3-Hexenal, (Z)-
- Formula: C6H10O
- Molecular weight: 98.1430
- IUPAC Standard InChIKey: GXANMBISFKBPEX-ARJAWSKDSA-N
- CAS Registry Number: 6789-80-6
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- Other names: cis-3-Hexenal; 3-(Z)-Hexenal; cis-β,γ-Hexylenic aldehyde; (3Z)-3-Hexenal; Hex-cis-3-enal; (Z)-3-Hexen-1-al; (Z)-3-Hexenal; (Z)-Hex-3enal
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | TNO Volatile Compounds in Food - Chemical Concepts |
NIST MS number | 249462 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 1138. | Umano, Hagi, et al., 1994 | He, 40. C @ 2. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 200. C |
Capillary | Carbowax 20M | 1142. | Nishimura, Yamaguchi, et al., 1989 | 2. K/min; Column length: 50. m; Column diameter: 0.22 mm; Tstart: 80. C; Tend: 200. C |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SE-54 | 810. | Schlutt B., Moran N., et al., 2007 | He, 40. C @ 2. min, 8. K/min, 240. C @ 5. min; Column length: 50. m; Column diameter: 0.32 mm |
Capillary | CP-Sil 8CB-MS | 808. | Elmore, Cooper, et al., 2005 | 0. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min, 280. C @ 5. min |
Capillary | DB-5MS | 806. | Seo and Baek, 2005 | 60. m/0.25 mm/0.25 μm, He, 2. K/min, 200. C @ 20. min; Tstart: 40. C |
Capillary | SPB-5 | 782. | Rodríguez-Burruezo, Kollmannsberger, et al., 2004 | 30. m/0.53 mm/1.5 μm, He, 5. K/min; Tstart: 100. C; Tend: 250. C |
Capillary | DB-5MS | 804. | Yu, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5MS | 805. | Yu, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5MS | 800. | Yu, Kim, et al., 2004, 2 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5MS | 800. | Yu, Kim, et al., 2004, 2 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5MS | 804. | Zheng, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5MS | 801. | Zheng, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-5 | 784. | Högnadóttir and Rouseff, 2003 | 30. m/0.32 mm/0.5 μm, 7. K/min, 265. C @ 5. min; Tstart: 40. C |
Capillary | DB-5 | 795. | Högnadóttir and Rouseff, 2003 | 30. m/0.32 mm/0.5 μm, 7. K/min, 265. C @ 5. min; Tstart: 40. C |
Capillary | DB-5 | 795. | Valim, Rouseff, et al., 2003 | 60. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 40. C; Tend: 275. C |
Capillary | HP-5 | 801. | Ruther, 2000 | 30. m/0.32 mm/0.25 μm, 40. C @ 4. min, 3. K/min; Tend: 280. C |
Capillary | OV-1 | 778. | Schreyen, Dirinck, et al., 1976 | 1. K/min; Column length: 183. m; Column diameter: 0.762 mm; Tstart: 0. C; Tend: 230. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SE-54 | 800. | Schuh and Schieberle, 2006 | 30. m/0.32 mm/0.25 μm; Program: 40C(2min) => 6C/min => 150C => 20C/min => 230C |
Capillary | DB-5MS | 803. | Zheng, Kim, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 40 (5min) => 4C/min => 140C => 4C/min => 200C (20min) |
Capillary | DB-5MS | 799. | Zheng, Kim, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 40 (5min) => 4C/min => 140C => 4C/min => 200C (20min) |
Capillary | HP-5 | 803. | Carrapiso, Jurado, et al., 2002 | 50. m/0.32 mm/1.05 μm; Program: 35C (5min) => 10C/min => 150C => 20C/min => 250C (10min) |
Capillary | HP-5 | 803. | Carrapiso, Ventanas, et al., 2002 | 50. m/0.32 mm/1.05 μm; Program: 35C(5min) => 10C/min => 150C => 20C/min => 250C(10 min) |
Capillary | CP Sil 8 CB | 800. | Fuhrmann and Grosch, 2002 | 25. m/0.32 mm/0.25 μm, He; Program: 35C(2min) => 5C/min => 170C => 20C/min => 240C (10min) |
Capillary | RTX-5 | 800. | Fuhrmann and Grosch, 2002 | Program: not specified |
Capillary | DB-5 | 796. | Beaulieu and Grimm, 2001 | 30. m/0.25 mm/0.25 μm, He; Program: 50C (1min) => 5C/min => 100C => 10C/min => 250C (9min) |
Capillary | CP Sil 8 CB | 797. | Steinhaus and Schieberle, 2000 | He; Column length: 30. m; Column diameter: 0.32 mm; Program: 35C (2min) => 40C/min => 50C (2min) => 6C/min => 180C => 10C/min => 240C |
Capillary | DB-5 | 785. | Boulanger, Chassagne, et al., 1999 | 30. m/0.25 mm/0.25 μm, H2; Program: 40C(5min) => 2C/min => 220C => 5C/min => 250C(15min) |
