Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Methyl Alcohol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-49. ± 3.kcal/molAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Deltacgas-182.52 ± 0.048kcal/molCmRossini, 1932Flame Calorimetry; Corresponding «DELTA»fgas = -48.157 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
8.12650.Thermodynamics Research Center, 1997p=1 bar. Recommended entropies and heat capacities are in good agreement with other statistically calculated values [ Ivash E.V., 1955, Zhuravlev E.Z., 1959, Chen S.S., 1977, Chao J., 1986, Gurvich, Veyts, et al., 1989]. Please also see Chao J., 1986, 2.; GT
8.831100.
9.235150.
9.491200.
10.18273.15
10.53 ± 0.007298.15
10.56300.
12.34400.
14.27500.
16.06600.
17.65700.
19.06800.
20.30900.
21.401000.
22.361100.
23.211200.
23.9581300.
24.6131400.
25.1911500.
26.341750.
27.202000.
27.842250.
28.352500.
28.72750.
28.93000.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
10.13 ± 0.30279.Stromsoe E., 1970Heat capacity at 279 K was obtained by thermal conductivity [ Halford J.O., 1957]. Vapor heat capacities from calorimetric measurements [ De Vries T., 1941] were converted to the ideal gas heat capacities by corrections for the gas imperfection effects [ Chen S.S., 1977, Chao J., 1986, 2]. Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1*(a+bT). This expression approximates the experimental values with the average deviation of 1.17 J/mol*K. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see De Vries T., 1941, Weltner W., 1951, Halford J.O., 1957.; GT
11.46 ± 0.30345.6
11.19 ± 0.28347.35
11.01 ± 0.30349.65
11.37 ± 0.28356.55
11.17 ± 0.30358.15
11.52 ± 0.30358.85
11.67 ± 0.30359.85
12.02 ± 0.30368.15
11.71 ± 0.28373.35
12.26 ± 0.30382.15
12.22 ± 0.28398.95
12.51 ± 0.30401.15
12.27 ± 0.28401.35
12.43 ± 0.10403.2
12.72 ± 0.30420.15
12.88 ± 0.28431.45
13.09 ± 0.28442.15
13.36 ± 0.30442.65
13.39 ± 0.28457.35
13.67 ± 0.10464.0
13.80 ± 0.28477.75
13.95 ± 0.28485.05
14.23 ± 0.28498.95
14.44 ± 0.30521.2
14.68 ± 0.28521.35
15.37 ± 0.28555.95
15.88 ± 0.28581.35
15.96 ± 0.28585.35

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-56.97kcal/molCcrBaroody and Carpenter, 1972ALS
Deltafliquid-57.24 ± 0.04kcal/molCcbChao and Rossini, 1965see Rossini, 1934; ALS
Deltafliquid-57.10 ± 0.86kcal/molCcbGreen, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -57.01 ± 0.05 kcal/mol; ALS
Deltafliquid-59.89kcal/molCcbParks, 1925ALS
Deltafliquid-60.1 ± 1.2kcal/molCcbRichards and Davis, 1920DRB
Quantity Value Units Method Reference Comment
Deltacliquid-173.45 ± 0.03kcal/molCcbChao and Rossini, 1965see Rossini, 1934; Corresponding «DELTA»fliquid = -57.23 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-173.64 ± 0.05kcal/molCcbGreen, 1960Corresponding «DELTA»fliquid = -57.04 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-173.60 ± 0.048kcal/molCcbRossini, 1931Corresponding «DELTA»fliquid = -57.082 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-170.90kcal/molCcbParks, 1925Corresponding «DELTA»fliquid = -59.78 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-170.61kcal/molCcbRichards and Davis, 1920At 291 K; Corresponding «DELTA»fliquid = -60.072 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid30.399cal/mol*KN/ACarlson and Westrum, 1971DH
liquid30.31cal/mol*KN/AKelley, 1929DH
liquid31.00cal/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 34.3 J/mol*K. Revision of previous data.; DH
liquid32.60cal/mol*KN/AParks, 1925Extrapolation below 90 K, 40.75 J/mol*K.; DH
Quantity Value Units Method Reference Comment
solid,1 bar0.2670cal/mol*KN/AAhlberg, Blanchard, et al., 1937DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
19.0298.15Filatov and Afanas'ev, 1992DH
19.39298.15Khasanshin and Zykova, 1989T = 175 to 338 K. Unsmoothed experimental datum.; DH
19.18298.15Andreoli-Ball, Patterson, et al., 1988DH
19.20298.15Okano, Ogawa, et al., 1988DH
19.4298.15Lankford and Criss, 1987DH
19.44298.Korolev, Kukharenko, et al., 1986DH
19.19298.15Ogawa and Murakami, 1986DH
19.49298.15Tanaka, Toyama, et al., 1986DH
19.17298.15Costas and Patterson, 1985T = 298.15, 313.15 K.; DH
19.47298.15Zegers and Somsen, 1984DH
18.86288.15Benson and D'Arcy, 1982DH
19.58298.15Villamanan, Casanova, et al., 1982DH
19.3293.15Atalla, El-Sharkawy, et al., 1981DH
19.39298.15Carlson and Westrum, 1971T = 5 to 332 K.; DH
20.0298.Deshpande and Bhatagadde, 1971T = 298 to 318 K.; DH
20.5313.2Paz Andrade, Paz, et al., 1970DH
20.5298.2Katayama, 1962T = 10 to 60°C.; DH
19.3311.Swietoslawski and Zielenkiewicz, 1960Mean value 21 to 56°C.; DH
20.6323.Hough, Mason, et al., 1950T = 323 to 353 K.; DH
18.11270.Staveley and Gupta, 1949T = 90 to 270 K.; DH
20.7300.8Phillip, 1939DH
19.97313.15Fiock, Ginnings, et al., 1931T = 40 to 110°C.; DH
19.1292.0Kelley, 1929T = 16 to 293 K. Value is unsmoothed experimental datum.; DH
18.7270.Mitsukuri and Hara, 1929T = 190 to 270 K.; DH
19.1290.1Parks, 1925T = 89 to 290 K. Value is unsmoothed experimental datum.; DH
19.9298.von Reis, 1881T = 288 to 335 K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
16.35120.Sugisaki, Suga, et al., 1968glass phase; T = 20 to 120 K.; DH
1.2920.5Ahlberg, Blanchard, et al., 1937T = 5 to 28 K.; DH
25.1173.Maass and Walbauer, 1925T = 93 to 173 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil337.8 ± 0.3KAVGN/AAverage of 155 out of 172 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus176. ± 1.KAVGN/AAverage of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple175.5 ± 0.5KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tc513. ± 1.KAVGN/AAverage of 27 out of 31 values; Individual data points
Quantity Value Units Method Reference Comment
Pc79. ± 1.atmAVGN/AAverage of 17 out of 20 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.117l/molN/AGude and Teja, 1995 
Vc0.113024l/molN/ACraven and de Reuck, 1986TRC
Vc0.118l/molN/AFrancesconi, Lentz, et al., 1981Uncertainty assigned by TRC = 0.004 l/mol; TRC
Vc0.11663l/molN/AZubarev and Bagdonas, 1969Uncertainty assigned by TRC = 0.0035 l/mol; TRC
Quantity Value Units Method Reference Comment
rhoc8.51 ± 0.07mol/lAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Deltavap9.0 ± 0.1kcal/molAVGN/AAverage of 11 out of 12 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
8.415337.7N/AMajer and Svoboda, 1985 
9.37258.AStephenson and Malanowski, 1987Based on data from 175. - 273. K.; AC
8.82353.AStephenson and Malanowski, 1987Based on data from 338. - 487. K.; AC
10.4213.AStephenson and Malanowski, 1987Based on data from 188. - 228. K.; AC
9.30275.AStephenson and Malanowski, 1987Based on data from 224. - 290. K.; AC
9.15300.AStephenson and Malanowski, 1987Based on data from 285. - 345. K.; AC
8.84350.AStephenson and Malanowski, 1987Based on data from 335. - 376. K.; AC
8.63388.AStephenson and Malanowski, 1987Based on data from 373. - 458. K.; AC
8.39468.AStephenson and Malanowski, 1987Based on data from 453. - 513. K.; AC
7.82373.CYerlett and Wormald, 1986AC
6.72423.CYerlett and Wormald, 1986AC
4.92473.CYerlett and Wormald, 1986AC
1.8510.CYerlett and Wormald, 1986AC
8.96331.EBCervenkova and Boublik, 1984Based on data from 316. - 336. K.; AC
9.15303.N/AGibbard and Creek, 1974Based on data from 288. - 337. K. See also Boublik, Fried, et al., 1984.; AC
8.41 ± 0.02338.CCounsell and Lee, 1973AC
8.51 ± 0.02331.CCounsell and Lee, 1973AC
8.65 ± 0.02321.CCounsell and Lee, 1973AC
8.84 ± 0.02306.CCounsell and Lee, 1973AC
8.77 ± 0.02313.CSvoboda, Veselý, et al., 1973AC
8.65 ± 0.02323.CSvoboda, Veselý, et al., 1973AC
8.51 ± 0.02333.CSvoboda, Veselý, et al., 1973AC
8.44 ± 0.02338.CSvoboda, Veselý, et al., 1973AC
8.29 ± 0.02343.CSvoboda, Veselý, et al., 1973AC
8.84352.N/AWilhoit and Zwolinski, 1973Based on data from 337. - 383. K.; AC
9.25290.EBBoublík and Aim, 1972Based on data from 275. - 336. K. See also Stephenson and Malanowski, 1987.; AC
9.15303.EBAmbrose and Sprake, 1970Based on data from 288. - 357. K.; AC
8.68368.N/AHirata, Suda, et al., 1967Based on data from 353. - 483. K.; AC
9.18293.N/AKlyueva, Mischenko, et al., 1960Based on data from 278. - 323. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-αTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) 298. - 477.
A (kcal/mol) 10.8
alpha -0.31
beta 0.4241
Tc (K) 512.6
ReferenceMajer and Svoboda, 1985

