SiH3F+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 52400 ± 400 gas Frost, Herring, et al., 1971


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

800 T gas PE Frost, Herring, et al., 1971

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 28900 T gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SiH3 stretch 1470 ± 80 gas PE Frost, Herring, et al., 1971

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 26900 T gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971

Additional references: Jacox, 1994, page 240

Notes

TTentative assignment or approximate value
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Herring, et al., 1971
Frost, D.C.; Herring, F.G.; Katrib, A.; McLean, R.A.N.; Drake, J.E.; Westwood, N.P.C., Photoelectron spectra and bonding in some halosilanes, Can. J. Chem., 1971, 49, 4033. [all data]

Cradock and Whiteford, 1971
Cradock, S.; Whiteford, R.A., Photo-electron spectra of the mono and dihalo silanes and germanes, J. Chem. Soc. Faraday Trans., 1971, 67, 3425. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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