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1,3-Dioxolane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-301.7 ± 2.2kJ/molCcbPihlaja and Heikklia, 1969ALS
Quantity Value Units Method Reference Comment
gas310.5 ± 4.1J/mol*KN/AClegg G.A., 1969This calorimetric value of S(298.15 K) is 10.8 J/mol*K larger than that obtained by statistical calculation [ Dorofeeva O.V., 1992]. However, statistical value agrees well with estimation by difference method [ Dorofeeva O.V., 1992].; GT

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
38.1450.Dorofeeva O.V., 1992p=1 bar.; GT
40.67100.
44.54150.
50.90200.
65.20273.15
71.0 ± 4.0298.15
71.45300.
95.78400.
118.09500.
136.88600.
152.49700.
165.51800.
176.46900.
185.731000.
193.621100.
200.351200.
206.111300.
211.071400.
215.351500.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pihlaja and Heikklia, 1969
Pihlaja, K.; Heikklia, J., Enthalpies of formation of cyclic acetals. 1,3-dioxolane, 2-methyl-1,3-dioxolane, and 2,4-dimethyl-1,3-dioxolanes, Acta Chem. Scand., 1969, 23, 1053-1055. [all data]

Clegg G.A., 1969
Clegg G.A., Thermodynamics of polymerization of heterocyclic compounds. Part V. The heat capacity, entropy, enthalpy and free energy of 1,3-dioxolan and poly-1,3-dioxolan, Polymer, 1969, 10, 912-922. [all data]

Dorofeeva O.V., 1992
Dorofeeva O.V., Ideal gas thermodynamic properties of oxygen heterocyclic compounds. Part 1. Three-membered, four-membered and five-membered rings, Thermochim. Acta, 1992, 194, 9-46. [all data]


Notes

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