Cyclohexanemethanol, 4-ethenyl-α,α,4-trimethyl-3-(1-methylethenyl)-, [1R-(1α,3α,4β)]-


Van Den Dool and Kratz RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20BP-20Supelcowax-10BP-20DB-Wax
Column length (m) 50.50.30.50.60.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.220.220.20.220.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.60.70.60.70.
Tend (C) 220.220.220.220.230.
Heat rate (K/min) 2.2.3.2.2.
Initial hold (min)     2.
Final hold (min) 20.20.15.20.20.
I 2080.2080.2070.2079.2090.
ReferenceBoti, Koukoua, et al., 2007Duquesnoy, Dinh, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Boti J.B., Koukoua G., et al., 2005Choi, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxRTX-WaxSupelcowax-10DB-Wax
Column length (m) 30.60.60.30.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 40.70.60.70.40.
Tend (C) 250.230.230.220.200.
Heat rate (K/min) 3.2.2.3.4.
Initial hold (min)  2.  5.
Final hold (min) 20.20.35.15.20.
I 2058.2086.2052.2073.2063.
ReferenceFanciullino, Gancel, et al., 2005Njoroge, Koaze, et al., 2005Paolini, Costa, et al., 2005Cavaleiro, Salgueiro, et al., 2004Yu, Kim, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxDB-WaxDB-WaxRTX-WaxDB-Wax
Column length (m) 60.60.60.30.60.
Carrier gas HeN2H2HeHe
Substrate      
Column diameter (mm) 0.220.250.320.250.5
Phase thickness (μm) 0.250.250.250.250.32
Tstart (C) 60.70.40.45.40.
Tend (C) 230.230.245.250.290.
Heat rate (K/min) 2.2.1.53.4.
Initial hold (min)  2. 6.2.
Final hold (min) 45.20.20.10.5.
I 2077.2089.2058.2056.2101.
ReferenceCavalli, Tomi, et al., 2003Choi, 2003Gancel, Ollitrault, et al., 2003Mondello, Zappia, et al., 2002Bartley and Jacobs, 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCP-Wax 52CBDB-WaxMegawax
Column length (m) 60.60.25.60.30.
Carrier gas HeHe N2He
Substrate      
Column diameter (mm) 0.530.530.250.250.25
Phase thickness (μm) 1.01.00.150.250.25
Tstart (C) 50.50.40.70.40.
Tend (C) 220.220.220.230.220.
Heat rate (K/min) 3.3.3.2.2.
Initial hold (min)   5.2.6.
Final hold (min)    20.10.
I 2110.2110.2086.2090.2043.
ReferenceBrophy, Goldsack, et al., 2000Brophy, Goldsack, et al., 2000, 2Chagonda, Makanda, et al., 2000Choi and Sawamura, 2000Verzera, Trozzi, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxInnowaxCarbowax 20MCP-Wax 52CBDB-Wax
Column length (m) 60.60.25.50.60.
Carrier gas HeHe H2He
Substrate      
Column diameter (mm) 0.530.250.250.230.25
Phase thickness (μm)  0.250.30.120.25
Tstart (C) 50.50.50.50.50.
Tend (C) 220.180.200.200.180.
Heat rate (K/min) 3.2.53.1.52.5
Initial hold (min)  5.1.10.5.
Final hold (min)   20.10. 
I 2110.2076.2083.2098.2076.
ReferenceBrophy, Goldsack, et al., 1999Stashenko, Cervantes, et al., 1999Bicchi, Fresia, et al., 1997Chyau, Mau, et al., 1996Stashenko, Prada, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase Carbowax 20M
Column length (m) 60.
Carrier gas He
Substrate  
Column diameter (mm) 0.32
Phase thickness (μm)  
Tstart (C) 50.
Tend (C) 225.
Heat rate (K/min) 1.5
Initial hold (min)  
Final hold (min) 80.
I 2076.
ReferenceChen and Ho, 1988
Comment MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boti, Koukoua, et al., 2007
Boti, J.B.; Koukoua, G.; N'Guessan, T.Y.; Casanova, J., Chemical variability of Conyza sumatrensis and Microglossa pyrifolia from Côte d'Ivoire, Flavour Fragr. J., 2007, 22, 1, 27-31, https://doi.org/10.1002/ffj.1743 . [all data]

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Paolini, Costa, et al., 2005
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Cavaleiro, Salgueiro, et al., 2004
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Yu, Kim, et al., 2004
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Cavalli, Tomi, et al., 2003
Cavalli, J.-F.; Tomi, F.; Bernardini, A.-F.; Casanova, J., Composition and chemical variability of the bark oil of Cedrelopsis grevei H. Baillon from Madagascar, Flavour Fragr. J., 2003, 18, 6, 532-538, https://doi.org/10.1002/ffj.1263 . [all data]

Choi, 2003
Choi, H.-S., Character impact odorants of Citrus Hallabong [(C. unshiu Marcov × C. sinensis Osbeck) × C. reticulata Blanco] cold-pressed peel oil, J. Agric. Food Chem., 2003, 51, 9, 2687-2692, https://doi.org/10.1021/jf021069o . [all data]

Gancel, Ollitrault, et al., 2003
Gancel, A.-L.; Ollitrault, P.; Froelicher, Y.; Tomi, F.; Jacquemond, C.; Luro, F.; Brillouet, J.-M., Leaf volatile compounds of seven citrus somatic tetraploid hybrids sharing willow leaf mandarin (Citrus deliciosa Ten.) as their common parent, J. Agric. Food Chem., 2003, 51, 20, 6006-6013, https://doi.org/10.1021/jf0345090 . [all data]

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Brophy, Goldsack, et al., 2000, 2
Brophy, J.J.; Goldsack, R.J.; Punruckvong, A.; Bean, A.R.; Forster, P.I.; Lepschi, B.J.; Doran, J.C.; Rozefelds, A.C., Leaf essential oils of the genus Leptospermum (Myrtaceae) in eastern Australia. Part 7. Leptospermum petersonii, L. liversidgei and allies, Flavour Fragr. J., 2000, 15, 5, 342-351, https://doi.org/10.1002/1099-1026(200009/10)15:5<342::AID-FFJ924>3.0.CO;2-V . [all data]

Chagonda, Makanda, et al., 2000
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Choi and Sawamura, 2000
Choi, H.-S.; Sawamura, M., Composition of the essential oil of Citrus tamurana Hort. ex Tanaka (Hyuganatsu), J. Agric. Food Chem., 2000, 48, 10, 4868-4873, https://doi.org/10.1021/jf000651e . [all data]

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Stashenko, Cervantes, et al., 1999
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Notes

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