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
353.5 - 512.635.152821569.613-34.846Ambrose, Sprake, et al., 1975Coefficents calculated by NIST from author's data.
288.1 - 356.835.198381581.341-33.50Ambrose and Sprake, 1970Coefficents calculated by NIST from author's data.
353. - 483.5.307301676.569-21.728Hirata and Suda, 1967Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
0.760175.3Domalski and Hearing, 1996AC
0.5249176.Maass and Walbauer, 1925DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
2.99176.Maass and Walbauer, 1925DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
0.88161.1Domalski and Hearing, 1996CAL
4.33175.3
0.96157.3
4.37175.6

Enthalpy of phase transition

DeltaHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.1520157.34crystaline, IIcrystaline, ICarlson and Westrum, 1971DH
0.76850175.59crystaline, IliquidCarlson and Westrum, 1971DH
0.3681103.crystalineglassSugisaki, Suga, et al., 1968Glass transition.; DH
0.170157.8crystaline, IIcrystaline, IStaveley and Gupta, 1949DH
0.7550175.4crystaline, IliquidStaveley and Gupta, 1949DH
0.1543157.4crystaline, IIcrystaline, IKelley, 1929DH
0.7569175.2crystaline, IliquidKelley, 1929DH
0.141161.1crystaline, IIcrystaline, IParks, 1925DH
0.7591175.3crystaline, IliquidParks, 1925DH

Entropy of phase transition

DeltaStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.966157.34crystaline, IIcrystaline, ICarlson and Westrum, 1971DH
4.376175.59crystaline, IliquidCarlson and Westrum, 1971DH
3.573103.crystalineglassSugisaki, Suga, et al., 1968Glass; DH
1.08157.8crystaline, IIcrystaline, IStaveley and Gupta, 1949DH
4.304175.4crystaline, IliquidStaveley and Gupta, 1949DH
0.980157.4crystaline, IIcrystaline, IKelley, 1929DH
4.321175.2crystaline, IliquidKelley, 1929DH
0.875161.1crystaline, IIcrystaline, IParks, 1925DH
4.331175.3crystaline, IliquidParks, 1925DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Chlorine anion + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17. ± 3.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar24.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar22.9cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar14.8cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar10.1 ± 0.8kcal/molAVGN/AAverage of 10 values; Individual data points

CH3O- + Hydrogen cation = Methyl Alcohol

By formula: CH3O- + H+ = CH4O

Quantity Value Units Method Reference Comment
Deltar382. ± 2.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar376.02 ± 0.62kcal/molH-TSNee, Osterwalder, et al., 2006gas phase; B
Deltar376.04 ± 0.55kcal/molH-TSOsborn, Leahy, et al., 1998gas phase; B
Deltar374.0 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Deltar374.6 ± 2.1kcal/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B
Deltar375.10 ± 0.60kcal/molTDEqMeot-ner and Sieck, 1986gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

CH5O+ + Methyl Alcohol = (CH5O+ bullet Methyl Alcohol)

By formula: CH5O+ + CH4O = (CH5O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar32.6kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar32.3kcal/molPHPMSSzulejko and McMahon, 1992gas phase; M
Deltar32.1kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar33.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Deltar33.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar29.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar29.2cal/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M
Deltar26.6cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar30.5cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M
Deltar28.5cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar25.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

CH3O- + Methyl Alcohol = (CH3O- bullet Methyl Alcohol)

By formula: CH3O- + CH4O = (CH3O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar29.3 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B,M
Deltar28.80 ± 0.30kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B,M
Deltar29.4 ± 2.5kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Deltar19.0 ± 2.0kcal/molN/AMoylan, Dodd, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar31.8cal/mol*KPHPMSPaul and Kebarle, 1990gas phase; M
Deltar26.7cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar20.30kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar19.8 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B
Deltar20.80 ± 0.50kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B
Deltar20.3 ± 1.6kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
19.1296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(CH3O-)H2O; Meot-Ner(Mautner), 1986; M

C4H9O- + Methyl Alcohol = (C4H9O- bullet Methyl Alcohol)

By formula: C4H9O- + CH4O = (C4H9O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar25.5 ± 1.0kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B,M
Deltar23.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar26.0 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M
Quantity Value Units Method Reference Comment
Deltar27.9cal/mol*KN/AMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar17.1 ± 1.6kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B
Deltar17.3 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M

C2H5O- + Methyl Alcohol = (C2H5O- bullet Methyl Alcohol)

By formula: C2H5O- + CH4O = (C2H5O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar27.3 ± 2.9kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Deltar25.6 ± 1.9kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar18.6 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.4296.FAMackay, Rakshit, et al., 1982gas phase; From thermochemical cycle,switching reaction(CH3O-)CH3OH; Caldwell and Kebarle, 1986, Taft, 1983; M

(Chlorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol)

By formula: (Cl- bullet CH4O) + CH4O = (Cl- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.70 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar14.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar13.00 ± 0.70kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar19.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar7.10kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar6.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar7.20 ± 0.40kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 3Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + CH4O = (Cl- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar11.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.80 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar11.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar12.30 ± 0.60kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.7cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar23.6cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.00kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar4.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar5.20 ± 0.30kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

C8H5- + Methyl Alcohol = (C8H5- bullet Methyl Alcohol)

