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2,4,6-trinitro-m-xylene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-19.87kcal/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-22.91
Quantity Value Units Method Reference Comment
Deltacsolid-966.63 ± 0.97kcal/molCcbBadoche, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -967.41 kcal/mol
Deltacsolid-967.32 ± 0.97kcal/molCcbBurlot, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -970.57 kcal/mol
Deltacsolid-971.643kcal/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-22.91

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
31.02 ± 0.26365.MEStephenson and Malanowski, 1987Based on data from 319. - 411. K. See also Cundall, Frank Palmer, et al., 1978.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference
9.199455.4Bell and Sawyer, 1919

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rinkenbach, 1930
Rinkenbach, W.H., The heats of combustion and formation of aromatic nitro compounds, J. Am. Chem. Soc., 1930, 52, 115-120. [all data]

Badoche, 1939
Badoche, M.M., Determinations des chaleurs de combustion de derives nitres de la serie benzenique, Bull. Soc. Chim. France, 1939, 6, 570-579. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Burlot, 1939
Burlot, E., Etude relative a la calorimetrie des explosifs, Mem. Poudres, 1939, 29, 226-260. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Cundall, Frank Palmer, et al., 1978
Cundall, Robert B.; Frank Palmer, T.; Wood, Colin E.C., Vapour pressure measurements on some organic high explosives, J. Chem. Soc., Faraday Trans. 1, 1978, 74, 0, 1339, https://doi.org/10.1039/f19787401339 . [all data]

Bell and Sawyer, 1919
Bell, James M.; Sawyer, James P., Studies on the Nitrotoluenes. I---Binary Systems of a Nitrotoluene and Symmetrical Trinitromet-oxylene., J. Ind. Eng. Chem., 1919, 11, 11, 1025-1028, https://doi.org/10.1021/ie50119a007 . [all data]


Notes

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