Capillary | SE-54 | 798. | Buettner and Schieberle, 1999 | 30. m/0.32 mm/0.25 μm, He; Program: 35C (2min) => 40C/min => 50C (2min) => 6C/min => 180C => 10C/min => 230C (10min) |
Capillary | SE-54 | 793. | Derail, Hofmann, et al., 1999 | 30. m/0.32 mm/0.25 μm, He; Program: 35C (2min) => 40C/min => 50C => 4C/min => 230C (10min) |
Capillary | SE-54 | 798. | Hinterholzer, Lemos, et al., 1998 | 30. m/0.32 mm/0.25 μm, He; Program: 35C(2min) => 40C/min => 50C(2min) => 6C/min => 180C => 10C/min => 230C(10 min) |
Capillary | SE-54 | 798. | Hinterholzer and Schieberie, 1998 | 30. m/0.32 mm/0.25 μm, He; Program: 35C(2min) => 40C/min => 50C(2min) => 6C/min => 180C => 10C/min => 230C(10min) |
Capillary | SE-54 | 800. | Heiler and Schieberle, 1997 | Program: not specified |
Capillary | SE-54 | 795. | Ullrich and Grosch, 1988 | Program: not specified |
Van Den Dool and Kratz RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | FFAP | 1135. | Schlutt B., Moran N., et al., 2007 | He, 40. C @ 2. min, 8. K/min, 240. C @ 5. min; Column length: 30. m; Column diameter: 0.32 mm |
Capillary | Supelcowax-10 | 1153. | Arena, Guarrera, et al., 2006 | 30. m/0.32 mm/0.5 μm, He, 70. C @ 7. min, 4. K/min, 220. C @ 20. min |
Capillary | DB-Wax Etr | 1146. | Aubert C. and Pitrat M., 2006 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 5. K/min, 250. C @ 15. min |
Capillary | DB-Wax Etr | 1142. | Ménager, Jost, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 3. K/min, 245. C @ 20. min |
Capillary | DB-Wax | 1120. | Yu, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1124. | Yu, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1126. | Yu, Kim, et al., 2004, 2 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1118. | Yu, Kim, et al., 2004, 2 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1126. | Zheng, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1124. | Zheng, Kim, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 4. K/min, 200. C @ 20. min |
Capillary | DB-Wax | 1151. | Högnadóttir and Rouseff, 2003 | 30. m/0.32 mm/0.5 μm, 7. K/min, 240. C @ 5. min; Tstart: 40. C |
Capillary | DB-Wax | 1132. | Ruther, 2000 | 30. m/0.32 mm/0.25 μm, 40. C @ 4. min, 3. K/min; Tend: 230. C |
Capillary | Carbowax 20M | 1165. | Suárez and Duque, 1992 | 25. m/0.31 mm/0.3 μm, 2. K/min; Tstart: 50. C; Tend: 200. C |
Capillary | Carbowax 20M | 1160. | Suárez and Duque, 1991 | 2. K/min; Column length: 25. m; Column diameter: 0.31 mm; Tstart: 50. C; Tend: 200. C |
Capillary | Carbowax 20M | 1165. | Suárez and Duque, 1991 | 2. K/min; Column length: 25. m; Column diameter: 0.31 mm; Tstart: 50. C; Tend: 200. C |
Van Den Dool and Kratz RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | FFAP | 1148. | Schuh and Schieberle, 2006 | 30. m/0.32 mm/0.25 μm; Program: 40C(2min) => 6C/min => 150C => 20C/min => 230C |
Capillary | SOLGel-Wax | 1111. | Aubert, Baumann, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 35C(5min) => 3C/min => 150C => 5C/min => 250C (10min) |
Capillary | DB-FFAP | 1148. | Schuh and Schieberle, 2005 | 30. m/0.32 mm/0.25 μm; Program: 40C(2min) => 6C/min => 150C => 20C/min => 230C |
Capillary | DB-Wax | 1121. | Zheng, Kim, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 40 (5min) => 4C/min => 140C => 4C/min => 200C (20min) |
Capillary | DB-Wax | 1125. | Zheng, Kim, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 40 (5min) => 4C/min => 140C => 4C/min => 200C (20min) |
Capillary | Stabilwax | 1160. | Klesk, Qian, et al., 2004 | 30. m/0.32 mm/1. μm, He; Program: 40C (2min) => 5C/min => 100C => 4C/min => 230C (10min) |
Capillary | HP-FFAP | 1146. | Carrapiso, Ventanas, et al., 2002 | 30. m/0.32 mm/0.25 μm; Program: 35C(5min) => 10C/min => 150C => 20C/min => 250C(10 min) |
Capillary | FFAP | 1132. | Steinhaus and Schieberle, 2000 | He; Column length: 25. m; Column diameter: 0.32 mm; Program: 35C (2min) => 40C/min => 60C (2min) => 6C/min => 180C => 10C/min => 240C |