By formula: C8H5- + CH4O = (C8H5- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar21.5 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
Deltar21.4 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar11.0 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
Deltar12.7 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

CN- + Methyl Alcohol = (CN- bullet Methyl Alcohol)

By formula: CN- + CH4O = (CN- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.70 ± 0.80kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar16.6 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Deltar16.5 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar24.3cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar8.80 ± 0.20kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar10.4 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Deltar9.2 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar38.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar38.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar30.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Iodide + Methyl Alcohol = (Iodide bullet Methyl Alcohol)

By formula: I- + CH4O = (I- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar11.90 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.3 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar11.2kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar11.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar17.8cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.76kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.0 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar5.7 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

C2H5O+ + Methyl Alcohol = (C2H5O+ bullet Methyl Alcohol)

By formula: C2H5O+ + CH4O = (C2H5O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar30.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar22.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C2H7O+ + Methyl Alcohol = (C2H7O+ bullet Methyl Alcohol)

By formula: C2H7O+ + CH4O = (C2H7O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar29.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar26.6cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar21.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C3H7O- + Methyl Alcohol = (C3H7O- bullet Methyl Alcohol)

By formula: C3H7O- + CH4O = (C3H7O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar26.9 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar18.2 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Fluorine anion + Methyl Alcohol = (Fluorine anion bullet Methyl Alcohol)

By formula: F- + CH4O = (F- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar29.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Deltar29.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar23.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar22.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar22.8 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Deltar15.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 4Methyl Alcohol)

By formula: (Cl- bullet 3CH4O) + CH4O = (Cl- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar11.20 ± 0.60kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar26.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar3.70kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar3.30 ± 0.20kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Bromine anion + Methyl Alcohol = (Bromine anion bullet Methyl Alcohol)

By formula: Br- + CH4O = (Br- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar14.50 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.00 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B
Deltar8.4 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

C3H9Si+ + Methyl Alcohol = (C3H9Si+ bullet Methyl Alcohol)

By formula: C3H9Si+ + CH4O = (C3H9Si+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar39.2kcal/molPHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar29.7cal/mol*KN/AWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
25.3468.PHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) bullet Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar23.2 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar21.9 ± 1.4kcal/molCIDTArmentrout and Rodgers, 2000RCD
Deltar24.0 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
Deltar26.6 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar20500.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
Deltar24.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Chlorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 5Methyl Alcohol)

By formula: (Cl- bullet 4CH4O) + CH4O = (Cl- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50 ± 0.50kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar25.5cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar2.90 ± 0.10kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Water + Propane, 2,2-dimethoxy- = 2Methyl Alcohol + Acetone

By formula: H2O + C5H12O2 = 2CH4O + C3H6O

Quantity Value Units Method Reference Comment
Deltar4.86 ± 0.01kcal/molCmWiberg, Morgan, et al., 1994liquid phase; ALS
Deltar4.88 ± 0.01kcal/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis; ALS
Deltar4.8836 ± 0.0067kcal/molCmWiberg and Squires, 1979, 2liquid phase; solvent: Water; Hydrolysis; ALS
Deltar-3.95 ± 0.05kcal/molCmStern and Dorer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 3.69 ± 0.05 kcal/mol; Heat of hydrolysis; ALS

(CH5O+ bullet Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet CH4O) + CH4O = (CH5O+ bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar21.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar21.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar21.3kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar25.8cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar28.2cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

C5H11O- + Methyl Alcohol = (C5H11O- bullet Methyl Alcohol)

By formula: C5H11O- + CH4O = (C5H11O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar25.7 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar17.0 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

C6H11S2- + Methyl Alcohol = (C6H11S2- bullet Methyl Alcohol)

By formula: C6H11S2- + CH4O = (C6H11S2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar13.2 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

(Copper ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Copper ion (1+) bullet 2Methyl Alcohol)

By formula: (Cu+ bullet CH4O) + CH4O = (Cu+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar13.8kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar6.3kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(CH5O+ bullet 2Water bullet 3Methyl Alcohol) + Water = (CH5O+ bullet 3Water bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 2H2O bullet 3CH4O) + H2O = (CH5O+ bullet 3H2O bullet 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.1kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.1272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet 3Water bullet 2Methyl Alcohol) + Water = (CH5O+ bullet 4Water bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet 3H2O bullet 2CH4O) + H2O = (CH5O+ bullet 4H2O bullet 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.3kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.2272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet 4Water bullet Methyl Alcohol) + Water = (CH5O+ bullet 5Water bullet Methyl Alcohol)

By formula: (CH5O+ bullet 4H2O bullet CH4O) + H2O = (CH5O+ bullet 5H2O bullet CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.5269.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet Water) + Methyl Alcohol = (CH5O+ bullet Methyl Alcohol bullet Water)

By formula: (CH5O+ bullet H2O) + CH4O = (CH5O+ bullet CH4O bullet H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6452.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

C6H5NO2- + Methyl Alcohol = (C6H5NO2- bullet Methyl Alcohol)

By formula: C6H5NO2- + CH4O = (C6H5NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.10 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.1cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.40kcal/molTDAsSieck, 1985gas phase; B
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

Copper ion (1+) + Methyl Alcohol = (Copper ion (1+) bullet Methyl Alcohol)

By formula: Cu+ + CH4O = (Cu+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar5.9kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(Fluorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 2Methyl Alcohol)

By formula: (F- bullet CH4O) + CH4O = (F- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar20.30 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar19.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.97kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 3Methyl Alcohol)

By formula: (F- bullet 2CH4O) + CH4O = (F- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar15.10 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar14.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 3Methyl Alcohol)

By formula: (Br- bullet 2CH4O) + CH4O = (Br- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 2Methyl Alcohol)

By formula: (Br- bullet CH4O) + CH4O = (Br- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar12.00 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.62kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 2Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 3Methyl Alcohol)

By formula: (I- bullet 2CH4O) + CH4O = (I- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.41kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar3.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 2Methyl Alcohol)

By formula: (I- bullet CH4O) + CH4O = (I- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 11Methyl Alcohol)

By formula: (Cl- bullet 10CH4O) + CH4O = (Cl- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar7.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Sodium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 2Methyl Alcohol)

By formula: (Na+ bullet CH4O) + CH4O = (Na+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar21.4 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar20.5 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar20.2 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

H4ClO2- + Methyl Alcohol + 2Water = CH8ClO3-

By formula: H4ClO2- + CH4O + 2H2O = CH8ClO3-

Quantity Value Units Method Reference Comment
Deltar10.40 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar11.40 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B
Quantity Value Units Method Reference Comment
Deltar5.80kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar6.00kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B

(CH5O+ bullet 2Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet 2CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar17.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar28.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ bullet 3Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 3CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ bullet 2Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 2CH4O) + CH4O = (CH5O+ bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar16.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar28.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 3Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 4Methyl Alcohol)

By formula: (CH5O+ bullet 3CH4O) + CH4O = (CH5O+ bullet 4CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar11.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar13.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar28.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 4Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 5Methyl Alcohol)

By formula: (CH5O+ bullet 4CH4O) + CH4O = (CH5O+ bullet 5CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar12.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar31.1cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet Methyl Alcohol)

By formula: (CH5O+ bullet CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar21.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ bullet 5Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 6Methyl Alcohol)

By formula: (CH5O+ bullet 5CH4O) + CH4O = (CH5O+ bullet 6CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar11.9kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar32.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 6Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 7Methyl Alcohol)

