6β-Hydroxymethandienone, 2TMS derivative
- Formula: C26H44O3Si2
- Molecular weight: 460.7968
- IUPAC Standard InChI: InChI=1S/C26H44O3Si2/c1-24-13-10-18(27)16-22(24)23(28-30(4,5)6)17-19-20(24)11-14-25(2)21(19)12-15-26(25,3)29-31(7,8)9/h10,13,16,19-21,23H,11-12,14-15,17H2,1-9H3
- IUPAC Standard InChIKey: RAKGZQRFODNUHY-UHFFFAOYSA-N
- CAS Registry Number: 67896-65-5
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: 17α-Methyl-6β,17β-dihydroxy-1,4-androstadien-3-one, bis(trimethylsilyl); 17-Methyl-6,17-bis[(trimethylsilyl)oxy]androsta-1,4-dien-3-one, (6β,17β)-; 6-β-Hydroxymetandienone, per-TMS; 6β-Hydroxy-Methandienone, bis-TMS; 6B-Hydroxymetandienone (Androst-1,4-dien-17A-methyl-6B,17B-diol-3-one), TMS; Hydrastine, bis(trimethylsilyl) ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 2919. | Schänzer, Opfermann, et al., 1992 | 5. K/min; Column length: 17. m; Phase thickness: 0.33 μm; Tstart: 200. C; Tend: 320. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2915. | Bowers, 1996 | 30. m/0.25 mm/0.25 μm, Helium; Program: 170 0C 20 0C/min -> 260 0C 2.7 0C/min -> 305 0C 20 0C/min -> 320 0C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schänzer, Opfermann, et al., 1992
Schänzer, W.; Opfermann, G.; Donike, M.,
17-Epimerization of 17α-methyl anabolic steroids in humans: metabolism and synthesis of 17α-hydroxy-17β-methyl steroids,
Steroids, 1992, 57, 11, 537-550, https://doi.org/10.1016/0039-128X(92)90023-3
. [all data]
Bowers, 1996
Bowers, L.D.,
Separation and confirmation of anabolic steroids with quadrupole ion trap tandem mass spectrometry,
J. Chromatogr. B, 1996, 687, 1, 69-78, https://doi.org/10.1016/S0378-4347(96)00231-9
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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