Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Methyl Alcohol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 151 to 200

C10H4Cl2O2- + Methyl Alcohol = (C10H4Cl2O2- bullet Methyl Alcohol)

By formula: C10H4Cl2O2- + CH4O = (C10H4Cl2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar<1.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.5343.PHPMSChowdhury, 1987gas phase; DG<; M

CH6N+ + Methyl Alcohol = (CH6N+ bullet Methyl Alcohol)

By formula: CH6N+ + CH4O = (CH6N+ bullet CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

1,1,1-Trimethoxy-2-methylpropane + Water = Methyl isobutyrate + 2Methyl Alcohol

By formula: C7H16O3 + H2O = C5H10O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-7.799 ± 0.017kcal/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane; ALS
Deltar-12.72 ± 0.28kcal/molEqkGuthrie and Cullimore, 1980liquid phase; ALS

1,4-Naphthalenedione anion + Methyl Alcohol = (1,4-Naphthalenedione anion bullet Methyl Alcohol)

By formula: C10H6O2- + CH4O = (C10H6O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.6343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.8343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.0 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.0343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Methyl Alcohol = (C6H4ClNO2- bullet Methyl Alcohol)

By formula: C6H4ClNO2- + CH4O = (C6H4ClNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.6343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Methyl Alcohol = (C7H7NO2- bullet Methyl Alcohol)

By formula: C7H7NO2- + CH4O = (C7H7NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Methyl Alcohol = (C7H7NO2- bullet Methyl Alcohol)

By formula: C7H7NO2- + CH4O = (C7H7NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.5343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.3343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.3343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Methyl Alcohol = (C6H4N2O4- bullet Methyl Alcohol)

By formula: C6H4N2O4- + CH4O = (C6H4N2O4- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.8343.PHPMSChowdhury, 1987gas phase; M

C6F4O2- + Methyl Alcohol = (C6F4O2- bullet Methyl Alcohol)

By formula: C6F4O2- + CH4O = (C6F4O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar3.0 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.0343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Methyl Alcohol = (p-Benzoquinone anion bullet Methyl Alcohol)

By formula: C6H4O2- + CH4O = (C6H4O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar5.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.5343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C4H2O3- + Methyl Alcohol = (C4H2O3- bullet Methyl Alcohol)

By formula: C4H2O3- + CH4O = (C4H2O3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7343.PHPMSChowdhury, 1987gas phase; M

C8H9NO2- + Methyl Alcohol = (C8H9NO2- bullet Methyl Alcohol)

By formula: C8H9NO2- + CH4O = (C8H9NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Methyl Alcohol = (C7H7NO3- bullet Methyl Alcohol)

By formula: C7H7NO3- + CH4O = (C7H7NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar6.1 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1343.PHPMSChowdhury, 1987gas phase; M

(Potassium ion (1+) bullet Water bullet Methyl Alcohol) + Water = (Potassium ion (1+) bullet 2Water bullet Methyl Alcohol)

By formula: (K+ bullet H2O bullet CH4O) + H2O = (K+ bullet 2H2O bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

2-Butene, 2-methyl- + Methyl Alcohol = Butane, 2-methoxy-2-methyl-

By formula: C5H10 + CH4O = C6H14O

Quantity Value Units Method Reference Comment
Deltar-7.84kcal/molEqkSerda, Izquierdo, et al., 1995liquid phase; ALS
Deltar-6.41 ± 0.55kcal/molEqkRihko, Linnekoski, et al., 1994liquid phase; solvent: Alcohol/alkane mixture; ALS

(Potassium ion (1+) bullet 2Methyl Alcohol bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet 3Methyl Alcohol bullet Water)

By formula: (K+ bullet 2CH4O bullet H2O) + CH4O = (K+ bullet 3CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar12.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet 2Methyl Alcohol bullet Water)

By formula: (K+ bullet CH4O bullet H2O) + CH4O = (K+ bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.5kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol bullet Water)

By formula: (Cl- bullet CH4O bullet H2O) + CH4O = (Cl- bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(CH3O- bullet Water) + Methyl Alcohol = (CH3O- bullet Methyl Alcohol bullet Water)

By formula: (CH3O- bullet H2O) + CH4O = (CH3O- bullet CH4O bullet H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.7296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(CH3O-)2H2O; Meot-Ner(Mautner), 1986; M