By formula: (CH5O+ bullet 6CH4O) + CH4O = (CH5O+ bullet 7CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar12.0kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.7cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar35.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(Fluorine anion bullet 11Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 12Methyl Alcohol)

By formula: (F- bullet 11CH4O) + CH4O = (F- bullet 12CH4O)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference Comment
140. QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
220. XN/A 
220.5200.MN/A 
220. XN/AValue given here as quoted by missing citation.
160.5600.XN/A 
230. MN/A 
210. M,XTimmermans, 1960Value given here as quoted by missing citation.
230. MButler, Ramchandani, et al., 1935This paper supersedes earlier work with more concentrated solutions Butler, Thomson, et al., 1933.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH4O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.84 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)180.3kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity173.2kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.85 ± 0.03PITao, Klemm, et al., 1992LL
10.82 ± 0.05EIHolmes and Lossing, 1991LL
10.84 ± 0.07EIBowen and Maccoll, 1984LBLHLM
10.9EIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
10.84 ± 0.08EIAllam, Migahed, et al., 1982LBLHLM
10.90 ± 0.03EISahini, Constantin, et al., 1978LLK
10.85 ± 0.01PIBerkowitz, 1978LLK
10.846 ± 0.002PEMacNeil and Dixon, 1977LLK
10.90 ± 0.12EIFinney and Harrison, 1972LLK
10.83 ± 0.03PIWarneck, 1971LLK
10.85 ± 0.02PECocksey, Eland, et al., 1971LLK
10.85PEBaker, Betteridge, et al., 1971LLK
10.85PEBaker, Betteridge, et al., 1971LLK
10.829 ± 0.015PIOmura, Kaneko, et al., 1969RDSH
10.85EILifshitz, Shapiro, et al., 1969RDSH
10.83PEDewar and Worley, 1969RDSH
10.84 ± 0.02PIRefaey and Chupka, 1968RDSH
10.85CICermak, 1968RDSH
10.83PEAl-Joboury and Turner, 1964RDSH
10.85 ± 0.02PIWatanabe, 1954RDSH
10.96EIVorob'ev, Furlei, et al., 1989Vertical value; LL
11.0PEVon Niessen, Bieri, et al., 1980Vertical value; LLK
10.95PEUtsunomiya, Kobayashi, et al., 1980Vertical value; LLK
10.95PEKobayashi, 1978Vertical value; LLK
10.86PEBenoit and Harrison, 1977Vertical value; LLK
10.97 ± 0.03PEPeel and Willett, 1975Vertical value; LLK
10.96PERobin and Kuebler, 1973Vertical value; LLK
10.95PEOgata, Onizuka, et al., 1973Vertical value; LLK
10.94PEKatsumata, Iwai, et al., 1973Vertical value; LLK
10.95PEOgata, Onizuka, et al., 1972Vertical value; LLK
10.96PEBaker, Betteridge, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH+22.31 ± 0.09?EIReed and Snedden, 1956RDSH
CHO+13.06 ± 0.10H2+HPIWarneck, 1971LLK
CHO+14.0 ± 0.2H2+HEILifshitz, Shapiro, et al., 1969RDSH
CH2+14.05 ± 0.05H2OPIWarneck, 1971LLK
CH2+15.3H2OEIHaney and Franklin, 1968RDSH
CH2O+10.9H2EIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
CH2O+12.05 ± 0.12H2PIWarneck, 1971LLK
CH2O+12.45H2PIRefaey and Chupka, 1968RDSH
CH3+13.82 ± 0.04OHPIWarneck, 1971LLK
CH3+13.5OHEIFriedman, Long, et al., 1957RDSH
CH3O+11.67 ± 0.09HEIBowen and Maccoll, 1984LBLHLM
CH3O+10.4HEIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
CH3O+11.85 ± 0.08HEIAllam, Migahed, et al., 1982LBLHLM
CH3O+11.88 ± 0.05HEISelim and Helal, 1981LLK
CH3O+11.69HEILossing, 1977LLK
CH3O+11.76 ± 0.11HEIFinney and Harrison, 1972LLK
CH3O+11.55 ± 0.03HPIWarneck, 1971LLK
CH3O+11.66 ± 0.04HPIOmura, Kaneko, et al., 1969RDSH
CH3O+11.67HEILifshitz, Shapiro, et al., 1969RDSH
CH3O+11.67 ± 0.03HPIRefaey and Chupka, 1968RDSH
CH3O+[CH2OH+]11.649 ± 0.003HPIBerkowitz, Ellison, et al., 1994Unpublished results of B. Ruscic and J. Berkowitz; LL
CO+13.72H2EIFriedman, Long, et al., 1957RDSH
CO+14.31 ± 0.052H2EIFriedland and Strakna, 1956RDSH

De-protonation reactions

CH3O- + Hydrogen cation = Methyl Alcohol

By formula: CH3O- + H+ = CH4O

Quantity Value Units Method Reference Comment
Deltar382. ± 2.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar376.02 ± 0.62kcal/molH-TSNee, Osterwalder, et al., 2006gas phase; B
Deltar376.04 ± 0.55kcal/molH-TSOsborn, Leahy, et al., 1998gas phase; B
Deltar374.0 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Deltar374.6 ± 2.1kcal/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B
Deltar375.10 ± 0.60kcal/molTDEqMeot-ner and Sieck, 1986gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Methyl Alcohol = (Bromine anion bullet Methyl Alcohol)

By formula: Br- + CH4O = (Br- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar14.50 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.00 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B
Deltar8.4 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

(Bromine anion bullet Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 2Methyl Alcohol)

By formula: (Br- bullet CH4O) + CH4O = (Br- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar12.00 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.62kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 3Methyl Alcohol)

By formula: (Br- bullet 2CH4O) + CH4O = (Br- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 4Methyl Alcohol)

By formula: (Br- bullet 3CH4O) + CH4O = (Br- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 5Methyl Alcohol)

By formula: (Br- bullet 4CH4O) + CH4O = (Br- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 6Methyl Alcohol)

By formula: (Br- bullet 5CH4O) + CH4O = (Br- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 7Methyl Alcohol)

By formula: (Br- bullet 6CH4O) + CH4O = (Br- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 8Methyl Alcohol)

By formula: (Br- bullet 7CH4O) + CH4O = (Br- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar8.4 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 9Methyl Alcohol)

By formula: (Br- bullet 8CH4O) + CH4O = (Br- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Bromine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 10Methyl Alcohol)

By formula: (Br- bullet 9CH4O) + CH4O = (Br- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar8.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

CHO- + Methyl Alcohol = (CHO- bullet Methyl Alcohol)

By formula: CHO- + CH4O = (CHO- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar28.8kcal/molPHPMSMeot-ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.7cal/mol*KPHPMSMeot-ner and Sieck, 1986gas phase; M

HCO2 anion + Methyl Alcohol = (HCO2 anion bullet Methyl Alcohol)

By formula: CHO2- + CH4O = (CHO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.0kcal/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.6kcal/molTDAsMeot-Ner and Sieck, 1986gas phase; B

CH3O- + Methyl Alcohol = (CH3O- bullet Methyl Alcohol)

By formula: CH3O- + CH4O = (CH3O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar29.3 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B,M
Deltar28.80 ± 0.30kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B,M
Deltar29.4 ± 2.5kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Deltar19.0 ± 2.0kcal/molN/AMoylan, Dodd, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar31.8cal/mol*KPHPMSPaul and Kebarle, 1990gas phase; M
Deltar26.7cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar20.30kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar19.8 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B
Deltar20.80 ± 0.50kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B
Deltar20.3 ± 1.6kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
19.1296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(CH3O-)H2O; Meot-Ner(Mautner), 1986; M