Capillary | FFAP | 1135. | Buettner and Schieberle, 1999 | 30. m/0.32 mm/0.25 μm, He; Program: 35C (2min) => 40C/min => 60C (2min) => 6C/min => 180C => 10C/min => 230C (10min) |
Capillary | FFAP | 1147. | Derail, Hofmann, et al., 1999 | 30. m/0.32 mm/0.25 μm, He; Program: 35C (2min) => 40C/min => 60C => 4C/min => 230C (10min) |
Capillary | FFAP | 1135. | Hinterholzer, Lemos, et al., 1998 | 30. m/0.32 mm/0.25 μm, He; Program: 35C(2min) => 40C/min => 60C(2min) => 6C/min => 180C => 10C/min => 230C(10 min) |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | RTX-5Sil | 802. | Holland, Larkov, et al., 2005 | 30. m/0.25 mm/0.25 μm, He, 45. C @ 5. min, 3. K/min; Tend: 200. C |
Capillary | SE-54 | 799. | Kilic, Hafizoglu, et al., 2004 | 30. m/0.25 mm/0.25 μm, He, 60. C @ 5. min, 2. K/min; Tend: 260. C |
Capillary | SE-54 | 796. | Kilic, Hafizoglu, et al., 2004 | 30. m/0.053 mm/1.5 μm, He, 5. K/min; Tstart: 100. C; Tend: 250. C |
Capillary | HP-5 | 802. | Darriet, Pons, et al., 2002 | 30. m/0.32 mm/0.25 μm, H2, 45. C @ 1. min, 3. K/min, 230. C @ 10. min |
Capillary | DB-5 | 797. | Lin, Rouseff, et al., 2002 | 30. m/0.32 mm/0.25 μm, He, 7. K/min; Tstart: 40. C; Tend: 290. C |
Capillary | OV-101 | 834. | Yang, 2001 | N2, 2. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 80. C; Tend: 200. C |
Capillary | DB-5 | 798. | Schlüter, Steinhart, et al., 1999 | 34. C @ 3. min, 5. K/min, 200. C @ 10. min; Phase thickness: 0.25 μm |
Capillary | Optima 1 | 829. | Fons, Rapior, et al., 1998 | 25. m/0.20 mm/0.25 μm, Helium, 3. K/min; Tstart: 50. C; Tend: 200. C |
Capillary | SE-54 | 800. | Milo and Grosch, 1996 | 30. m/0.52 mm/1.5 μm, 6. K/min; Tstart: 5. C; Tend: 230. C |
Capillary | SE-54 | 800. | Milo and Grosch, 1996 | 30. m/0.52 mm/1.5 μm, 6. K/min; Tstart: 5. C; Tend: 230. C |
Capillary | OV-101 | 770. | Roberts and Acree, 1996 | 35. C @ 3. min, 6. K/min; Column length: 12. m; Column diameter: 0.32 mm; Tend: 225. C |
Capillary | OV-101 | 770. | Roberts and Acree, 1996 | 35. C @ 3. min, 6. K/min; Column length: 12. m; Column diameter: 0.32 mm; Tend: 225. C |
Capillary | SPB-1 | 766. | Wong and Lai, 1996 | 50. m/0.2 mm/0.33 μm, He, 40. C @ 3. min, 3. K/min, 200. C @ 30. min |
Capillary | RTX-5 | 800. | Milo and Grosch, 1995 | 30. m/0.52 mm/1.5 μm, He, 6. K/min; Tstart: 5. C; Tend: 230. C |
Capillary | DB-1 | 769. | Hansen, Buttery, et al., 1992 | 30. C @ 25. min, 4. K/min, 200. C @ 20. min; Column length: 60. m; Column diameter: 0.32 mm |
Capillary | DB-1 | 765. | Buttery, Teranishi, et al., 1990 | He, 30. C @ 25. min, 4. K/min, 200. C @ 5. min; Column length: 60. m; Column diameter: 0.25 mm |
Capillary | DB-1 | 769. | Engel, Flath, et al., 1988 | 60. m/0.315 mm/0.25 μm, He, 4. K/min; Tstart: 50. C; Tend: 250. C |
Capillary | OV-1 | 834. | Wu, Liou, et al., 1987 | Hydrogen, 1. K/min, 200. C @ 35. min; Column length: 50. m; Column diameter: 0.20 mm; Tstart: 50. C |
Capillary | OV-3 | 820. | Buttery, Xu, et al., 1985 | 1. K/min; Column length: 150. m; Column diameter: 0.66 mm; Tstart: 20. C; Tend: 170. C |
Capillary | DB-1 | 779. | Habu, Flath, et al., 1985 | 3. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tstart: 0. C; Tend: 250. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-1 | 775. | Delort and Jaquier, 2009 | 60. m/0.25 mm/0.25 μm, Helium; Program: 50 0C (5 min) 3 0C/min -> 120 0C 5 0C/min -> 250 0C (3 min) 15 0C/min -> 300 0C (20 min) |
Capillary | DB-5 | 800. | Greger and Schieberle, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: 40C(1min) => 7C/min => 110C => 5C/min => 180C => 10C/min => 240C(10min) |
Capillary | HP-5MS | 800. | Mallia, Escher, et al., 2007 | Program: not specified |
Capillary | 5 % Phenyl methyl siloxane | 799. | Beaulieu J.C. and Lea J.M., 2006 | 30. m/0.25 mm/0.75 μm; Program: 50C(1min) => 5C/min => 100C => 10C/min => 190C => 30C/min => 250C(1min) |
Capillary | DB-5 | 796. | Beaulieu, 2005 | 60. m/0.25 mm/0.25 μm; Program: 50C => 5C/min => 100C => 15C/min => 250C (19C) |
Capillary | HP-5 | 803. | Himanen, Vuorinen, et al., 2005 | 50. m/0.2 mm/0.5 μm, He; Program: 40C(1min) => 5C/min => 210C => 20C/min => 250C(8min) |
