Diethylamine, hydrochloride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

N,N'-Dithiobisdiethylamine + 2Diethylamine, hydrochloride = Sulfur monochloride + 4Ethanamine, N-ethyl-

By formula: C8H20N2S2 + 2C4H12ClN = Cl2S2 + 4C4H11N

Quantity Value Units Method Reference Comment
Δr87.30 ± 0.70kcal/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 88.0 ± 0.7 kcal/mol

Tetraethyl sulphamide + 2Diethylamine, hydrochloride = 4Ethanamine, N-ethyl- + sulphuryl dichloride

By formula: C8H20N2O2S + 2C4H12ClN = 4C4H11N + Cl2O2S

Quantity Value Units Method Reference Comment
Δr130.0 ± 1.7kcal/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 129.8 ± 1.7 kcal/mol

sulphinylbis(diethylamide) + 2Diethylamine, hydrochloride = 4Ethanamine, N-ethyl- + Thionyl chloride

By formula: C8H20N2OS + 2C4H12ClN = 4C4H11N + Cl2OS

Quantity Value Units Method Reference Comment
Δr90.7 ± 1.0kcal/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 93.9 ± 1.0 kcal/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Claydon and Mortimer, 1962
Claydon, A.P.; Mortimer, C.T., Heats of formation and bond energies. Part VIII. Diethylaminotrimethylsilane, NN'-dithiodiethylamine, NN'-thionylbisdiethylamine, and NN'-sulphurylbisdiethylamine, J. Chem. Soc., 1962, 3212-3216. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]


Notes

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