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Methyl Alcohol

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Critical temperature

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Tc (K) Reference Comment
512.5 ± 0.2Gude and Teja, 1995 
512.5Lydersen and Tsochev, 1990TRC
512.64Teja, Lee, et al., 1989TRC
512.47Brunner, 1988Uncertainty assigned by TRC = 0.1 K; Visual, optical cell 30cm high. TE cal. vs platinum resistance thermometer; TRC
512.5De Loos, Poot, et al., 1988TRC
512.64Craven and de Reuck, 1986TRC
512.6Majer and Svoboda, 1985 
512.5Francesconi, Lentz, et al., 1981Uncertainty assigned by TRC = 1. K; TRC
512.36Kay and Young, 1976Uncertainty assigned by TRC = 0.15 K; TRC
512.36Kay and Khera, 1975Uncertainty assigned by TRC = 0.2 K; TRC
512.36Kay and Young, 1975Uncertainty assigned by TRC = 0.2 K; TRC
514.7Marshall and Jones, 1974TRC
512.65Zubarev and Bagdonas, 1969Uncertainty assigned by TRC = 0.3 K; TRC
513.Efremov, 1966TRC
512.68Skaates and Kay, 1964TRC
513.15McCracken, Storvick, et al., 1960Uncertainty assigned by TRC = 2.77 K; TRC
513.9Mocharnyuk, 1960TRC
513.2Nozdrev, 1956TRC
505.2Golik, Ravikovich, et al., 1955TRC; Data excluded from overall average
512.60Kay and Donham, 1955TRC
513.8Fischer and Reichel, 1943TRC
513.2Salzwedel, 1930TRC
513.2Young, 1910TRC
513.4Centnerszwer, 1904Uncertainty assigned by TRC = 0.5 K; max. temp. of disappearance of meniscis for various fillings; TRC
514.35Kuenen, 1903Uncertainty assigned by TRC = 1. K; TRC
515.2Schmidt, 1891TRC
513.4Schmidt, 1891, 2TRC
536.De Heen, 1888TRC; Data excluded from overall average
513.2Ramsay and Young, 1887TRC
506.2Nadezhdin, 1883TRC; Data excluded from overall average
505.9Hannay, 1882TRC; Data excluded from overall average

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Critical temperature, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gude and Teja, 1995
Gude, M.; Teja, A.S., Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols, J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]

Lydersen and Tsochev, 1990
Lydersen, A.L.; Tsochev, V., Critical temperatures and pressures and high temperature vapour pressures of seven alcohols, Chem. Eng. Technol., 1990, 13, 125-30. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Brunner, 1988
Brunner, E., Fluid Mixtures at High Pressures VI. Phase Separation and Critical Phenomena in 18 (n-Alkane + Ammonia) and 4 (n-Alkane _ Methanol) Mixtures, J. Chem. Thermodyn., 1988, 20, 273. [all data]

De Loos, Poot, et al., 1988
De Loos, T.W.; Poot, W.; De Swaan Arons, J., Vapor-Liquid Equilibria and Critical Phenomena in Methanol + n-Alkane Systems, Fluid Phase Equilib., 1988, 42, 209. [all data]

Craven and de Reuck, 1986
Craven, R.J.B.; de Reuck, K.M., Ideal-Gas and Saturation Properties of Methanol, Int. J. Thermophys., 1986, 7, 541. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Francesconi, Lentz, et al., 1981
Francesconi, A.Z.; Lentz, H.; Franck, E.U., Phase Equilibriums and PVT Data for the Methane-Methanol System to 300 MPa and 240 degree C, J. Phys. Chem., 1981, 85, 3303. [all data]

Kay and Young, 1976
Kay, W.B.; Young, C.L., Gas-liquid critical properties. Diethylamine-methanol system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1976, No. 1, 74. [all data]

Kay and Khera, 1975
Kay, W.B.; Khera, R., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 1, 62. [all data]

Kay and Young, 1975
Kay, W.B.; Young, C.L., Gas-liquid critical properties. Ethanenitrile(acetonitrile)-methanol system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 1, 62. [all data]

Marshall and Jones, 1974
Marshall, W.L.; Jones, E.V., Liquid-Vapor Critical Temperatures of Several Aqueous-Organic and Organic- Organic Solution Systems, J. Inorg. Nucl. Chem., 1974, 36, 2319-23. [all data]

