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Carbon monoxide

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
MS - José A. Martinho Simões
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 201 to 249

(Titanium ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 4Carbon monoxide)

By formula: (Ti+ bullet 3CO) + CO = (Ti+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar20.8 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 5Carbon monoxide)

By formula: (Ti+ bullet 4CO) + CO = (Ti+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 6Carbon monoxide)

By formula: (Ti+ bullet 5CO) + CO = (Ti+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar17.7 ± 0.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 7Carbon monoxide)

By formula: (Ti+ bullet 6CO) + CO = (Ti+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Platinum ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Platinum ion (1+) bullet 2Carbon monoxide)

By formula: (Pt+ bullet CO) + CO = (Pt+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar46.1 ± 2.4kcal/molCIDTZhang and Armentrout, 2001RCD

C12Fe2O12Ru (cr) = 12Carbon monoxide (g) + 2iron (cr) + ruthenium (cr)

By formula: C12Fe2O12Ru (cr) = 12CO (g) + 2Fe (cr) + Ru (cr)

Quantity Value Units Method Reference Comment
Deltar118. ± 2.kcal/molTD-HFCBaev, Connor, et al., 1981MS

(Titanium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 2Carbon monoxide)

By formula: (Ti+ bullet CO) + CO = (Ti+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

Molybdenum hexacarbonyl (cr) + 31,3-Diazine (g) = C18H15MoN3O3 (cr) + 3Carbon monoxide (g)

By formula: C6MoO6 (cr) + 3C4H4N2 (g) = C18H15MoN3O3 (cr) + 3CO (g)

Quantity Value Units Method Reference Comment
Deltar-12.0 ± 1.7kcal/molHFCAdedeji, Connor, et al., 1978MS

Rhodium, bis(η2-ethene)(2,4-pentanedionato-O,O')- (cr) + 2Carbon monoxide (g) = Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-, (SP-4-2)- (cr) + 2Ethylene (g)

By formula: C9H15O2Rh (cr) + 2CO (g) = C7H7O4Rh (cr) + 2C2H4 (g)

Quantity Value Units Method Reference Comment
Deltar-12.8 ± 0.41kcal/molDSCJesse, Baks, et al., 1978MS

C9H15IrO2 (cr) + 2Carbon monoxide (g) = C7H7IrO4 (cr) + 2Ethylene (g)

By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)

Quantity Value Units Method Reference Comment
Deltar-17.7 ± 1.1kcal/molDSCJesse, Baks, et al., 1978MS

(Magnesium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) bullet 2Carbon monoxide)

By formula: (Mg+ bullet CO) + CO = (Mg+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Tungsten hexacarbonyl (cr) + 31,3-Diazine (g) = C18H15N3O3W (g) + 3Carbon monoxide (g)

By formula: C6O6W (cr) + 3C4H4N2 (g) = C18H15N3O3W (g) + 3CO (g)

Quantity Value Units Method Reference Comment
Deltar-13.1 ± 2.0kcal/molHFCAdedeji, Connor, et al., 1978MS

C3MnO3 + Carbon monoxide = C3MnO3-

By formula: C3MnO3 + CO = C3MnO3-

Quantity Value Units Method Reference Comment
Deltar28.4 ± 3.0kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C3O3V + Carbon monoxide = C3O3V-

By formula: C3O3V + CO = C3O3V-

Quantity Value Units Method Reference Comment
Deltar35.8 ± 4.4kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

Pt4- + Carbon monoxide = (Pt4- bullet Carbon monoxide)

By formula: Pt4- + CO = (Pt4- bullet CO)

Quantity Value Units Method Reference Comment
Deltar60.0 ± 9.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

Pt5- + Carbon monoxide = (Pt5- bullet Carbon monoxide)

By formula: Pt5- + CO = (Pt5- bullet CO)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 9.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

C7H5CrO2- + Carbon monoxide = C8H5CrO3-

By formula: C7H5CrO2- + CO = C8H5CrO3-

Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.80kcal/molN/ASunderlin and Squires, 1999gas phase; B

C7H5O2V- + Carbon monoxide = C8H5O3V-

By formula: C7H5O2V- + CO = C8H5O3V-

Quantity Value Units Method Reference Comment
Deltar7.60 ± 0.60kcal/molN/ASunderlin and Squires, 1999gas phase; B

C7H5O2V- + Carbon monoxide = C7H5O2V-

By formula: C7H5O2V- + CO = C7H5O2V-

Quantity Value Units Method Reference Comment
Deltar7.90 ± 0.70kcal/molN/ASunderlin and Squires, 1999gas phase; B

C6H5MnO- + Carbon monoxide = C7H5MnO2-

By formula: C6H5MnO- + CO = C7H5MnO2-

Quantity Value Units Method Reference Comment
Deltar7.80 ± 0.60kcal/molN/ASunderlin and Squires, 1999gas phase; B

