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Benzoic acid

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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Deltacsolid (kcal/mol) Method Reference Comment
-771.5 ± 0.1CcbLi, Gao, et al., 1990Corresponding «DELTA»fsolid = -91.795 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.52 ± 0.11CcbPilcher, Bickerton, et al., 1984Corresponding «DELTA»fsolid = -91.778 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-770.2 ± 1.0CcbHoldiness, 1983Corresponding «DELTA»fsolid = -93.10 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.240 ± 0.043CcbMosselman and Dekker, 1969Corresponding «DELTA»fsolid = -92.063 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-777.894 ± 0.098CcbChurney and Armstrong, 1968Hc =-26434.0±3.3 J/g; Corresponding «DELTA»fsolid = -85.409 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS; Data excluded from overall average
-771.34 ± 0.08CcbCorral, 1960Corresponding «DELTA»fsolid = -91.96 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.367 ± 0.072CcbGundry and Meetham, 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -771.58 kcal/mol; Corresponding «DELTA»fsolid = -91.936 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.32 ± 0.12CcbCoops, Adriaanse, et al., 1956Reanalyzed by Cox and Pilcher, 1970, Original value = -771.1 ± 1. kcal/mol; Corresponding «DELTA»fsolid = -91.984 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.343 ± 0.072CcbChalloner, Gundry, et al., 1955Reanalyzed by Cox and Pilcher, 1970, Original value = -771.630 kcal/mol; Corresponding «DELTA»fsolid = -91.960 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.393 ± 0.076CcbJessup, 1946Corresponding «DELTA»fsolid = -91.910 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.41 ± 0.07CcbProsen and Rossini, 1944Corresponding «DELTA»fsolid = -91.90 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.126 ± 0.076CcbJessup, 1942see Jessup and Green, 1934; Corresponding «DELTA»fsolid = -92.177 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.94CcbMatsui and Abe, 1939Corresponding «DELTA»fsolid = -91.36 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.700CcbHirsbrunner, 1934Corresponding «DELTA»fsolid = -91.603 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-772.31CcbMilone and Rossignoli, 1932Corresponding «DELTA»fsolid = -90.99 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.74CcbBurriel, 1931Corresponding «DELTA»fsolid = -91.56 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-771.1CcbLandrieu, Baylocq, et al., 1929Corresponding «DELTA»fsolid = -92.2 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-772.459CcbWrede, 1911Corresponding «DELTA»fsolid = -90.844 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Gao, et al., 1990
Li, S.; Gao, P.; Yu, X.; Li, X.; He, X., Certification of national research center for certified reference materials (NRCCRM, Beijing) thermochemical standard benzoic acid, J. Chem. Thermodyn., 1990, 22, 319-320. [all data]

Pilcher, Bickerton, et al., 1984
Pilcher, G.; Bickerton, J.; Ribeiro Da Silva, M.M.D.C.C., Certification of B.D.H. thermochemical standard benzoic acid, J. Chem. Thermodyn., 1984, 16, 401-402. [all data]

Holdiness, 1983
Holdiness, M.R., Heats of atomization and resonance energy of some ortho-substituted benzoic acids, Thermochim. Acta, 1983, 71, 257-263. [all data]

Mosselman and Dekker, 1969
Mosselman, C.; Dekker, H., The heat of combustion of benzoic acid - NBS standard sample 391, Recueil, 1969, 88, 161-176. [all data]

Churney and Armstrong, 1968
Churney, K.L.; Armstrong, G.T., Studies in bomb calorimetry. A new determination of the energy of combustion of benzoic acid in terms of electrical units, J. Res. NBS, 1968, 72, 453-465. [all data]

Corral, 1960
Corral, L.B., Investigaciones termoquimicas sobre los acidos toluicos y dimetilbenzoicos, Rev. R. Acad. Cienc., 1960, 54, 365-403. [all data]

Gundry and Meetham, 1958
Gundry, H.A.; Meetham, A.R., Comparison of calorimeters for evaluating the heat of combustion of benzoic acid, Trans. Faraday Soc., 1958, 54, 665-670. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Coops, Adriaanse, et al., 1956
Coops, J.; Adriaanse, N.; Van Nes, K., The absolute heat of combustion of benzoic acid, Rec. Trav. Chim. Pays/Bas, 1956, 75, 237-253. [all data]

Challoner, Gundry, et al., 1955
Challoner, A.R.; Gundry, H.A.; Meetham, A.R., An electrically calibrated bomb calorimeter, Phil. Trans. Roy. Soc. London, 1955, 247, 553-580. [all data]

Jessup, 1946
Jessup, R.S., Note on the density and heat of combustion of benzoic acid, J. Res. NBS, 1946, 36, 421-423. [all data]

Prosen and Rossini, 1944
Prosen, E.J.; Rossini, F.D., Some experimental data on the heats of combustion of benzoic acid and carbon (graphite), J. Res. NBS, 1944, 33, 439-446. [all data]

Jessup, 1942
Jessup, R.S., Heat of combustion of benzoic acid, with special reference to the standardization of bomb calorimeters, J. Res. NBS, 1942, 29, 247-270. [all data]

Jessup and Green, 1934
Jessup, R.S.; Green, C.B., Heat of combustion of standard sample benzoic acid, J. Res. NBS, 1934, 13, 469-495. [all data]

Matsui and Abe, 1939
Matsui, M.; Abe, T., Arbeitsweise eines adiabatischen calormeters, Bull. Tokyo Univ. Eng., 1939, 8, 339. [all data]

Hirsbrunner, 1934
Hirsbrunner, H., Uber das gleichgewicht der thermischen dissoziation der salicylsaure, Helv. Chim. Acta, 1934, 17, 477-504. [all data]

Milone and Rossignoli, 1932
Milone, M.; Rossignoli, P., Sul calore di combustione di alcune miscele di composti organici, Gazz. Chim. Ital., 1932, 62, 644-655. [all data]

Burriel, 1931
Burriel, F., 7. Estudio fisico-quimico de algunos compuestos organicos solidos a la temperatura ordinaria, que se proponen como patrones de temperatura, An. R. Soc. Esp. Fis. Quim., 1931, 29, 89-125. [all data]

Landrieu, Baylocq, et al., 1929
Landrieu, P.; Baylocq, F.; Johnson, J.R., Etude thermochimique dans la serie furanique, Bull. Soc. Chim. France, 1929, 45, 36-49. [all data]

Wrede, 1911
Wrede, F., Uber die Bestimmung von Berbrennungswarmen mittels der kalorimetrischen Bombe unter Benutzung des Platinwiderstandsthermometers, Z. Phys. Chem. (Leipzig), 1911, 81-94. [all data]


Notes

Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), References