Zubarev and Bagdonas, 1969
Zubarev, V.N.; Bagdonas, A., Saturation Curve Properties and Specific Volumes of Methanol, Teploenergetika (Moscow), 1969, 16, 88-91. [all data]

Efremov, 1966
Efremov, Yu.V., Density, Surface Tension, Saturated Vapor Pressurs and Critical Parameters of Alcohols, Zh. Fiz. Khim., 1966, 40, 1240. [all data]

Skaates and Kay, 1964
Skaates, J.M.; Kay, W.B., The Phase Relations of Binary Systems that Form Azeotropes: N-Alkyl Alcohol-Benzene Systems: Methanol Through N-Butanol, Chem. Eng. Sci., 1964, 19, 431-44. [all data]

McCracken, Storvick, et al., 1960
McCracken, P.G.; Storvick, T.S.; Smith, J.M., Phase Behavior from Enthalpy Measurements. Oentane-Ethyl Alcohol and n-Pentane-Ethyl Alcohol Systems, J. Chem. Eng. Data, 1960, 5, 130-2. [all data]

Mocharnyuk, 1960
Mocharnyuk, R.F., Physicochemical investigation of solutions of certain monoatomic alcohols in acetone, Zh. Obshch. Khim., 1960, 30, 1098-102. [all data]

Nozdrev, 1956
Nozdrev, V.F., The problem of applying ultrasonic methods in the investigation of organic substances in the critical region, Akust. Zh., 1956, 2, 209-14. [all data]

Golik, Ravikovich, et al., 1955
Golik, A.Z.; Ravikovich, S.D.; Orishchenko, A.V., Viscosity and Molecular Struct. of Normal Alcohols and Their Solutions, Ukr. Khim. Zh. (Russ. Ed.), 1955, 21, 167. [all data]

Kay and Donham, 1955
Kay, W.B.; Donham, W.E., Liquid-Vapor Equilibrium in the Isobutyl Alcohol-Butanol, Methanol- Butanol, and Diethyl Ether-Butanol Systems, Chem. Eng. Sci., 1955, 4, 1-16. [all data]

Fischer and Reichel, 1943
Fischer, R.; Reichel, T., Determination of the Critical Temperature BY Means of the Micro Melting-Point Apparatus, Mikrochem. Ver. Mikrochim. Acta, 1943, 31, 102. [all data]

Salzwedel, 1930
Salzwedel, E., The Development of a Generally Valid Formula For the Temperature Dependence of the Specific Gravity of Homogeneous Liquids from Experiment and Questions in Connection with It., Ann. Phys. (Leipzig), 1930, 5, 853. [all data]

Young, 1910
Young, S., The Internal Heat of Vaporization constants of thirty pure substances, Sci. Proc. R. Dublin Soc., 1910, 12, 374. [all data]

Centnerszwer, 1904
Centnerszwer, M., An Application of the Method of Cailletet and Mathias to Determine Critical Volume., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1904, 49, 199. [all data]

Kuenen, 1903
Kuenen, J.P., On the Mutual Solubility of Liquids, Philos. Mag., 1903, 6, 637. [all data]

Schmidt, 1891
Schmidt, G.C., The Critical Temperature of Liquid Mixtures, Justus Liebigs Ann. Chem., 1891, 266, 266-92. [all data]

Schmidt, 1891, 2
Schmidt, G.C., Vapor Pressures of Homologous Compounds homologous series of fatty alcohols, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1891, 8, 628-46. [all data]

De Heen, 1888
De Heen, P., Research on Physics and Theory of Liquids, Experimental Part Paris, 1888. [all data]

Ramsay and Young, 1887
Ramsay, W.; Young, S., On evaporation and dissociation: V a study of thermal properties of methyl alcohol, Philos. Trans. R. Soc. London, A, 1887, 178, 313-34. [all data]

Nadezhdin, 1883
Nadezhdin, A., The Critical Point., Beibl. Ann. Phys., 1883, 7, 678-81. [all data]

Hannay, 1882
Hannay, J.B., On the limit of the liquid state, Proc. R. Soc. London, 1882, 33, 294. [all data]


Notes

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