C6H5MnO- + Carbon monoxide = C6H5MnO-

By formula: C6H5MnO- + CO = C6H5MnO-

Quantity Value Units Method Reference Comment
Deltar5.00 ± 0.50kcal/molN/ASunderlin and Squires, 1999gas phase; B

CAS Reg. No. 501416-66-6 + Carbon monoxide = C7H5FeO2-

By formula: CAS Reg. No. 501416-66-6 + CO = C7H5FeO2-

Quantity Value Units Method Reference Comment
Deltar8.20 ± 0.70kcal/molN/ASunderlin and Squires, 1999gas phase; B

C3O3V- + Carbon monoxide = C4O4V-

By formula: C3O3V- + CO = C4O4V-

Quantity Value Units Method Reference Comment
Deltar40.4 ± 5.8kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C4O4V- + Carbon monoxide = C5O5V-

By formula: C4O4V- + CO = C5O5V-

Quantity Value Units Method Reference Comment
Deltar31.1 ± 3.0kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C5O5V- + Carbon monoxide = C6O6V-

By formula: C5O5V- + CO = C6O6V-

Quantity Value Units Method Reference Comment
Deltar30.8 ± 3.5kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C3MnO3- + Carbon monoxide = C4MnO4-

By formula: C3MnO3- + CO = C4MnO4-

Quantity Value Units Method Reference Comment
Deltar41.1 ± 3.0kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C10H5CrNO5 (cr) + Carbon monoxide (g) = Chromium hexacarbonyl (g) + 1,3-Diazine (g)

By formula: C10H5CrNO5 (cr) + CO (g) = C6CrO6 (g) + C4H4N2 (g)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kcal/molDSCDaamen, van der Poel, et al., 1979MS

CAS Reg. No. 151247-66-4 + Carbon monoxide = COPt6-

By formula: CAS Reg. No. 151247-66-4 + CO = COPt6-

Quantity Value Units Method Reference Comment
Deltar53.0 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

C6O6Pt4- + Carbon monoxide = C8O8Pt4-

By formula: C6O6Pt4- + CO = C8O8Pt4-

Quantity Value Units Method Reference Comment
Deltar18.4 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

C10H5MoNO5 (cr) + Carbon monoxide (g) = Molybdenum hexacarbonyl (g) + 1,3-Diazine (g)

By formula: C10H5MoNO5 (cr) + CO (g) = C6MoO6 (g) + C4H4N2 (g)

Quantity Value Units Method Reference Comment
Deltar14. ± 0.7kcal/molDSCDaamen, van der Poel, et al., 1979MS

Manganese, acetylpentacarbonyl-, (OC-6-21)- (cr) = Manganese, pentacarbonylmethyl- (g) + Carbon monoxide (g)

By formula: C7H3MnO6 (cr) = C6H3MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar28.5 ± 0.2kcal/molTD-HFCConnor, Zafarani-Moattar, et al., 1982MS

C4FeI2O4 (cr) = 4Carbon monoxide (g) + FeI2 (cr)

By formula: C4FeI2O4 (cr) = 4CO (g) + FeI2 (cr)

Quantity Value Units Method Reference Comment
Deltar39.03 ± 0.24kcal/molTD-HFCConnor, Demain, et al., 1979MS

Platinum ion (1+) + Carbon monoxide = (Platinum ion (1+) bullet Carbon monoxide)

By formula: Pt+ + CO = (Pt+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar50.7 ± 2.4kcal/molCIDTZhang and Armentrout, 2001RCD

C7F3MnO6 (cr) = C6F3MnO5 (g) + Carbon monoxide (g)

By formula: C7F3MnO6 (cr) = C6F3MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar21.7 ± 0.2kcal/molTD-HFCConnor, Zafarani-Moattar, et al., 1982MS

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) bullet Carbon monoxide)

By formula: Ti+ + CO = (Ti+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar28.2 ± 1.4kcal/molCIDTMeyer and Armentrout, 1996RCD

Hydrogen + Carbon monoxide = Formaldehyde

By formula: H2 + CO = CH2O

Quantity Value Units Method Reference Comment
Deltar-2.90kcal/molEqkNewton and Dodge, 1933gas phase; ALS

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) bullet Carbon monoxide)

By formula: Mg+ + CO = (Mg+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Potassium ion (1+) + Carbon monoxide = (Potassium ion (1+) bullet Carbon monoxide)

By formula: K+ + CO = (K+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar4.3 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

C12H5MnO6 (cr) = C11H5MnO5 (g) + Carbon monoxide (g)

By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar35.4 ± 0.7kcal/molTD-HFCConnor, Zafarani-Moattar, et al., 1982MS