Capillary | CP-Sil5 CB MS | 764. | Iraqi, Vermeulen, et al., 2005 | 50. m/0.32 mm/1.2 μm; Program: 36C(2min) => 20C/min => 85C => 1C/min => 145C => 3C/min => 250C(30min) |
Capillary | SE-54 | 798. | Buettner, Mestres, et al., 2003 | 30. m/0.32 mm/0.25 μm; Program: 35C (2min) => 40C/min => 50C (2min) => 6C/min => 180C => 10C/min => 230C (10min) |
Capillary | DB-5 | 800. | Triqui and Bouchriti, 2003 | 30. m/0.3 mm/0.25 μm, H2; Program: 35C (1min) => 40C/min => 60C (5min) => 4C/min => 240C |
Capillary | SF-96 | 773. | Kawasaki, Matsui, et al., 1998 | Column length: 40. m; Column diameter: 0.28 mm; Program: 75C => 3C/min => 190C(25min) => 3C/min => 210C |
Capillary | RTX-5 | 800. | Masanetz and Grosch, 1998 | 30. m/0.53 mm/1.5 μm, He; Program: 35 0C (2 min) 40 0C/min -> 60 0C (1 min) 6 0C/min -> 230 0C |
Capillary | RTX-5 | 800. | Masanetz, Guth, et al., 1998 | Program: not specified |
Capillary | RTX-5 | 800. | Masanetz, Guth, et al., 1998 | Program: not specified |
Capillary | SE-54 | 800. | Reiners and Grosch, 1998 | 30. m/0.32 mm/0.25 μm; Program: 35 0C (2 min) 40 0C/min -> 50 0C (1 min) 6 0C/min -> 230 0C |
Capillary | SE-54 | 800. | Milo and Grosch, 1993 | He; Column length: 30. m; Column diameter: 0.32 mm; Program: 40 0C -> (unknowm rate) 50 0C (2 min) 6 0C/min -> 200 0C |
Capillary | SE-54 | 800. | Schieberle, Ofner, et al., 1990 | 30. m/0.32 mm/0.20 μm; Program: 2 min at 35 0C; 35-50 0C at 40 deg/min; 5 min at 50 0C; 50 - 220 0C at 4 deg/min; |
Normal alkane RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP Wax 52 CB | 1154. | Birtic, Ginies, et al., 2009 | 30. m/0.32 mm/0.50 μm, Helium, 40. C @ 2. min, 4. K/min, 230. C @ 15. min |
Capillary | TC-WAX | 1149. | Miyazawa, Tomita, et al., 2009 | Helium, 40. C @ 3. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 230. C |
Capillary | DB-Wax | 1148. | Kishimoto, Wanikawa, et al., 2006 | 15. m/0.32 mm/0.25 μm, He, 6. K/min, 230. C @ 20. min; Tstart: 40. C |
Capillary | DB-Wax | 1138. | Dregus and Engel, 2003 | 60. m/0.32 mm/0.25 μm, H2, 40. C @ 5. min, 4. K/min, 230. C @ 25. min |
Capillary | DB-Wax | 1158. | López, Ortín, et al., 2003 | 30. m/0.32 mm/0.5 μm, H2, 40. C @ 5. min, 4. K/min; Tend: 200. C |
Capillary | Supelcowax-10 | 1137. | Vichi, Castellote, et al., 2003 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 10. min, 3. K/min; Tend: 200. C |
Capillary | Supelcowax-10 | 1133. | Vichi, Pizzale, et al., 2003 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 10. min, 3. K/min; Tend: 200. C |
Capillary | BP-20 | 1126. | Darriet, Pons, et al., 2002 | 50. m/0.25 mm/0.25 μm, H2, 45. C @ 1. min, 3. K/min, 230. C @ 10. min |
Capillary | DB-Wax | 1147. | Lin, Rouseff, et al., 2002 | 30. m/0.32 mm/0.5 μm, He, 7. K/min, 240. C @ 5. min; Tstart: 40. C |
Capillary | DB-Wax | 1130. | Umano, Hagi, et al., 2002 | 60. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 2. K/min; Tend: 200. C |
Capillary | EC-1000 | 1160. | Bendall, 2001 | 30. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 5. K/min, 230. C @ 15. min |
Capillary | DB-Wax | 1114. | Weckerle, Bastl-Borrmann, et al., 2001 | 30. m/0.25 mm/0.25 μm, He, 50. C @ 3. min, 4. K/min; Tend: 220. C |
Capillary | DB-Wax | 1134. | Morales, Duque, et al., 2000 | 25. m/0.25 mm/0.25 μm, He, 50. C @ 4. min, 4. K/min, 200. C @ 10. min |
Capillary | DB-Wax | 1138. | Morales, Duque, et al., 2000 | 25. m/0.25 mm/0.25 μm, He, 50. C @ 4. min, 4. K/min, 200. C @ 10. min |
Capillary | DB-Wax | 1139. | Paniandy, Chane-Ming, et al., 2000 | 60. m/0.32 mm/0.25 μm, Helium, 50. C @ 2. min, 5. K/min; Tend: 230. C |
Capillary | DB-Wax | 1161. | Schlüter, Steinhart, et al., 1999 | 60. m/0.32 mm/0.5 μm, He, 34. C @ 3. min, 5. K/min, 200. C @ 10. min |
Capillary | DB-Wax | 1131. | Schlüter, Steinhart, et al., 1999 | 60. m/0.32 mm/0.25 μm, He, 34. C @ 3. min, 5. K/min, 200. C @ 10. min |
Capillary | DB-Wax | 1139. | Umano, Nakahara, et al., 1999 | 60. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 2. K/min; Tend: 200. C |
