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Quinoline, 1,2,3,4-tetrahydro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil522.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil524.KN/APerkin, 1896Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Ttriple289.910KN/ASteele, Chirico, et al., 1989Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Deltavap65.33kJ/molVSteele, Chirico, et al., 1989, 2ALS
Deltavap65.3kJ/molN/ASteele, Chirico, et al., 1989, 2DRB
Deltavap65.3 ± 0.2kJ/molIP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
62.1 ± 0.1340.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC
59.2 ± 0.1380.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC
56.3 ± 0.1420.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC
53.5 ± 0.2460.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC
50.8 ± 0.3500.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC
47.9 ± 0.4540.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 323. - 572. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
11.81290.Acree, 1991AC

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
61.7crystaline, IVcrystaline, IIISteele, Chirico, et al., 1989, 3DH
114.75crystaline, IIIcrystaline, IISteele, Chirico, et al., 1989, 3DH
231.8crystaline, IIcrystaline, ISteele, Chirico, et al., 1989, 3DH

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
11.813289.913crystaline, IliquidSteele, Chirico, et al., 1989, 3DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
40.75289.913crystaline, IliquidSteele, Chirico, et al., 1989, 3DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Perkin, 1896
Perkin, W.H., LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds, J. Chem. Soc., 1896, 69, 1025-1257. [all data]

Steele, Chirico, et al., 1989
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of 1,2,3,4- and 5,6,7,8-tetrahydroquinolines, J. Chem. Thermodyn., 1989, 21, 1121. [all data]

Steele, Chirico, et al., 1989, 2
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of 1,2,3,4- and 5,6,7,8-tetrahydroquinolines, J. Chem. Thermodyn., 1989, 21, 1121-1149. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Steele, Chirico, et al., 1989, 3
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of the five benzoquinolines, J. Chem. Thermodyn., 1989, 21, 81-107. [all data]


Notes

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