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1,3-Dioxolane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-337.2 ± 1.4kJ/molCcbPihlaja and Heikklia, 1969ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1700.8 ± 1.4kJ/molCcbPihlaja and Heikklia, 1969Corresponding «DELTA»fliquid = -337.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1700.kJ/molCcbFletcher, Mortimer, et al., 1959Corresponding «DELTA»fliquid = -338. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1705.kJ/molCcbSkuratov, Strepikheev, et al., 1957Combustion for liq at 293 K; Corresponding «DELTA»fliquid = -333. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid280.2J/mol*KN/AClegg and Melia, 1969DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
120.84298.15Inglese, Castagnolo, et al., 1981DH
118.0298.Conti, Gianni, et al., 1976DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pihlaja and Heikklia, 1969
Pihlaja, K.; Heikklia, J., Enthalpies of formation of cyclic acetals. 1,3-dioxolane, 2-methyl-1,3-dioxolane, and 2,4-dimethyl-1,3-dioxolanes, Acta Chem. Scand., 1969, 23, 1053-1055. [all data]

Fletcher, Mortimer, et al., 1959
Fletcher, S.E.; Mortimer, C.T.; Springall, H.D., Heats of combustion and molecular structure. Part VII. 1:3-dioxa- and 1:3:5-trioxa-cycloalkanes, J. Chem. Soc., 1959, 580-584. [all data]

Skuratov, Strepikheev, et al., 1957
Skuratov, S.M.; Strepikheev, A.A.; Shtekhter, S.M.; Volokhina, A.V., About the enthalpies of polymerization of cyclic formales, Dokl. Akad. Nauk SSSR, 1957, 117, 263-265. [all data]

Clegg and Melia, 1969
Clegg, G.A.; Melia, T.P., Thermodynamics of polymerization of heterocyclic compounds. Part V. The heat capacity, entropy, enthalpy and free energy of 1,3-dioxolan and poly-1,3-dioxolan, Polymer, 1969, 10(12), 912-922. [all data]

Inglese, Castagnolo, et al., 1981
Inglese, A.; Castagnolo, M.; Dell'Atti, A.; DeGiglio, A., Thermochim. Acta, 1981, 77-87. [all data]

Conti, Gianni, et al., 1976
Conti, G.; Gianni, P.; Matteoli, E.; Mengheri, M., Capacita termiche molari di alcuni composti organici mono- e bifunzionali nel liquido puro e in soluzione acquosa a 25C, Chim. Ind. (Milan), 1976, 58, 225. [all data]


Notes

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