Capillary | DB-Wax | 1131. | Horiuchi, Umano, et al., 1998 | 60. m/0.25 mm/1. μm, He, 3. K/min, 200. C @ 40. min; Tstart: 50. C |
Capillary | DB-Wax | 1135. | Ravichandran and Parthiban, 1998 | 60. m/0.25 mm/0.25 μm, 2. K/min; Tstart: 50. C; Tend: 230. C |
Capillary | DB-Wax | 1135. | Werkhoff, Güntert, et al., 1998 | 60. m/0.32 mm/0.25 μm, H2, 3. K/min; Tstart: 60. C; Tend: 220. C |
Capillary | HP-Innowax | 1147. | Ulrich, Hoberg, et al., 1997 | 60. m/0.32 mm/0.5 μm, H2, 1.5 K/min; Tstart: 50. C; Tend: 180. C |
Capillary | Carbowax 20M | 1145. | Roberts and Acree, 1996 | 50. C @ 3. min, 6. K/min; Column length: 15. m; Column diameter: 0.32 mm; Tend: 225. C |
Capillary | Supelcowax-10 | 1146. | Wong and Lai, 1996 | 60. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 3. K/min, 200. C @ 30. min |
Capillary | DB-Wax | 1138. | Takeoka and Butter, 1989 | 60. m/0.32 mm/0.25 μm, He, 30. C @ 4. min, 2. K/min; Tend: 180. C |
Capillary | DB-Wax | 1138. | Takeoka and Butter, 1989 | 60. m/0.32 mm/0.25 μm, He, 30. C @ 4. min, 2. K/min; Tend: 180. C |
Capillary | DB-Wax | 1145. | Takeoka and Butter, 1989 | 60. m/0.32 mm/0.25 μm, He, 30. C @ 4. min, 2. K/min; Tend: 180. C |
Capillary | DB-Wax | 1145. | Takeoka and Butter, 1989 | 60. m/0.32 mm/0.25 μm, He, 30. C @ 4. min, 2. K/min; Tend: 180. C |
Capillary | DB-Wax | 1138. | Engel, Flath, et al., 1988 | 60. m/0.322 mm/0.25 μm, He, 4. K/min; Tstart: 50. C; Tend: 230. C |
Capillary | DB-Wax | 1142. | Takeoka, Flath, et al., 1988 | 60. m/0.25 mm/0.25 μm, H2, 30. C @ 2. min, 2. K/min; Tend: 180. C |
Capillary | DB-Wax | 1142. | Takeoka, Flath, et al., 1988 | 60. m/0.25 mm/0.25 μm, H2, 30. C @ 2. min, 2. K/min; Tend: 180. C |
Capillary | Carbowax 20M | 1176. | Wu, Liou, et al., 1987 | Hydrogen, 1. K/min, 200. C @ 35. min; Column length: 50. m; Column diameter: 0.20 mm; Tstart: 50. C |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-FFAP | 1144. | Greger and Schieberle, 2007 | 30. m/0.32 mm/0.25 μm, He; Program: 40C(1min) => 7C/min => 180C => 10C/min => 240C (10min) |
Capillary | Supelcowax-10 | 1115. | Vichi, Guadayol, et al., 2007 | 30. m/0.25 mm/0.25 μm, He; Program: 40C(3min) => 4C/min => 75C => 8C/min => 250C(5min) |
Capillary | DB-Wax | 1191. | Kim. J.H., Ahn, et al., 2004 | 60. m/0.25 mm/0.25 μm, Helium; Program: 60 0C (3 min) 2 0C/min -> 150 0C 4 0C/min -> 200 0C |
Capillary | FFAP | 1134. | Buettner, Mestres, et al., 2003 | 30. m/0.32 mm/0.25 μm; Program: 35C (2min) => 40C/min => 60C (2min) => 6C/min => 180C => 10C/min => 230C (10min |
Capillary | DB-FFAP | 1145. | Triqui and Bouchriti, 2003 | 30. m/0.3 mm/0.25 μm, H2; Program: 35C (1min) => 40C/min => 60C (5min) => 4C/min => 220C |
Capillary | FFAP | 1135. | Buettner and Schieberle, 2001 | 30. m/0.32 mm/0.25 μm, He; Program: 35C (2min) => 40C/min => 60C (2min) => 6C/min => 180C => 10C/min => 230C (10min) |
Capillary | DB-Wax | 1142. | Paniandy, Chane-Ming, et al., 2000 | 60. m/0.32 mm/0.25 μm, Helium; Program: not specified |
Capillary | FFAP | 1140. | Reiners and Grosch, 1998 | 25. m/0.32 mm/0.3 μm; Program: 35C (2min) => 40C/min => 60C(1min) => 6C/min => 230C |
Capillary | CP-Wax 52CB | 1143. | Luning, Carey, et al., 1995 | Program: 40C => 2C/min => 150C => 10C/min => 250C |
Capillary | CP-Wax 52CB | 1147. | Luning, de Rijk, et al., 1994 | 50. m/0.32 mm/1.5 μm; Program: 40C => 2C/min => 150C => 10C/min => 250C |
Capillary | CP-Wax 52CB | 1147. | Luning, de Rijk, et al., 1994 | 50. m/0.32 mm/1.5 μm; Program: 40C => 2C/min => 150C => 10C/min => 250C |
Capillary | DB-Wax | 1145. | Milo and Grosch, 1993 | 30. m/0.25 mm/0.5 μm, He; Program: 35C => 40C/min => 50C(2min) => 6C/min => 200C |
Capillary | CP-Wax 52CB | 1120. | Vernin, 1991 | Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Fuhrmann and Grosch, 2002
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Steinhaus and Schieberle, 2000
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Comparison of the most odor-active compounds in fresh and dried hop cones (Humulus lupulus L. variety Spalter Select) based on GC-olfactometry and odor dilution techniques,
