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3,3,3-Trifluoropropene

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.95ESTTakhistov and Ponomarev, 1994LL
11.24 ± 0.04EISteele and Stone, 1962RDSH
10.9PIBralsford, Harris, et al., 1960RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CF3+15.0 ± 0.2?EISteele and Stone, 1962RDSH
CHF2+14.9 ± 0.1?EISteele and Stone, 1962RDSH
C2H2+13.3 ± 0.15?EISteele and Stone, 1962RDSH
C2H3+14.20 ± 0.05?EISteele and Stone, 1962RDSH
C2H3F+13.85 ± 0.02?EISteele and Stone, 1962RDSH
C3HF2+14.8 ± 0.2?EISteele and Stone, 1962RDSH
C3H2F2+13.8 ± 0.1?EISteele and Stone, 1962RDSH
C3H2F3+12.69 ± 0.05HEISteele and Stone, 1962RDSH
C3H3F2+13.3 ± 0.15?EISteele and Stone, 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Takhistov and Ponomarev, 1994
Takhistov, V.V.; Ponomarev, D.A., Isodesmic reactions and thermochemistry of ions, Org. Mass Spectrom., 1994, 29, 395. [all data]

Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A., An electron impact study of 1,1,1-trifluoroethane, 1,1,1-trifluoropropane and 3,3,3-trifluoropropene, J. Am. Chem. Soc., 1962, 84, 3450. [all data]

Bralsford, Harris, et al., 1960
Bralsford, R.; Harris, P.V.; Price, W.C., The effect of fluorine on the electronic spectra and ionization potentials of molecules, Proc. Roy. Soc. (London), 1960, A258, 459. [all data]


Notes

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