Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Acetic acid

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-115.56 ± 0.086kcal/molCcbSteele, Chirico, et al., 1997ALS
Deltafliquid-115.80 ± 0.05kcal/molCcbLebedeva, 1964ALS
Deltafliquid-115.7 ± 0.1kcal/molCcbEvans and Skinner, 1959ALS
Deltafliquid-116.4kcal/molCmCarson and Skinner, 1949Unpublished result by Rossini; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-209.17 ± 0.081kcal/molCcbSteele, Chirico, et al., 1997Corresponding «DELTA»fliquid = -115.56 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-208.94 ± 0.05kcal/molCcbLebedeva, 1964Corresponding «DELTA»fliquid = -115.79 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-209.0 ± 0.1kcal/molCcbEvans and Skinner, 1959Corresponding «DELTA»fliquid = -115.7 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-208.5kcal/molCcbSchjanberg, 1935Corresponding «DELTA»fliquid = -116.2 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid37.76cal/mol*KN/AMartin and Andon, 1982DH
liquid46.30cal/mol*KN/AParks and Kelley, 1925Extrapolation below 90 K. 76.82 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
29.42298.15Martin and Andon, 1982T = 13 to 450 K. Data also given by equation.; DH
33.39332.Swietoslawski and Zielenkiewicz, 1958Mean value 22 to 96°C.; DH
28.80298.Radulescu and Jula, 1934DH
28.99297.1Neumann, 1932T = 23.9 to 80.5°C. Value is unsmoothed experimental datum.; DH
38.19298.1Parks, Kelley, et al., 1929Extrapolation below 90 K, 42.68 J/mol*K. Revision of previous data.; DH
29.49294.7Parks and Kelley, 1925T = 87 to 295 K. Value is unsmoothed experimental datum.; DH
32.7287. - 335.Pickering, 1895T = 260 to 335 K.; DH
29.52298.von Reis, 1881T = 292 to 358 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1997
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic properties and ideal-gas enthalpies of formation for 2-aminoisobutyric acid (2-methylalanine), acetic acid, (4-methyl-3-penten-2-one), 4-methylpent-1-ene, 2,2'-bis(phenylthio)propane, and glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane), J. Chem. Eng. Data, 1997, 42, 1052-1066. [all data]

Lebedeva, 1964
Lebedeva, N.D., Heats of combustion of monocarboxylic acids, Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 1435-1437. [all data]

Evans and Skinner, 1959
Evans, F.W.; Skinner, H.A., The heat of combustion of acetic acid, Trans. Faraday Soc., 1959, 55, 260-261. [all data]

Carson and Skinner, 1949
Carson, A.S.; Skinner, H.A., 201. Carbon-halogen bond energies in the acetyl halides, J. Chem. Soc., 1949, 936-939. [all data]

Schjanberg, 1935
Schjanberg, E., Die Verbrennungswarmen und die Refraktionsdaten einiger chlorsubstituierter Fettsauren und Ester., Z. Phys. Chem. Abt. A, 1935, 172, 197-233. [all data]

Martin and Andon, 1982
Martin, J.F.; Andon, R.J.L., Thermodynamic properties of organic oxygen compounds. Part LII. Molar heat capacity of ethanoic, propanoic, and butanoic acids, J. Chem. Thermodynam., 1982, 14, 679-688. [all data]

Parks and Kelley, 1925
Parks, G.S.; Kelley, K.K., Thermal data on organic compounds. II. The heat capacities of five organic compounds. The entropies and free energies of some homologous series of aliphatic compounds, J. Am. Chem. Soc., 1925, 47, 2089-2097. [all data]

Swietoslawski and Zielenkiewicz, 1958
Swietoslawski, W.; Zielenkiewicz, A., Mean specific heat of some ternary azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1958, 6, 365-366. [all data]

Radulescu and Jula, 1934
Radulescu, D.; Jula, O., Beiträge zur Bestimmung der Abstufung der Polarität des Aminstickstoffes in den organischen Verbindungen, Z. Phys. Chem., 1934, B26, 390-393. [all data]

Neumann, 1932
Neumann, M.B., Die Untersuchung der Wärmekapazität vom binären System CH3COOH + H2O bei verschiedenen Temperaturen, Z. Phys. Chem., 1932, A158, 258-264. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Pickering, 1895
Pickering, S.U., A comparison of some properties of acetic acid and its chloro- and bromo-derivatives, J. Chem. Soc., 1895, 67, 664-684. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References