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2-Hexenal, 2-ethyl-

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Condensed phase thermochemistry data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-261.3 ± 0.71kJ/molCcbTjebbes, 1960 
Quantity Value Units Method Reference Comment
Deltacliquid-4887.62 ± 0.71kJ/molCcbTjebbes, 1960Corresponding «DELTA»fliquid = -261.2 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil450.2KN/ADykvy, Seprakova, et al., 1961Uncertainty assigned by TRC = 0.3 K; TRC
Tboil444.65KN/AKomarewsky and Kritchevsky, 1943Uncertainty assigned by TRC = 3. K; TRC
Tboil445.15KN/AVon Braun and Manz, 1934Uncertainty assigned by TRC = 2. K; TRC
Tboil441.65KN/AGrignard and Fluchaire, 1928Uncertainty assigned by TRC = 2. K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
344. - 347.0.040Frinton Laboratories Inc., 1986BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
48.4341.AStephenson and Malanowski, 1987Based on data from 326. - 448. K. See also Dykvy, Seprakova, et al., 1961.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118166

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tjebbes, 1960
Tjebbes, J., Heats of combustion of butannal and some related compounds, Acta Chem. Scand., 1960, 14, 180-188. [all data]

Dykvy, Seprakova, et al., 1961
Dykvy, J.; Seprakova, M.; Paulech, J., Chem. Zvesti, 1961, 15, 465. [all data]

Komarewsky and Kritchevsky, 1943
Komarewsky, V.I.; Kritchevsky, T.H., Synthesis of Olefin Hydrocarbons by Catalytic Condensation and Dehydration of Aliphatic Aldehydes, J. Am. Chem. Soc., 1943, 65, 547-8. [all data]

Von Braun and Manz, 1934
Von Braun, J.; Manz, G., The Decomposition of Aldehydes with Metals and Its Catalysis, Chem. Ber., 1934, 67, 1696. [all data]

Grignard and Fluchaire, 1928
Grignard, V.; Fluchaire, M., Suiz les proprietetes condensantes des alcoolates magnesiens mixtures, Ann. Chim. (Paris), 1928, 9, 5. [all data]

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References