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Formamide, N,N-dimethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-57.21 ± 0.29kcal/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Deltafliquid-57.13kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-464.06 ± 0.29kcal/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Deltacliquid-464.13kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
34.907298.15Grolier, Roux-Desgranges, et al., 1993DH
35.411298.15Kolker, Kulikov, et al., 1992T = 283 to 323 K.; DH
35.679308.Kulikov, Krestov, et al., 1989DH
35.85298.15Petrov, Peshekhodov, et al., 1989T = 258.15, 278.15, 298.15, 318.15 K.; DH
35.459298.15Zegers and Somsen, 1984DH
35.97298.15Vorob'ev and Yakovlev, 1982T = 297.15 to 299.15 K. Cp given as 2.059 J/g*K.; DH
36.04298.15de Visser and Somsen, 1979DH
28.80298.Marchidan and Ciopec, 1978T = 298 to 427 K. Mean value over range.; DH
35.4298.15De Visser, Perron, et al., 1977DH
35.4298.De Visser, Perron, et al., 1977One temperature only.; DH
36.04298.15De Visser, Perron, et al., 1977, 2DH
34.9298.15Bonner and Cerutti, 1976DH
36.33298.15de Visser and Somsen, 1974DH
37.450298.Geller, 1961T = 273 to 323 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'eva, Zhil'tsova, et al., 1972
Vasil'eva, T.F.; Zhil'tsova, E.N.; Vvedenskii, A.A., Enthalpies of combustion of NN-dimethylformamide and NN-dimethylacetamide, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 315. [all data]

Medard and Thomas, 1957
Medard, L.; Thomas, M., Chaleur de combustion de onze substances explosives ou apparentees a des explosifs, Mem. Poudres, 1957, 39, 195-208. [all data]

Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide, J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]

Kolker, Kulikov, et al., 1992
Kolker, A.M.; Kulikov, M.V.; Krestov, Al.G., Volumes and heat capacities of binary non-aqueous mixtures. Part 2. The systems acetonitrile-N,N-dimethylformamide and acetonitrile-hexamethylphosphoric triamide, Thermochim. Acta, 1992, 211, 73-84. [all data]

Kulikov, Krestov, et al., 1989
Kulikov, M.V.; Krestov, A.G.; Safonova, L.P.; Kolker, A.M., Excess thermodynamic functions in the systems water + N-methylformamide, and water + N,N-dimethylformamide, Sbornik Nauch Trud., Termodin. rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A., Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Zegers and Somsen, 1984
Zegers, H.C.; Somsen, G., Partial molar volumes and heat capacities in (dimethylformamide + an n-alkanol), J. Chem. Thermodynam., 1984, 16, 225-235. [all data]

Vorob'ev and Yakovlev, 1982
Vorob'ev, A.F.; Yakovlev, P.N., The specific heats of dimethylformamide-water and hexamethylphosphoramide-water mixtures, Zhur. Fiz. Khim., 1982, 56, 1933-1936. [all data]

de Visser and Somsen, 1979
de Visser, C.; Somsen, G., Thermochemical behavior of mixtures of N,N-dimethylformamide with dimethylsulfoxide, acetonitrile, and N-methylformamide: volumes and heat capacities, J. Solution Chem., 1979, 8, 593-600. [all data]

Marchidan and Ciopec, 1978
Marchidan, D.I.; Ciopec, M., Relative enthalpies and related thermodynamic functions of some organic compounds by drop calorimetry, J. Therm. Anal., 1978, 14, 131-150. [all data]

De Visser, Perron, et al., 1977
De Visser, C.; Perron, G.; Desnoyers, J.E., Volumes and heat capacities of ternary aqueous systems at 25°C. Mixtures of urea, tert-butyl alcohol, N,N-dimethylformamide, and water, J. Amer. Chem. Soc., 1977, 99, 5894-5900. [all data]

De Visser, Perron, et al., 1977, 2
De Visser, C.; Perron, G.; Desnoyers, J.E.; Heuvelsland, W.J.M.; Somsen, G., Volumes and heat capacities of mixtures of N,N-dimethylformamide and water at 298.15 K, J. Chem. Eng. Data, 1977, 22, 74-79. [all data]

Bonner and Cerutti, 1976
Bonner, O.D.; Cerutti, P.J., The partial molar heat capacities of some solutes in water and deuterium oxide, J. Chem. Thermodynam., 1976, 8, 105-111. [all data]

de Visser and Somsen, 1974
de Visser, C.; Somsen, G., Molar heat capacities of binary mixtures of water and some amides at 298.15 K, Z. Physik. Chem. [N.F.], 1974, 92, 159-162. [all data]

Geller, 1961
Geller, B.E., Some physicochemical properties of dimethylformamide, Zhur. Fiz. Khim., 1961, 35, 2210-2216. [all data]


Notes

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