(CH3O- bullet Methyl Alcohol) + Methyl Alcohol = (CH3O- bullet 2Methyl Alcohol)

By formula: (CH3O- bullet CH4O) + CH4O = (CH3O- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar21.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar27.8cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet 2Methyl Alcohol) + Methyl Alcohol = (CH3O- bullet 3Methyl Alcohol)

By formula: (CH3O- bullet 2CH4O) + CH4O = (CH3O- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar15.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet 3Methyl Alcohol) + Methyl Alcohol = (CH3O- bullet 4Methyl Alcohol)

By formula: (CH3O- bullet 3CH4O) + CH4O = (CH3O- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar11.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet Water) + Methyl Alcohol = (CH3O- bullet Methyl Alcohol bullet Water)

By formula: (CH3O- bullet H2O) + CH4O = (CH3O- bullet CH4O bullet H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.7296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(CH3O-)2H2O; Meot-Ner(Mautner), 1986; M

CH5O+ + Methyl Alcohol = (CH5O+ bullet Methyl Alcohol)

By formula: CH5O+ + CH4O = (CH5O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar32.6kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar32.3kcal/molPHPMSSzulejko and McMahon, 1992gas phase; M
Deltar32.1kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar33.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Deltar33.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar29.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar29.2cal/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M
Deltar26.6cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar30.5cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M
Deltar28.5cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar25.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(CH5O+ bullet Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet CH4O) + CH4O = (CH5O+ bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar21.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar21.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar21.3kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar25.8cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
Deltar28.2cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 2Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 2CH4O) + CH4O = (CH5O+ bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar16.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar28.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 3Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 4Methyl Alcohol)

By formula: (CH5O+ bullet 3CH4O) + CH4O = (CH5O+ bullet 4CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar11.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar13.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar28.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 4Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 5Methyl Alcohol)

By formula: (CH5O+ bullet 4CH4O) + CH4O = (CH5O+ bullet 5CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar12.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar31.1cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 5Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 6Methyl Alcohol)

By formula: (CH5O+ bullet 5CH4O) + CH4O = (CH5O+ bullet 6CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar11.9kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar32.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 6Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 7Methyl Alcohol)

By formula: (CH5O+ bullet 6CH4O) + CH4O = (CH5O+ bullet 7CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar12.0kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.7cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar35.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ bullet 7Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 8Methyl Alcohol)

By formula: (CH5O+ bullet 7CH4O) + CH4O = (CH5O+ bullet 8CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 8Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 9Methyl Alcohol)

By formula: (CH5O+ bullet 8CH4O) + CH4O = (CH5O+ bullet 9CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar9.1kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.9200.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 9Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 10Methyl Alcohol)

By formula: (CH5O+ bullet 9CH4O) + CH4O = (CH5O+ bullet 10CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar8.7kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.5200.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 10Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 11Methyl Alcohol)

By formula: (CH5O+ bullet 10CH4O) + CH4O = (CH5O+ bullet 11CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar8.6kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.8184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 11Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 12Methyl Alcohol)

By formula: (CH5O+ bullet 11CH4O) + CH4O = (CH5O+ bullet 12CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.7184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 12Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 13Methyl Alcohol)

By formula: (CH5O+ bullet 12CH4O) + CH4O = (CH5O+ bullet 13CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar8.6kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.8184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (CH5O+ bullet 2Methyl Alcohol bullet Water)

By formula: (CH5O+ bullet CH4O bullet H2O) + CH4O = (CH5O+ bullet 2CH4O bullet H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar16.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.5cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet Water) + Methyl Alcohol = (CH5O+ bullet Methyl Alcohol bullet Water)

By formula: (CH5O+ bullet H2O) + CH4O = (CH5O+ bullet CH4O bullet H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6452.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet 2Water) + Methyl Alcohol = (CH5O+ bullet Methyl Alcohol bullet 2Water)

By formula: (CH5O+ bullet 2H2O) + CH4O = (CH5O+ bullet CH4O bullet 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar18.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH6N+ + Methyl Alcohol = (CH6N+ bullet Methyl Alcohol)

By formula: CH6N+ + CH4O = (CH6N+ bullet CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

CN- + Methyl Alcohol = (CN- bullet Methyl Alcohol)

By formula: CN- + CH4O = (CN- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.70 ± 0.80kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar16.6 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Deltar16.5 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar24.3cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar8.80 ± 0.20kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar10.4 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Deltar9.2 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M

C2H- + Methyl Alcohol = C3H5O-

By formula: C2H- + CH4O = C3H5O-

Quantity Value Units Method Reference Comment
Deltar21.6 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar10.90kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar11.6 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

MeCO2 anion + Methyl Alcohol = (MeCO2 anion bullet Methyl Alcohol)

By formula: C2H3O2- + CH4O = (C2H3O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B

(C2H4N+ bullet Methyl Alcohol) + Methyl Alcohol = (C2H4N+ bullet 2Methyl Alcohol)

By formula: (C2H4N+ bullet CH4O) + CH4O = (C2H4N+ bullet 2CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar20.9kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.0cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

(C2H4N+ bullet 2Methyl Alcohol) + Methyl Alcohol = (C2H4N+ bullet 3Methyl Alcohol)

By formula: (C2H4N+ bullet 2CH4O) + CH4O = (C2H4N+ bullet 3CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar13.9kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.4cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

(C2H4N+ bullet Methyl Alcohol bullet Acetonitrile) + Methyl Alcohol = (C2H4N+ bullet 2Methyl Alcohol bullet Acetonitrile)

By formula: (C2H4N+ bullet CH4O bullet C2H3N) + CH4O = (C2H4N+ bullet 2CH4O bullet C2H3N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.1cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

C2H4NO2- + Methyl Alcohol = C3H8NO3-

By formula: C2H4NO2- + CH4O = C3H8NO3-

Quantity Value Units Method Reference Comment
Deltar17.00 ± 0.50kcal/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.5 ± 1.0kcal/molTDAsNieckarz, Atkins, et al., 2008gas phase; B

C2H5O+ + Methyl Alcohol = (C2H5O+ bullet Methyl Alcohol)

By formula: C2H5O+ + CH4O = (C2H5O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar30.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar22.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C2H5O- + Methyl Alcohol = (C2H5O- bullet Methyl Alcohol)

By formula: C2H5O- + CH4O = (C2H5O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar27.3 ± 2.9kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Deltar25.6 ± 1.9kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar18.6 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.4296.FAMackay, Rakshit, et al., 1982gas phase; From thermochemical cycle,switching reaction(CH3O-)CH3OH; Caldwell and Kebarle, 1986, Taft, 1983; M

C2H7O+ + Methyl Alcohol = (C2H7O+ bullet Methyl Alcohol)

By formula: C2H7O+ + CH4O = (C2H7O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar26.3kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar27.1cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Methyl Alcohol) + Methyl Alcohol = (C2H7O+ bullet 2Methyl Alcohol)

By formula: (C2H7O+ bullet CH4O) + CH4O = (C2H7O+ bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar18.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar28.9cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Methyl Alcohol) + Methyl Alcohol = (C2H7O+ bullet 3Methyl Alcohol)

By formula: (C2H7O+ bullet 2CH4O) + CH4O = (C2H7O+ bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar15.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar31.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 3Methyl Alcohol) + Methyl Alcohol = (C2H7O+ bullet 4Methyl Alcohol)

By formula: (C2H7O+ bullet 3CH4O) + CH4O = (C2H7O+ bullet 4CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Methyl Alcohol bullet Dimethyl ether) + Methyl Alcohol = (C2H7O+ bullet 2Methyl Alcohol bullet Dimethyl ether)