(C2H4N+ bullet Acetonitrile bullet 2Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet 2Acetonitrile bullet 2Methyl Alcohol)

By formula: (C2H4N+ bullet C2H3N bullet 2CH4O) + C2H3N = (C2H4N+ bullet 2C2H3N bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar15.6kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

Butane, 1,1-dimethoxy + Water = Butanal + 2Methyl Alcohol

By formula: C6H14O2 + H2O = C4H8O + 2CH4O

Quantity Value Units Method Reference Comment
Deltar8.65 ± 0.03kcal/molCmWiberg, Morgan, et al., 1994liquid phase; ALS
Deltar8.732 ± 0.023kcal/molEqkWiberg and Squires, 1981liquid phase; ALS

(Chlorine anion bullet 2Water) + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol bullet 2Water)

By formula: (Cl- bullet 2H2O) + CH4O = (Cl- bullet CH4O bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar11.4kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.1cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet 2Methyl Alcohol) + Water = (Potassium ion (1+) bullet Water bullet 2Methyl Alcohol)

By formula: (K+ bullet 2CH4O) + H2O = (K+ bullet H2O bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar11.3kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.0cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(C2H4N+ bullet Acetonitrile bullet Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet 2Acetonitrile bullet Methyl Alcohol)

By formula: (C2H4N+ bullet C2H3N bullet CH4O) + C2H3N = (C2H4N+ bullet 2C2H3N bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar7.0kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.4cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

C2H4NO2- + Methyl Alcohol = C3H8NO3-

By formula: C2H4NO2- + CH4O = C3H8NO3-

Quantity Value Units Method Reference Comment
Deltar17.00 ± 0.50kcal/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.5 ± 1.0kcal/molTDAsNieckarz, Atkins, et al., 2008gas phase; B

(Chlorine anion bullet Water) + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol bullet Water)

By formula: (Cl- bullet H2O) + CH4O = (Cl- bullet CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.2kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet Methyl Alcohol) + Water = (Potassium ion (1+) bullet Water bullet Methyl Alcohol)

By formula: (K+ bullet CH4O) + H2O = (K+ bullet H2O bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar15.6kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) bullet Water) + Methyl Alcohol = (Potassium ion (1+) bullet Methyl Alcohol bullet Water)

By formula: (K+ bullet H2O) + CH4O = (K+ bullet CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar19.6kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.5cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

HS- + Methyl Alcohol = (HS- bullet Methyl Alcohol)

By formula: HS- + CH4O = (HS- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.0 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.0 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B

cyclopentadienide anion + Methyl Alcohol = (cyclopentadienide anion bullet Methyl Alcohol)

By formula: C5H5- + CH4O = (C5H5- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar13.2 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.9 ± 1.0kcal/molTDAsMeot-ner, 1988, 2gas phase; B

thiophenoxide anion + Methyl Alcohol = C7H9OS-

By formula: C6H5S- + CH4O = C7H9OS-

Quantity Value Units Method Reference Comment
Deltar13.40 ± 0.10kcal/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.50 ± 0.30kcal/molTDAsSieck and Meot-ner, 1989gas phase; B

(Sodium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 3Methyl Alcohol)

By formula: (Na+ bullet 2CH4O) + CH4O = (Na+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar17.4 ± 0.4kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) bullet 3Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) bullet 4Methyl Alcohol)

By formula: (Na+ bullet 3CH4O) + CH4O = (Na+ bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar15.7 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.0cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(C2H4N+ bullet Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet Acetonitrile bullet Methyl Alcohol)

By formula: (C2H4N+ bullet CH4O) + C2H3N = (C2H4N+ bullet C2H3N bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar22.6kcal/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.5cal/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

(Lead ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Lead ion (1+) bullet 2Methyl Alcohol)

By formula: (Pb+ bullet CH4O) + CH4O = (Pb+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar17.2 ± 0.3kcal/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.6cal/mol*KHPMSGuo and Castleman, 1990gas phase; M

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Deltar17.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.10 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C3H11O3- + Water + 2Methyl Alcohol = C3H13O4-

By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-

Quantity Value Units Method Reference Comment
Deltar13.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.40 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Deltar15.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.90 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase; B

MeCO2 anion + Methyl Alcohol = (MeCO2 anion bullet Methyl Alcohol)

By formula: C2H3O2- + CH4O = (C2H3O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B