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Buettner and Schieberle, 1999
Buettner, A.; Schieberle, P.,
Characterization of the most odor-active volatiles in fresh, hand squeezed juice of grapefruit (Citrus paradise Macfayden),
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Derail, Hofmann, et al., 1999
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Hinterholzer and Schieberie, 1998
Hinterholzer, A.; Schieberie, P.,
Identification of the most odour-active volatiles in fresh, hand-extracted juice of valencia late oranges by odour dilution techniques,
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Heiler and Schieberle, 1997
Heiler, C.; Schieberle, P.,
Model studies on the precursors and formation of the metallic smelling (E,Z)-2,6-nonadienol during the manufacture and storage of buttermilk,
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Ullrich and Grosch, 1988
Ullrich, F.; Grosch, W.,
Identification of the most intense odor compounds formed during autoxidation of methyl linolenate at room temperature,
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Comparison of odour active compounds detected by gas-chromatography-olfactometry between hand-squeezed juices from different orange varieties,
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Aubert C. and Pitrat M., 2006
Aubert C.; Pitrat M.,
Volatile compounds in the skin and pulp of Queen Anne's pocket melon,
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Ménager, I.; Jost, M.; Aubert, C.,
Changes in physicochemical characteristics and volatile constituents of strawberry (Cv. Cigaline) during maturation,
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Suárez and Duque, 1992
Suárez, M.; Duque, C.,
Change in volatile compounds during lulo (Solanum vestissimum D.) fruit maturation,
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Suárez and Duque, 1991
Suárez, M.; Duque, C.,
Volatile constituents of lulo (Salanum vestissimum D.) fruit,
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Aubert, Baumann, et al., 2005
Aubert, C.; Baumann, S.; Arguel, H.,
Optimization of the Analysis of Flavor Volatile Compounds by Liquid-Liquid Microextraction (LLME). Application to the Aroma Analysis of Melons, Peaches, Grapes, Strawberries, and Tomatoes,
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Schuh and Schieberle, 2005
Schuh, C.; Schieberle, P.,
Characterization of ( E, E, Z)-2,4,6-Nonatrienal as a character impact aroma compound of oat flakes,
J. Agric. Food Chem., 2005, 53, 22, 8699-8705, https://doi.org/10.1021/jf051601i
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Klesk, Qian, et al., 2004
Klesk, K.; Qian, M.; Martin, R.R.,
Aroma extract dilution analysis of cv. meeker (Rubus idaeus L.) red raspberries from Oregon and Washington,
J. Agric. Food Chem., 2004, 52, 16, 5155-5161, https://doi.org/10.1021/jf0498721
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Holland, Larkov, et al., 2005
Holland, D.; Larkov, O.; Bar-Ya'akov, I.; Bar, E.; Zax, A.; Brandeis, E.; Ravid, U.; Lewinsohn, E.,
Developmental and varietal differences in volatile ester formation and acetyl-CoA: alcohol acetyl transferase activities in apple (Malus domestica Borkh.) fruit,
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Kilic, Hafizoglu, et al., 2004
Kilic, A.; Hafizoglu, H.; Kollmannsberger, H.; Nitz, S.,
Volatile constituents and key odorants in leaves, buds, flowers, and fruits of Laurus nobilis L.,
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Darriet, Pons, et al., 2002
Darriet, P.; Pons, M.; Henry, R.; Dumont, O.; Findeling, V.; Cartolaro, P.; Calonnec, A.; Dubourdieu, D.,
Impact odorants contributing to the fungus type aroma from grape berries contaminated by powdery mildew (Uncinula necator); incidence of enzymatic activities of the yeast Saccharomyces cerevisiae,
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Lin, Rouseff, et al., 2002
Lin, J.; Rouseff, R.L.; Barros, S.; Naim, M.,