By formula: (C2H7O+ bullet CH4O bullet C2H6O) + CH4O = (C2H7O+ bullet 2CH4O bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar15.1kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar30.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Methyl Alcohol bullet Dimethyl ether) + Methyl Alcohol = (C2H7O+ bullet 3Methyl Alcohol bullet Dimethyl ether)

By formula: (C2H7O+ bullet 2CH4O bullet C2H6O) + CH4O = (C2H7O+ bullet 3CH4O bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.5cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Dimethyl ether) + Methyl Alcohol = (C2H7O+ bullet Methyl Alcohol bullet Dimethyl ether)

By formula: (C2H7O+ bullet C2H6O) + CH4O = (C2H7O+ bullet CH4O bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar18.1kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar30.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Methyl Alcohol = (C2H7O+ bullet Methyl Alcohol)

By formula: C2H7O+ + CH4O = (C2H7O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar29.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar26.6cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar21.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C2H7O2- + 2Methyl Alcohol = C3H11O3-

By formula: C2H7O2- + 2CH4O = C3H11O3-

Quantity Value Units Method Reference Comment
Deltar21.4 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.10 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Deltar17.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.10 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Deltar15.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.90 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

imidazolide anion + Methyl Alcohol = (imidazolide anion bullet Methyl Alcohol)

By formula: C3H3N2- + CH4O = (C3H3N2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.1kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H7O+ + Methyl Alcohol = (C3H7O+ bullet Methyl Alcohol)

By formula: C3H7O+ + CH4O = (C3H7O+ bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M

C3H7O- + Methyl Alcohol = (C3H7O- bullet Methyl Alcohol)

By formula: C3H7O- + CH4O = (C3H7O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar26.9 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar18.2 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

C3H9Si+ + Methyl Alcohol = (C3H9Si+ bullet Methyl Alcohol)

By formula: C3H9Si+ + CH4O = (C3H9Si+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar39.2kcal/molPHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar29.7cal/mol*KN/AWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
25.3468.PHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

C3H9Sn+ + Methyl Alcohol = (C3H9Sn+ bullet Methyl Alcohol)

By formula: C3H9Sn+ + CH4O = (C3H9Sn+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar32.6kcal/molPHPMSStone and Splinter, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.cal/mol*KPHPMSStone and Splinter, 1984gas phase; M

C3H10N+ + Methyl Alcohol = (C3H10N+ bullet Methyl Alcohol)

By formula: C3H10N+ + CH4O = (C3H10N+ bullet CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar15.1kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

(C3H10N+ bullet Methyl Alcohol) + Methyl Alcohol = (C3H10N+ bullet 2Methyl Alcohol)

By formula: (C3H10N+ bullet CH4O) + CH4O = (C3H10N+ bullet 2CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar11.7kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8cal/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

(C3H10N+ bullet 2Methyl Alcohol) + Methyl Alcohol = (C3H10N+ bullet 3Methyl Alcohol)

By formula: (C3H10N+ bullet 2CH4O) + CH4O = (C3H10N+ bullet 3CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar10.5kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

(C3H10N+ bullet Methyl Alcohol bullet Methylamine, N,N-dimethyl-) + Methyl Alcohol = (C3H10N+ bullet 2Methyl Alcohol bullet Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ bullet CH4O bullet C3H9N) + CH4O = (C3H10N+ bullet 2CH4O bullet C3H9N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar9.5kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M

(C3H10N+ bullet Methylamine, N,N-dimethyl-) + Methyl Alcohol = (C3H10N+ bullet Methyl Alcohol bullet Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ bullet C3H9N) + CH4O = (C3H10N+ bullet CH4O bullet C3H9N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar10.6kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

C3H11O3- + 3Methyl Alcohol = C4H15O4-

By formula: C3H11O3- + 3CH4O = C4H15O4-

Quantity Value Units Method Reference Comment
Deltar15.0 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.20 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C3H11O3- + Water + 2Methyl Alcohol = C3H13O4-

By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-

Quantity Value Units Method Reference Comment
Deltar13.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.40 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C4H2O3- + Methyl Alcohol = (C4H2O3- bullet Methyl Alcohol)

By formula: C4H2O3- + CH4O = (C4H2O3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7343.PHPMSChowdhury, 1987gas phase; M

pyrrolide anion + Methyl Alcohol = (pyrrolide anion bullet Methyl Alcohol)

By formula: C4H4N- + CH4O = (C4H4N- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar18.6 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.5cal/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.4 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B

C4H9O- + Methyl Alcohol = (C4H9O- bullet Methyl Alcohol)

By formula: C4H9O- + CH4O = (C4H9O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar25.5 ± 1.0kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B,M
Deltar23.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar26.0 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M
Quantity Value Units Method Reference Comment
Deltar27.9cal/mol*KN/AMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar17.1 ± 1.6kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B
Deltar17.3 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M

C4H11O2+ + Methyl Alcohol = (C4H11O2+ bullet Methyl Alcohol)

By formula: C4H11O2+ + CH4O = (C4H11O2+ bullet CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.3cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet Methyl Alcohol) + Methyl Alcohol = (C4H11O2+ bullet 2Methyl Alcohol)

By formula: (C4H11O2+ bullet CH4O) + CH4O = (C4H11O2+ bullet 2CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar14.4kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 2Methyl Alcohol) + Methyl Alcohol = (C4H11O2+ bullet 3Methyl Alcohol)

By formula: (C4H11O2+ bullet 2CH4O) + CH4O = (C4H11O2+ bullet 3CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar12.6kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 3Methyl Alcohol) + Methyl Alcohol = (C4H11O2+ bullet 4Methyl Alcohol)

By formula: (C4H11O2+ bullet 3CH4O) + CH4O = (C4H11O2+ bullet 4CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 4Methyl Alcohol) + Methyl Alcohol = (C4H11O2+ bullet 5Methyl Alcohol)

By formula: (C4H11O2+ bullet 4CH4O) + CH4O = (C4H11O2+ bullet 5CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar9.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 5Methyl Alcohol) + Methyl Alcohol = (C4H11O2+ bullet 6Methyl Alcohol)

By formula: (C4H11O2+ bullet 5CH4O) + CH4O = (C4H11O2+ bullet 6CH4O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar8.9kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C4H15O4- + 4Methyl Alcohol = C5H19O5-

By formula: C4H15O4- + 4CH4O = C5H19O5-

Quantity Value Units Method Reference Comment
Deltar11.4 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.70 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

cyclopentadienide anion + Methyl Alcohol = (cyclopentadienide anion bullet Methyl Alcohol)

By formula: C5H5- + CH4O = (C5H5- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.2 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.9 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B

C5H11O- + Methyl Alcohol = (C5H11O- bullet Methyl Alcohol)

By formula: C5H11O- + CH4O = (C5H11O- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar25.7 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar17.0 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

C6F4O2- + Methyl Alcohol = (C6F4O2- bullet Methyl Alcohol)

By formula: C6F4O2- + CH4O = (C6F4O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.0 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.0343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.6343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.8343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.0 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.0343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.8 ± 2.0kcal/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar29.8cal/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.6 ± 2.0kcal/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C6H4NO3- + Methyl Alcohol = (C6H4NO3- bullet Methyl Alcohol)

By formula: C6H4NO3- + CH4O = (C6H4NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.0 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C6H4NO3- + Methyl Alcohol = (C6H4NO3- bullet Methyl Alcohol)

By formula: C6H4NO3- + CH4O = (C6H4NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.3343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.3343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.8343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Methyl Alcohol = (p-Benzoquinone anion bullet Methyl Alcohol)

