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H2C=C radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas385. ± 15.kJ/molR-EAErvin, Gronert, et al., 1990Vinylidene neutral: «DELTA»Hf<=99±2 kcal, Kiefer, Sidhu, et al., 1989
Deltafgas260. ± 150.kJ/molIMRBDawson and Nibbering, 1978 
Deltafgas260. ± 150.kJ/molIMRBDawson and Jennings, 1976O- + C2H4 ->, C2H2- + N2O -> CH2CN-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C., Bonds Strengths of Ethylene and Acetylene, J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013 . [all data]

Kiefer, Sidhu, et al., 1989
Kiefer, J.H.; Sidhu, S.S.; Kumaran, S.S.; Irdan, E.A., RRKM Model of C2H4 Dissociation: Heat of Formation of Vinylidene, Chem. Phys. Lett., 1989, 159, 1, 32, https://doi.org/10.1016/S0009-2614(89)87448-2 . [all data]

Dawson and Nibbering, 1978
Dawson, J.H.J.; Nibbering, N.M.M., Concerning CH2=C-. and its reaction with 14N 15NO, J. Am. Chem. Soc., 1978, 100, 1928. [all data]

Dawson and Jennings, 1976
Dawson, J.H.J.; Jennings, K.R., Production of gas phase radical anions by reaction of O-. Ions with organic substrates, J. Chem. Soc. Faraday Trans. 2, 1976, 72, 700. [all data]


Notes

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