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Dimethyl Sulfoxide

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-203.4 ± 1.4kJ/molCcrMasuda, Nagano, et al., 1994H2SO4 (1:115 H2O); ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2037.3 ± 1.3kJ/molCcrMasuda, Nagano, et al., 1994H2SO4 (1:115 H2O); ALS
Quantity Value Units Method Reference Comment
liquid188.78J/mol*KN/AClever and Westrum, 1970DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
149.39298.15Grolier, Roux-Desgranges, et al., 1993DH
148.28298.15Barta, Kooner, et al., 1989DH
153.6298.15Rodante and Marrosu, 1988DH
153.2298.15Lankford and Criss, 1987DH
155.9298.15de Visser and Somsen, 1979DH
155.9298.15De Visser, Heuvelsland, et al., 1978DH
153.18298.15Clever and Westrum, 1970T = 5 to 350 K.; DH
149.0298.15Kenttmaa and Lindberg, 1960T = 298, 343 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Masuda, Nagano, et al., 1994
Masuda, N.; Nagano, Y.; Sakiyama, M., Standard molar enthalpy of formation of (CH3)2SO, dimethylsulfoxide, by combustion calorimetry, J. Chem. Thermodyn., 1994, 26, 971-975. [all data]

Clever and Westrum, 1970
Clever, H.L.; Westrum, E.F., Jr., Dimethylsulfoxide and dimethylsulfone. Heat capacities, enthalpies of fusion, and thermodynamic properties, J. Phys. Chem., 1970, 74, 1309-1317. [all data]

Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide, J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]

Barta, Kooner, et al., 1989
Barta, L.; Kooner, Z.S.; Hepler, L.G.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermal and volumetric properties of chloroform dimethylsulfoxide: Thermodynamic analysis using the ideal associated solution model, J. Solution Chem., 1989, 18(7), 663-673. [all data]

Rodante and Marrosu, 1988
Rodante, F.; Marrosu, G., Excess molar isobaric heat capacities and excess molar enthalpies for water-dimethylsulfoxide mixtures at 25°C, Thermochim. Acta, 1988, 136, 209-218. [all data]

Lankford and Criss, 1987
Lankford, J.I.; Criss, C.M., Partial molar heat caqpacities of selected electrolytes and benzene in methanol and dimethyldulfoxide at 25, 40 and 80°C, J. Solution Chem., 1987, 16(11), 885-906. [all data]

de Visser and Somsen, 1979
de Visser, C.; Somsen, G., Thermochemical behavior of mixtures of N,N-dimethylformamide with dimethylsulfoxide, acetonitrile, and N-methylformamide: volumes and heat capacities, J. Solution Chem., 1979, 8, 593-600. [all data]

De Visser, Heuvelsland, et al., 1978
De Visser, C.; Heuvelsland, W.J.M.; Dunn, L.A.; Somsen, G., Some properties of binary aqueous liquid mixtures, J. Chem. Soc., Faraday Trans.1, 1978, 74, 1159-1169. [all data]

Kenttmaa and Lindberg, 1960
Kenttmaa, J.; Lindberg, J.J., Volumes and heats of mixing of dimethyl sulfoxide-water solutions, Suom. Kemistilehti, 1960, B33, 32-35. [all data]


Notes

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