By formula: C6H4O2- + CH4O = (C6H4O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.5343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Methyl Alcohol = (C6H5NO2- bullet Methyl Alcohol)

By formula: C6H5NO2- + CH4O = (C6H5NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.10 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.1cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.40kcal/molTDAsSieck, 1985gas phase; B
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

thiophenoxide anion + Methyl Alcohol = (thiophenoxide anion bullet Methyl Alcohol)

By formula: C6H5S- + CH4O = (C6H5S- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.0cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Methyl Alcohol = C7H9OS-

By formula: C6H5S- + CH4O = C7H9OS-

Quantity Value Units Method Reference Comment
Deltar13.40 ± 0.10kcal/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.50 ± 0.30kcal/molTDAsSieck and Meot-ner, 1989gas phase; B

C6H9- + Methyl Alcohol = C7H13O-

By formula: C6H9- + CH4O = C7H13O-

Quantity Value Units Method Reference Comment
Deltar20.8 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar11.50kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar10.7 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

C6H11S2- + Methyl Alcohol = (C6H11S2- bullet Methyl Alcohol)

By formula: C6H11S2- + CH4O = (C6H11S2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar13.2 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Perfluoro(methylcyclohexane) anion + Methyl Alcohol = (Perfluoro(methylcyclohexane) anion bullet Methyl Alcohol)

By formula: C7F14- + CH4O = (C7F14- bullet CH4O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.4308.PHPMSKnighton, Zook, et al., 1990gas phase; M

C7H4F3NO2- + Methyl Alcohol = (C7H4F3NO2- bullet Methyl Alcohol)

By formula: C7H4F3NO2- + CH4O = (C7H4F3NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar14.6 ± 2.0kcal/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B
Quantity Value Units Method Reference Comment
Deltar4.9 ± 1.6kcal/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 2.0kcal/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar28.6cal/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.1 ± 2.0kcal/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C7H7NO2- + Methyl Alcohol = (C7H7NO2- bullet Methyl Alcohol)

By formula: C7H7NO2- + CH4O = (C7H7NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Methyl Alcohol = (C7H7NO2- bullet Methyl Alcohol)

By formula: C7H7NO2- + CH4O = (C7H7NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.5343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Methyl Alcohol = (C7H7NO2- bullet Methyl Alcohol)

By formula: C7H7NO2- + CH4O = (C7H7NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.4 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C7H7NO3- + Methyl Alcohol = (C7H7NO3- bullet Methyl Alcohol)

By formula: C7H7NO3- + CH4O = (C7H7NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.1 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Methyl Alcohol = (C7H7NO3- bullet Methyl Alcohol)

By formula: C7H7NO3- + CH4O = (C7H7NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 2.0kcal/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar23.4cal/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 2.0kcal/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C8H5- + Methyl Alcohol = (C8H5- bullet Methyl Alcohol)

By formula: C8H5- + CH4O = (C8H5- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar21.5 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
Deltar21.4 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
Deltar11.0 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
Deltar12.7 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

C8H9NO2- + Methyl Alcohol = (C8H9NO2- bullet Methyl Alcohol)

By formula: C8H9NO2- + CH4O = (C8H9NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C8H17O4+ + Methyl Alcohol = (C8H17O4+ bullet Methyl Alcohol)

By formula: C8H17O4+ + CH4O = (C8H17O4+ bullet CH4O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar19.5kcal/molPHPMSSharma and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.0cal/mol*KPHPMSSharma and Kebarle, 1984gas phase; M

C9H7- + Methyl Alcohol = C10H11O-

By formula: C9H7- + CH4O = C10H11O-

Quantity Value Units Method Reference Comment
Deltar21.6 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar11.1 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

C10H4Cl2O2- + Methyl Alcohol = (C10H4Cl2O2- bullet Methyl Alcohol)

By formula: C10H4Cl2O2- + CH4O = (C10H4Cl2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar<1.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.5343.PHPMSChowdhury, 1987gas phase; DG<; M

1,4-Naphthalenedione anion + Methyl Alcohol = (1,4-Naphthalenedione anion bullet Methyl Alcohol)

By formula: C10H6O2- + CH4O = (C10H6O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.6343.PHPMSChowdhury, 1987gas phase; M

C10H21O5+ + Methyl Alcohol = (C10H21O5+ bullet Methyl Alcohol)

By formula: C10H21O5+ + CH4O = (C10H21O5+ bullet CH4O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar20.0kcal/molPHPMSSharma and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KPHPMSSharma and Kebarle, 1984gas phase; M

C12H25O6+ + Methyl Alcohol = (C12H25O6+ bullet Methyl Alcohol)

By formula: C12H25O6+ + CH4O = (C12H25O6+ bullet CH4O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar20.0kcal/molPHPMSSharma and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KPHPMSSharma and Kebarle, 1984gas phase; M

Chlorine anion + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17. ± 3.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar24.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar22.9cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar14.8cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar10.1 ± 0.8kcal/molAVGN/AAverage of 10 values; Individual data points

(Chlorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol)

By formula: (Cl- bullet CH4O) + CH4O = (Cl- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.70 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar14.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar13.00 ± 0.70kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar19.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar7.10kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar6.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar7.20 ± 0.40kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 3Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + CH4O = (Cl- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar11.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.80 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar11.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar12.30 ± 0.60kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.7cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar23.6cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.00kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar4.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar5.20 ± 0.30kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 4Methyl Alcohol)

By formula: (Cl- bullet 3CH4O) + CH4O = (Cl- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar11.20 ± 0.60kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar26.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar3.70kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar3.30 ± 0.20kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 5Methyl Alcohol)

By formula: (Cl- bullet 4CH4O) + CH4O = (Cl- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50 ± 0.50kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar25.5cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar2.90 ± 0.10kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 6Methyl Alcohol)

By formula: (Cl- bullet 5CH4O) + CH4O = (Cl- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar8.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 7Methyl Alcohol)

By formula: (Cl- bullet 6CH4O) + CH4O = (Cl- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar8.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 8Methyl Alcohol)

By formula: (Cl- bullet 7CH4O) + CH4O = (Cl- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 9Methyl Alcohol)

By formula: (Cl- bullet 8CH4O) + CH4O = (Cl- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.6cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 10Methyl Alcohol)

By formula: (Cl- bullet 9CH4O) + CH4O = (Cl- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 11Methyl Alcohol)

By formula: (Cl- bullet 10CH4O) + CH4O = (Cl- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar7.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol bullet Water)

By formula: (Cl- bullet CH4O bullet H2O) + CH4O = (Cl- bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet Water) + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol bullet Water)

By formula: (Cl- bullet H2O) + CH4O = (Cl- bullet CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.2kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet 2Water) + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol bullet 2Water)

By formula: (Cl- bullet 2H2O) + CH4O = (Cl- bullet CH4O bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar11.4kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.1cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

Cobalt ion (1+) + Methyl Alcohol = (Cobalt ion (1+) bullet Methyl Alcohol)

By formula: Co+ + CH4O = (Co+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar35.4 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Methyl Alcohol = (Copper ion (1+) bullet Methyl Alcohol)

By formula: Cu+ + CH4O = (Cu+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar5.9kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(Copper ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Copper ion (1+) bullet 2Methyl Alcohol)

By formula: (Cu+ bullet CH4O) + CH4O = (Cu+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar13.8kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Deltar6.3kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

Fluorine anion + Methyl Alcohol = CH3D4FO-

By formula: F- + CH4O = CH3D4FO-

Quantity Value Units Method Reference Comment
Deltar29.8 ± 2.0kcal/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B
Quantity Value Units Method Reference Comment
Deltar22.4 ± 2.0kcal/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

