1,2,4,5-Benzenetetracarboxylic acid, tetramethyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tfus418.0KN/ADozen, Fujishima, et al., 1978Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Δsub143.3 ± 0.8kJ/molN/AJimenez, Menendez, et al., 1995AC
Δsub79.0kJ/molN/AVan Chin, Dibrivnyi, et al., 1980DRB
Δsub135.9 ± 1.3kJ/molN/ATurrión, 1967See also Jimenez, Menendez, et al., 1995.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
140.4 ± 0.8381.MEJimenez, Menendez, et al., 1995Based on data from 371. to 391. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
35.7416.7DSCAcree, 1993AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dozen, Fujishima, et al., 1978
Dozen, Y.; Fujishima, S.; Shingu, H., Structures and fusion parameters of methoxycarbonyl-benzenes and -naphthalenes, Thermochim. Acta, 1978, 25, 2, 209, https://doi.org/10.1016/0040-6031(78)85008-4 . [all data]

Jimenez, Menendez, et al., 1995
Jimenez, P.; Menendez, V.; Roux, M.V.; Turrion, C., Vapour pressures and enthalpies of sublimation of four polymethoxycarbonylbenzenes, J. Chem. Thermodyn., 1995, 27, 679-683. [all data]

Van Chin, Dibrivnyi, et al., 1980
Van Chin, S.; Dibrivnyi, N.V.; Donchak, V.A., Peroxide bond energy in tetra-tert-butyl peroxypyromellitate, Vestn. L'vov. Politekhn. In-ta, 1980, 18-21. [all data]

Turrión, 1967
Turrión, C., , Presiones de vapor y calores de sublimación de los ácidos bencenecarboxilicos y sus ésteres metilicos. Beca "Juan March" de estudios en España, grupo B, Madrid, 1967. [all data]

Acree, 1993
Acree, William E., Thermodynamic properties of organic compounds, Thermochimica Acta, 1993, 219, 97-104, https://doi.org/10.1016/0040-6031(93)80486-T . [all data]


Notes

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