Aroma composition changes in early season grapefruit juice produced from thermal concentration,
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Yang, 2001
Yang, R.,
Volatile compounds in peel oil of Citrus sudachi,
Food Sci. (Beijing), 2001, 22, 3, 71-73. [all data]
Schlüter, Steinhart, et al., 1999
Schlüter, S.; Steinhart, H.; Schwarz, F.J.; Kirchgessner, M.,
Changes in the odorants of boiled carp fillet (Cyprinus carpio L.) as affected by increasing methionine levels in feed,
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Fons, Rapior, et al., 1998
Fons, F.; Rapior, S.; Gargadennec, A.; Andary, C.; Bessiere, J.-M.,
Volatile components of Plantago lanceolata (Plantaginaceae),
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Milo and Grosch, 1996
Milo, C.; Grosch, W.,
Changes in the odorants of boiled salmon and cod as affected by the storage of the raw material,
J. Agric. Food Chem., 1996, 44, 8, 2366-2371, https://doi.org/10.1021/jf9507203
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Roberts and Acree, 1996
Roberts, D.D.; Acree, T.E.,
Effects of heating and cream addition on fresh raspberry aroma using a retronasal aroma simulator and gas chromatography olfactometry,
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Wong and Lai, 1996
Wong, K.C.; Lai, F.Y.,
Volatile constituents from the fruits of four Syzygium species grown in Malaysia,
Flavour Fragr. J., 1996, 11, 1, 61-66, https://doi.org/10.1002/(SICI)1099-1026(199601)11:1<61::AID-FFJ539>3.0.CO;2-1
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Milo and Grosch, 1995
Milo, C.; Grosch, W.,
Detection of odor defects in boiled cod and trout by gas chromatography-olfactometry of headspace samples,
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Hansen, Buttery, et al., 1992
Hansen, M.; Buttery, R.G.; Stern, D.J.; Cantwell, M.I.; Ling, L.C.,
Broccoli storage under low-oxygen atmosphere: Identification of higher boiling volatiles,
J. Agric. Food Chem., 1992, 40, 5, 850-852, https://doi.org/10.1021/jf00017a029
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Buttery, Teranishi, et al., 1990
Buttery, R.G.; Teranishi, R.; Ling, L.C.; Turnbaugh, J.G.,
Quantitative and sensory studies on tomato paste volatiles,
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Engel, Flath, et al., 1988
Engel, K.-H.; Flath, R.A.; Buttery, R.G.; Mon, T.R.; Ramming, D.W.; Teranishi, R.,
Investigation of volatile constituents in nectarines. 1. Analytical and sensory characterization of aroma components in some nectarine cultivars,
J. Agric. Food Chem., 1988, 36, 3, 549-553, https://doi.org/10.1021/jf00081a036
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Wu, Liou, et al., 1987
Wu, C.-M.; Liou, S.-E.; Chang, Y.-H.; Chiang, W.,
Volatile compounds of the wax gourd (Benincasa hispida, Cogn) and a wax gourd beverage,
J. Food Sci., 1987, 52, 1, 132-134, https://doi.org/10.1111/j.1365-2621.1987.tb13988.x
. [all data]
Buttery, Xu, et al., 1985
Buttery, R.G.; Xu, C.; Ling, L.C.,
Volatile components of wheat leaves (and stems): Possible insect attractants,
J. Agric. Food Chem., 1985, 33, 1, 115-117, https://doi.org/10.1021/jf00061a033
. [all data]
Habu, Flath, et al., 1985
Habu, T.; Flath, R.A.; Mon, T.R.; Morton, J.F.,
Volatile components of Rooibos tea (Aspalathus linearis),
J. Agric. Food Chem., 1985, 33, 2, 249-254, https://doi.org/10.1021/jf00062a024
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Delort and Jaquier, 2009
Delort, E.; Jaquier, A.,
Novel terpenyl esters from Australian finger lime (Citrus australasica) peel extract,
Flav. Fragr. J., 2009, 24, 3, 123-132, https://doi.org/10.1002/ffj.1922
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Greger and Schieberle, 2007
Greger, V.; Schieberle, P.,
Characterization of the Key Aroma Compounds in Apricots (Prunus armeniaca) by Application of the Molecular Sensory Science Concept,
J. Agric. Food Chem., 2007, 55, 13, 5221-5228, https://doi.org/10.1021/jf0705015
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Mallia, Escher, et al., 2007