Fluorine anion + Methyl Alcohol = (Fluorine anion bullet Methyl Alcohol)

By formula: F- + CH4O = (F- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar29.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Deltar29.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar23.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar22.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar22.8 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Deltar15.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 2Methyl Alcohol)

By formula: (F- bullet CH4O) + CH4O = (F- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar20.30 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar19.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.97kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 3Methyl Alcohol)

By formula: (F- bullet 2CH4O) + CH4O = (F- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar15.10 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar14.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 4Methyl Alcohol)

By formula: (F- bullet 3CH4O) + CH4O = (F- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 5Methyl Alcohol)

By formula: (F- bullet 4CH4O) + CH4O = (F- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar11.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 6Methyl Alcohol)

By formula: (F- bullet 5CH4O) + CH4O = (F- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar29.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.6 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 7Methyl Alcohol)

By formula: (F- bullet 6CH4O) + CH4O = (F- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 8Methyl Alcohol)

By formula: (F- bullet 7CH4O) + CH4O = (F- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar9.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 9Methyl Alcohol)

By formula: (F- bullet 8CH4O) + CH4O = (F- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 10Methyl Alcohol)

By formula: (F- bullet 9CH4O) + CH4O = (F- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 11Methyl Alcohol)

By formula: (F- bullet 10CH4O) + CH4O = (F- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 11Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 12Methyl Alcohol)

By formula: (F- bullet 11CH4O) + CH4O = (F- bullet 12CH4O)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

F6S- + Methyl Alcohol = (F6S- bullet Methyl Alcohol)

By formula: F6S- + CH4O = (F6S- bullet CH4O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5308.PHPMSKnighton, Zook, et al., 1990gas phase; M

HS- + Methyl Alcohol = (HS- bullet Methyl Alcohol)

By formula: HS- + CH4O = (HS- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.0 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.0 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B

H4ClO2- + Methyl Alcohol + 2Water = CH8ClO3-

By formula: H4ClO2- + CH4O + 2H2O = CH8ClO3-

Quantity Value Units Method Reference Comment
Deltar10.40 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar11.40 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B
Quantity Value Units Method Reference Comment
Deltar5.80kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar6.00kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B

Iodide + Methyl Alcohol = (Iodide bullet Methyl Alcohol)

By formula: I- + CH4O = (I- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar11.90 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.3 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar11.2kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar11.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar17.8cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.76kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.0 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar5.7 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

(Iodide bullet Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 2Methyl Alcohol)

By formula: (I- bullet CH4O) + CH4O = (I- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 2Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 3Methyl Alcohol)

By formula: (I- bullet 2CH4O) + CH4O = (I- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.41kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar3.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 3Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 4Methyl Alcohol)

By formula: (I- bullet 3CH4O) + CH4O = (I- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar9.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 4Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 5Methyl Alcohol)

By formula: (I- bullet 4CH4O) + CH4O = (I- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 5Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 6Methyl Alcohol)

By formula: (I- bullet 5CH4O) + CH4O = (I- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 6Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 7Methyl Alcohol)

By formula: (I- bullet 6CH4O) + CH4O = (I- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar9.4 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 7Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 8Methyl Alcohol)

By formula: (I- bullet 7CH4O) + CH4O = (I- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

Potassium ion (1+) + Methyl Alcohol = (Potassium ion (1+) bullet Methyl Alcohol)

By formula: K+ + CH4O = (K+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9kcal/molHPMSEvans and Keesee, 1991gas phase; switching reaction,n(K+)H2O; M
Quantity Value Units Method Reference Comment
Deltar31.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; switching reaction,n(K+)H2O; M

(Potassium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Potassium ion (1+) bullet 2Methyl Alcohol)

By formula: (K+ bullet CH4O) + CH4O = (K+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar18.0kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar35.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Potassium ion (1+) bullet 3Methyl Alcohol)

By formula: (K+ bullet 2CH4O) + CH4O = (K+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar14.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet 3Methyl Alcohol) + Methyl Alcohol = (Potassium ion (1+) bullet 4Methyl Alcohol)

By formula: (K+ bullet 3CH4O) + CH4O = (K+ bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar12.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet 2Methyl Alcohol bullet Water)

By formula: (K+ bullet CH4O bullet H2O) + CH4O = (K+ bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet 2Methyl Alcohol bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet 3Methyl Alcohol bullet Water)

By formula: (K+ bullet 2CH4O bullet H2O) + CH4O = (K+ bullet 3CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar12.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet Methyl Alcohol bullet Water)

By formula: (K+ bullet H2O) + CH4O = (K+ bullet CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar19.6kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.5cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet 2Water) + Methyl Alcohol = (Potassium ion (1+) bullet Methyl Alcohol bullet 2Water)

By formula: (K+ bullet 2H2O) + CH4O = (K+ bullet CH4O bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar16.6kcal/molHPMSEvans and Keesee, 1991gas phase; switching reaction,n(K+)3H2O; M
Quantity Value Units Method Reference Comment
Deltar30.9cal/mol*KHPMSEvans and Keesee, 1991gas phase; switching reaction,n(K+)3H2O; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar38.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar38.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar30.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Magnesium ion (1+) + Methyl Alcohol = (Magnesium ion (1+) bullet Methyl Alcohol)

By formula: Mg+ + CH4O = (Mg+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar61. ± 5.kcal/molPDissOperti, Tews, et al., 1988gas phase; M

(Magnesium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 2Methyl Alcohol)

By formula: (Mg+ bullet CH4O) + CH4O = (Mg+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar28.8 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 3Methyl Alcohol)

By formula: (Mg+ bullet 2CH4O) + CH4O = (Mg+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Nitrogen oxide anion + Methyl Alcohol = (Nitrogen oxide anion bullet Methyl Alcohol)

By formula: NO2- + CH4O = (NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.40 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.8cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.70 ± 0.40kcal/molTDAsSieck, 1985gas phase; B

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) bullet Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar23.2 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar21.9 ± 1.4kcal/molCIDTArmentrout and Rodgers, 2000RCD
Deltar24.0 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
Deltar26.6 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar20500.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
Deltar24.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 2Methyl Alcohol)

By formula: (Na+ bullet CH4O) + CH4O = (Na+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar21.4 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar20.5 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar20.2 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 3Methyl Alcohol)

By formula: (Na+ bullet 2CH4O) + CH4O = (Na+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar17.4 ± 0.4kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) bullet 3Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 4Methyl Alcohol)

By formula: (Na+ bullet 3CH4O) + CH4O = (Na+ bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar15.7 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.0cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Oxygen anion + Methyl Alcohol = (Oxygen anion bullet Methyl Alcohol)

By formula: O2- + CH4O = (O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar19.10kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.50kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Oxygen anion bullet Methyl Alcohol) + Methyl Alcohol = (Oxygen anion bullet 2Methyl Alcohol)

By formula: (O2- bullet CH4O) + CH4O = (O2- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar15.50 ± 0.80kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.10 ± 0.40kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Oxygen anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Oxygen anion bullet 3Methyl Alcohol)

By formula: (O2- bullet 2CH4O) + CH4O = (O2- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar13.50 ± 0.70kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.9cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.30kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Lead ion (1+) + Methyl Alcohol = (Lead ion (1+) bullet Methyl Alcohol)

By formula: Pb+ + CH4O = (Pb+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar23.3 ± 0.2kcal/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.3cal/mol*KHPMSGuo and Castleman, 1990gas phase; M

(Lead ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Lead ion (1+) bullet 2Methyl Alcohol)

By formula: (Pb+