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3-Hexenal, (Z)-

Normal alkane RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5HP-5MS5 % Phenyl methyl siloxaneDB-5
Column length (m) 60.30. 30.60.
Carrier gas HeliumHe   
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (mum) 0.250.25 0.750.25
Program 50 0C (5 min) 3 0C/min -> 120 0C 5 0C/min -> 250 0C (3 min) 15 0C/min -> 300 0C (20 min)40C(1min) => 7C/min => 110C => 5C/min => 180C => 10C/min => 240C(10min)not specified50C(1min) => 5C/min => 100C => 10C/min => 190C => 30C/min => 250C(1min)50C => 5C/min => 100C => 15C/min => 250C (19C)
I 775.800.800.799.796.
ReferenceDelort and Jaquier, 2009Greger and Schieberle, 2007Mallia, Escher, et al., 2007Beaulieu J.C. and Lea J.M., 2006Beaulieu, 2005
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5CP-Sil5 CB MSSE-54DB-5SF-96
Column length (m)
Carrier gas He  H2 
Column diameter (mm) 0.20.320.320.30.28
Phase thickness (mum) 
Program 40C(1min) => 5C/min => 210C => 20C/min => 250C(8min)36C(2min) => 20C/min => 85C => 1C/min => 145C => 3C/min => 250C(30min)35C (2min) => 40C/min => 50C (2min) => 6C/min => 180C => 10C/min => 230C (10min)35C (1min) => 40C/min => 60C (5min) => 4C/min => 240C75C => 3C/min => 190C(25min) => 3C/min => 210C
I 803.764.798.800.773.
ReferenceHimanen, Vuorinen, et al., 2005Iraqi, Vermeulen, et al., 2005Buettner, Mestres, et al., 2003Triqui and Bouchriti, 2003Kawasaki, Matsui, et al., 1998
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5RTX-5RTX-5SE-54SE-54
Column length (m) 30.  30.30.
Carrier gas He   He
Column diameter (mm) 0.53  0.320.32
Phase thickness (mum) 1.5  0.25 
Program 35 0C (2 min) 40 0C/min -> 60 0C (1 min) 6 0C/min -> 230 0Cnot specifiednot specified35 0C (2 min) 40 0C/min -> 50 0C (1 min) 6 0C/min -> 230 0C40 0C -> (unknowm rate) 50 0C (2 min) 6 0C/min -> 200 0C
I 800.800.800.800.800.
ReferenceMasanetz and Grosch, 1998Masanetz, Guth, et al., 1998Masanetz, Guth, et al., 1998Reiners and Grosch, 1998Milo and Grosch, 1993
Column type Capillary
Active phase SE-54
Column length (m) 30.
Carrier gas  
Column diameter (mm) 0.32
Phase thickness (mum) 0.20
Program 2 min at 35 0C; 35-50 0C at 40 deg/min; 5 min at 50 0C; 50 - 220 0C at 4 deg/min;
I 800.
ReferenceSchieberle, Ofner, et al., 1990
Comment MSDC-RI


Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Delort and Jaquier, 2009
Delort, E.; Jaquier, A., Novel terpenyl esters from Australian finger lime (Citrus australasica) peel extract, Flav. Fragr. J., 2009, 24, 3, 123-132, https://doi.org/10.1002/ffj.1922 . [all data]

Greger and Schieberle, 2007
Greger, V.; Schieberle, P., Characterization of the Key Aroma Compounds in Apricots (Prunus armeniaca) by Application of the Molecular Sensory Science Concept, J. Agric. Food Chem., 2007, 55, 13, 5221-5228, https://doi.org/10.1021/jf0705015 . [all data]

Mallia, Escher, et al., 2007
Mallia, S.; Escher, F.; Rehberger, B.; Schlichtherle-Cerny, H., Aroma-active secondary oxidation products of butter, 3rd QLIF Congress, Hohenheim, Germany, March 20-23, 2007, 2007, retrieved from http://orgprints.org/view/projects/intconfqlif2007.html; http://orgprints.org/9734/. [all data]