Mallia, S.; Escher, F.; Rehberger, B.; Schlichtherle-Cerny, H.,
Aroma-active secondary oxidation products of butter, 3rd QLIF Congress, Hohenheim, Germany, March 20-23, 2007, 2007, retrieved from http://orgprints.org/view/projects/intconfqlif2007.html; http://orgprints.org/9734/. [all data]
Beaulieu J.C. and Lea J.M., 2006
Beaulieu J.C.; Lea J.M.,
Characterization and semiquantitative analysis of volatiles in seedless watermelon varieties using solid-phase microextraction,
J. Agric. Food Chem., 2006, 54, 20, 7789-7793, https://doi.org/10.1021/jf060663l
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Beaulieu, 2005
Beaulieu, J.C.,
Within-Season Volatile and Quality Differences in Stored Fresh-Cut Cantaloupe Cultivars,
J. Agric. Food Chem., 2005, 53, 22, 8679-8687, https://doi.org/10.1021/jf050241w
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Himanen, Vuorinen, et al., 2005
Himanen, S.; Vuorinen, T.; Tuovinen, T.; Holopainen, J.K.,
Effects of Cyclamen Mite (Phytonemus pallidus) and Leaf Beetle (Galerucella tenella) Damage on Volatile Emission from Strawberry (Fragaria ´ ananassa Duch.) Plants and Orientation of Predatory Mites (Neoseiulus cucumeris, N. californicus, and Euseius finlandicus),
J. Agric. Food Chem., 2005, 53, 8624-8630. [all data]
Iraqi, Vermeulen, et al., 2005
Iraqi, R.; Vermeulen, C.; Benzekri, A.; Bouseta, A.; Collin, S.,
Screening for key odorants in Moroccan green olives by gas chromatography-olfactometry/aroma extract dilution analysis,
J. Agric. Food Chem., 2005, 53, 4, 1179-1184, https://doi.org/10.1021/jf040349w
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Buettner, Mestres, et al., 2003
Buettner, A.; Mestres, M.; Fischer, A.; Guasch, J.; Schieberle, P.,
Evaluation of the most odour-active compounds in the peel oil of clementines ( citrus reticulata blanco cv. clementine),
Eur. Food Res. Technol., 2003, 216, 11-14. [all data]
Triqui and Bouchriti, 2003
Triqui, R.; Bouchriti, N.,
Freshness assessments of Moroccan sardine (Sardina pilchardus): comparison of overall sensory changes to instrumentally determined volatiles,
J. Agric. Food Chem., 2003, 51, 26, 7540-7546, https://doi.org/10.1021/jf0348166
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Kawasaki, Matsui, et al., 1998
Kawasaki, W.; Matsui, K.; Akakabe, Y.; Itai, N.; Kajiwara, T.,
Long-chain aldehyde-forming activity in tobacco leaves,
Phytochemistry, 1998, 49, 6, 1565-1568, https://doi.org/10.1016/S0031-9422(98)00236-2
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Masanetz and Grosch, 1998
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Changes in the odorants of boiled trout (Salmo fario) as affected by the storage of the raw material,
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Schieberle, Ofner, et al., 1990
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Kishimoto, Wanikawa, et al., 2006
Kishimoto, T.; Wanikawa, A.; Kono, K.; Shibata, K.,
Comparison of the Odor-Active Compounds in Unhopped Beer and Beers Hopped with Different Hop Varieties,
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Dregus, M.; Engel, K.-H.,
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Umano, Hagi, et al., 2002
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Bendall, 2001
Bendall, J.G.,
Aroma compounds of fresh milk from New Zealand cows fed different diets,
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Morales, Duque, et al., 2000
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Paniandy, J.-C.; Chane-Ming, J.; Pierbattesti, J.-C.,
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Buettner, A.; Schieberle, P.,
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Characterization and occurrence of lipoxygenase in bell peppers at different ripening stages in relation to the formation of volatile flavor compounds,
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Vernin, G.,
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Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
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