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Zirconium, dimethylbis[(1,2,3,4,5-«eta»5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C22H36Zr (solution) + 2Iodine (solution) = C20H30I2Zr (solution) + 2Methane, iodo- (solution)

By formula: C22H36Zr (solution) + 2I2 (solution) = C20H30I2Zr (solution) + 2CH3I (solution)

Quantity Value Units Method Reference Comment
Deltar-292.9 ± 2.5kJ/molRSCSchock and Marks, 1988solvent: Toluene

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
6.8PECiliberto, Condorelli, et al., 1981 
7.18PECiliberto, Condorelli, et al., 1981Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schock and Marks, 1988
Schock, L.E.; Marks, T.J., J. Am. Chem. Soc., 1988, 110, 7701. [all data]

Ciliberto, Condorelli, et al., 1981
Ciliberto, E.; Condorelli, G.; Fagan, P.J.; Manriquez, J.M.; Fragala, I.; Marks, T.J., Photoelectron spectroscopy of f-element organometallic complexes. 4. Comparative studies of bis(pentamethylcyclopentadienyl)dichloride and dimethyl complexes of uranium(IV), thorium(IV), and zirconium(IV), J. Am. Chem. Soc., 1981, 103, 4755. [all data]


Notes

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