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Hexanal

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)9.72 ± 0.05eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.80EIMorgan, Derrick, et al., 1980LLK
9.62 ± 0.02PEAshmore and Burgess, 1978LLK
9.722 ± 0.005PEHernandez, Masclet, et al., 1977LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H4O+11.60C4H8EIMorgan, Derrick, et al., 1980LLK
C3H6O+10.20C3H6EIMorgan, Derrick, et al., 1980LLK
C3H6O+9.72C3H6EIHolmes and Lossing, 1980LLK
C4H8+10.70C2H4OEIMorgan, Derrick, et al., 1980LLK
C4H8O+10.00C2H4EIMorgan, Derrick, et al., 1980LLK
C6H10+9.80H2OEIMorgan, Derrick, et al., 1980LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Morgan, Derrick, et al., 1980
Morgan, R.P.; Derrick, P.J.; Loudon, A.G., Kinetics and mechanisms of the decompositions of the molecular ions of pentanal and its monomethyl- substituted homologues in the picosecond to microsecond time interval following field ionization, J. Chem. Soc. Perkin Trans. 2, 1980, 306. [all data]

Ashmore and Burgess, 1978
Ashmore, F.S.; Burgess, A.R., Photoelectron spectra of the unbranched C5-C7 alkenes, aldehydes and ketones, J. Chem. Soc. Faraday Trans. 2, 1978, 74, 734. [all data]

Hernandez, Masclet, et al., 1977
Hernandez, R.; Masclet, P.; Mouvier, G., Spectroscopie de photoelectrons d'aldehydes et de cetones aliphatiques, J. Electron Spectrosc. Relat. Phenom., 1977, 10, 333. [all data]

Holmes and Lossing, 1980
Holmes, J.L.; Lossing, F.P., Gas-phase heats of formation of keto and enol ions of carbonyl compounds., J. Am. Chem. Soc., 1980, 102, 1591. [all data]


Notes

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