(C3H10N+ bullet Methyl Alcohol bullet Methylamine, N,N-dimethyl-) + Methyl Alcohol = (C3H10N+ bullet 2Methyl Alcohol bullet Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ bullet CH4O bullet C3H9N) + CH4O = (C3H10N+ bullet 2CH4O bullet C3H9N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar9.5kcal/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M

(CH3O- bullet 2Methyl Alcohol) + Methyl Alcohol = (CH3O- bullet 3Methyl Alcohol)

By formula: (CH3O- bullet 2CH4O) + CH4O = (CH3O- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar15.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet 3Methyl Alcohol) + Methyl Alcohol = (CH3O- bullet 4Methyl Alcohol)

By formula: (CH3O- bullet 3CH4O) + CH4O = (CH3O- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar11.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Wiberg, Martin, et al., 1985
Wiberg, K.B.; Martin, E.J.; Squires, R.R., Thermochemical studies of carbonyl compounds. 3. Enthalpies of hydrolysis of ortho esters, J. Org. Chem., 1985, 50, 4717-4720. [all data]

Guthrie and Cullimore, 1980
Guthrie, J.P.; Cullimore, P.A., Effect of the acyl substituent on the equilibrium constant for hydration of esters, Can. J. Chem., 1980, 58, 1281-1294. [all data]

Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G., Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions, J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024 . [all data]

Serda, Izquierdo, et al., 1995
Serda, J.A.; Izquierdo, J.F.; Tejero, J.; Cunill, F.; Iborra, M., Equilibrium and thermodynamics for 2-methyl-2-methoxybutane liquid-phase decomposition, Thermochim. Acta, 1995, 259, 111-120. [all data]

Rihko, Linnekoski, et al., 1994
Rihko, L.K.; Linnekoski, J.A.; Krause, A.O., Reaction equilibria in the synthesis of 2-methoxy-2-methylbutane and 2-ethyoxy-2-methylbutane in the liquid phase, J. Chem. Eng. Data, 1994, 39, 700-704. [all data]

MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]

El-Shall, Olafsdottir, et al., 1991
El-Shall, M.S.; Olafsdottir, S.; Meot-ner (Mautner), M.; Sieck, L.W., Energy effects on cluster ion distributions: Beam expansion and thermochemical studies on mixed clusters of methanol and acetonitrile, Chem. Phys. Lett., 1991, 185, 3-4, 193, https://doi.org/10.1016/S0009-2614(91)85046-Y . [all data]

Wiberg, Morgan, et al., 1994
Wiberg, K.B.; Morgan, K.M.; Maltz, H., Thermochemistry of carbonyl reactions. 6. A study of hydration equilibria, J. Am. Chem. Soc., 1994, 116, 11067-11077. [all data]

Wiberg and Squires, 1981
Wiberg, K.B.; Squires, R.R., Thermochemical studies of carbonyl reactions. 2. Steric effects in acetal and ketal hydrolysis, J. Am. Chem. Soc., 1981, 103, 4473-4478. [all data]

Nieckarz, Atkins, et al., 2008
Nieckarz, R.J.; Atkins, C.G.; McMahon, T.B., Effects of Isomerization on the Measured Thermochemical Properties of Deprotonated Glycine/Protic-Solvent Clusters, Chemphyschem, 2008, 9, 18, 2816-2825, https://doi.org/10.1002/cphc.200800525 . [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Meot-ner, 1988, 2
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities., J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079 . [all data]

Guo, Conklin, et al., 1989
Guo, B.C.; Conklin, B.J.; Castleman, A.W., Thermochemical Properties of Ion Complexes Na+(M)n in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 17, 6506, https://doi.org/10.1021/ja00199a005 . [all data]

Guo and Castleman, 1990
Guo, B.C.; Castleman, A.W., The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase, Int. J. Mass Spectrom. Ion Proc., 1990, 100, 665, https://doi.org/10.1016/0168-1176(90)85101-7 . [all data]

El-Shall, Daly, et al., 1992
El-Shall, M.S.; Daly, G.M.; Gao, J.; Meot-Ner (Mautner), M.; Sieck, L.W., How Sensitive are Cluster Compositions to Energetics? A Joint Beam Expansion/ Thermochemical Study of Water - Methanol - Trimethylamine Clusters, J. Phys. Chem., 1992, 96, 2, 507, https://doi.org/10.1021/j100181a002 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References