 1975
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Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

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Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

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Desfrancois, C.; Periquet, V.; Carles, S.; Schermann, J.P.; Smith, D.M.A.; Adamowicz, L., Experimental and ab initio theoretical studies of electron binding to formamide, N-methylformamide, and N,N-dimethylformamide., J. Chem. Phys., 1999, 110, 9, 4309-4314, https://doi.org/10.1063/1.478353 . [all data]

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Baldwin, M.A.; Loudon, A.G.; Webb, K.S.; Cardnell, P.C., Charge location and fragmentation under electron impact. V-The ionization potentials of (methylated) phosphoramides, guanidines, formamides, acetamides, ureas and thioureas, Org. Mass Spectrom., 1977, 12, 279. [all data]

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Gowenlock, Jones, et al., 1961
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Hunt and Simpson, 1953
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Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References