Beaulieu J.C. and Lea J.M., 2006
Beaulieu J.C.; Lea J.M., Characterization and semiquantitative analysis of volatiles in seedless watermelon varieties using solid-phase microextraction, J. Agric. Food Chem., 2006, 54, 20, 7789-7793, https://doi.org/10.1021/jf060663l . [all data]

Beaulieu, 2005
Beaulieu, J.C., Within-Season Volatile and Quality Differences in Stored Fresh-Cut Cantaloupe Cultivars, J. Agric. Food Chem., 2005, 53, 22, 8679-8687, https://doi.org/10.1021/jf050241w . [all data]

Himanen, Vuorinen, et al., 2005
Himanen, S.; Vuorinen, T.; Tuovinen, T.; Holopainen, J.K., Effects of Cyclamen Mite (Phytonemus pallidus) and Leaf Beetle (Galerucella tenella) Damage on Volatile Emission from Strawberry (Fragaria ´ ananassa Duch.) Plants and Orientation of Predatory Mites (Neoseiulus cucumeris, N. californicus, and Euseius finlandicus), J. Agric. Food Chem., 2005, 53, 8624-8630. [all data]

Iraqi, Vermeulen, et al., 2005
Iraqi, R.; Vermeulen, C.; Benzekri, A.; Bouseta, A.; Collin, S., Screening for key odorants in Moroccan green olives by gas chromatography-olfactometry/aroma extract dilution analysis, J. Agric. Food Chem., 2005, 53, 4, 1179-1184, https://doi.org/10.1021/jf040349w . [all data]

Buettner, Mestres, et al., 2003
Buettner, A.; Mestres, M.; Fischer, A.; Guasch, J.; Schieberle, P., Evaluation of the most odour-active compounds in the peel oil of clementines ( citrus reticulata blanco cv. clementine), Eur. Food Res. Technol., 2003, 216, 11-14. [all data]

Triqui and Bouchriti, 2003
Triqui, R.; Bouchriti, N., Freshness assessments of Moroccan sardine (Sardina pilchardus): comparison of overall sensory changes to instrumentally determined volatiles, J. Agric. Food Chem., 2003, 51, 26, 7540-7546, https://doi.org/10.1021/jf0348166 . [all data]

Kawasaki, Matsui, et al., 1998
Kawasaki, W.; Matsui, K.; Akakabe, Y.; Itai, N.; Kajiwara, T., Long-chain aldehyde-forming activity in tobacco leaves, Phytochemistry, 1998, 49, 6, 1565-1568, https://doi.org/10.1016/S0031-9422(98)00236-2 . [all data]

Masanetz and Grosch, 1998
Masanetz, C.; Grosch, W., Key odorants of parsley leaves (Petroselinum crispum [Mill.] Nym. ssp. crispum) by odour-activity values, Flavour Fragr. J., 1998, 13, 2, 115-124, https://doi.org/10.1002/(SICI)1099-1026(199803/04)13:2<115::AID-FFJ706>3.0.CO;2-6 . [all data]

Masanetz, Guth, et al., 1998
Masanetz, C.; Guth, H.; Grosch, W., Fishy and hay-like off-flavours of dry spinach, Z. Lebensm. Unters. Forsch. A, 1998, 206, 2, 108-113, https://doi.org/10.1007/s002170050224 . [all data]

Reiners and Grosch, 1998
Reiners, J.; Grosch, W., Odorants of virgin olive oils with different flavor profiles, J. Agric. Food Chem., 1998, 46, 7, 2754-2763, https://doi.org/10.1021/jf970940b . [all data]

Milo and Grosch, 1993
Milo, C.; Grosch, W., Changes in the odorants of boiled trout (Salmo fario) as affected by the storage of the raw material, J. Agric. Food Chem., 1993, 41, 11, 2076-2081, https://doi.org/10.1021/jf00035a048 . [all data]

Schieberle, Ofner, et al., 1990
Schieberle, P.; Ofner, S.; Grosch, W., Evaluation of Potent Odorants in Cucumbers (Cucumis sativus) and Muskmelons (Cucumis melo) by Aroma Extract Dilution Analysis, J. Food Sci., 1990, 55, 1, 193-195, https://doi.org/10.1111/j.1365-2621.1990.tb06050.x . [all data]


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