Pt3- + Carbon monoxide = COPt3-

By formula: Pt3- + CO = COPt3-

Quantity Value Units Method Reference Comment
Deltar53.0 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

C3O3Pt3- + Carbon monoxide = C4O4Pt3-

By formula: C3O3Pt3- + CO = C4O4Pt3-

Quantity Value Units Method Reference Comment
Deltar24.4 ± 3.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

C4O4Pt3- + Carbon monoxide = C5O5Pt3-

By formula: C4O4Pt3- + CO = C5O5Pt3-

Quantity Value Units Method Reference Comment
Deltar26.1 ± 4.4kcal/molN/AGrushow and Ervin, 1997gas phase; B

Formamide = Carbon monoxide + Ammonia

By formula: CH3NO = CO + H3N

Quantity Value Units Method Reference Comment
Deltar7.02kcal/molEqkBauder and Gunthard, 1958gas phase; ALS

Chromium hexacarbonyl (g) = 3Carbon monoxide (g) + C3CrO3 (g)

By formula: C6CrO6 (g) = 3CO (g) + C3CrO3 (g)

Quantity Value Units Method Reference Comment
Deltar94. ± 10.kcal/molMBPSVenkataraman, Hou, et al., 1990MS

COPt3- + Carbon monoxide = C2O2Pt3-

By formula: COPt3- + CO = C2O2Pt3-

Quantity Value Units Method Reference Comment
Deltar53. ± 12.kcal/molN/AGrushow and Ervin, 1997gas phase; B

Molybdenum hexacarbonyl (g) = C3MoO3 (g) + 3Carbon monoxide (g)

By formula: C6MoO6 (g) = C3MoO3 (g) + 3CO (g)

Quantity Value Units Method Reference Comment
Deltar105. ± 10.kcal/molMBPSVenkataraman, Hou, et al., 1990MS

Tungsten hexacarbonyl (g) = C3O3W (g) + 3Carbon monoxide (g)

By formula: C6O6W (g) = C3O3W (g) + 3CO (g)

Quantity Value Units Method Reference Comment
Deltar111. ± 10.kcal/molMBPSVenkataraman, Hou, et al., 1990MS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meyer and Armentrout, 1996
Meyer, F.; Armentrout, P.B., Sequential Bond Energies of Ti(CO)x+, x=1-7, Molec. Phys., 1996, 88, 187. [all data]

Zhang and Armentrout, 2001
Zhang, X.-G.; Armentrout, P.B., Sequential Bond Energies of Pt(CO)x, (x=1-4) Determined by Collision-Induced Dissociation, Organometallics, 2001, 20, 20, 4266, https://doi.org/10.1021/om010390d . [all data]

Baev, Connor, et al., 1981
Baev, A.K.; Connor, J.A.; El-Saied, N.I.; Skinner H.A., J. Organometal. Chem., 1981, 213, 151. [all data]

Adedeji, Connor, et al., 1978
Adedeji, F.A.; Connor, J.A.; Demain, C.P.; Martinho Simões, J.A.; Skinner, H.A.; Zafarani- Moattar, M.T., J. Organometal. Chem., 1978, 149, 333. [all data]

Jesse, Baks, et al., 1978
Jesse, A.C.; Baks, A.; Stufkens, D.J.; Vrieze, K., Inorg. Chim. Acta, 1978, 29, 177. [all data]

Andersen, Muntean, et al., 2000
Andersen, A.; Muntean, F.; Walter, D.; Rue, C.; Armentrout, P.B., Collision-Induced Dissociation and Theoretical Studies of Mg+ Complexes with CO, CO2, NH3, CH4, CH3OH, and C6H6, J. Phys. Chem. A, 2000, 104, 4, 692, https://doi.org/10.1021/jp993031t . [all data]

Sunderlin, Wang, et al., 1993
Sunderlin, L.S.; Wang, D.N.; Squires, R.R., Bond Strengths in 1st-Row-Metal Carbonyl Anions, J. Am. Chem. Soc., 1993, 115, 25, 12060, https://doi.org/10.1021/ja00078a051 . [all data]

Grushow and Ervin, 1997
Grushow, A.; Ervin, K.M., Ligand and Metal Binding Energies in Platinum Carbonyl Cluster Anions: Collision Induced Dissociation of PtM- and Ptm(CO)n-, J. Chem. Phys., 1997, 106, 23, 9580, https://doi.org/10.1063/1.474116 . [all data]

Sunderlin and Squires, 1999
Sunderlin, L.S.; Squires, R.R., Bond strengths in cyclopentadienyl metal carbonyl anions, Int. J. Mass Spectrom., 1999, 183, 149-161, https://doi.org/10.1016/S1387-3806(98)14230-6 . [all data]

Daamen, van der Poel, et al., 1979
Daamen, H.; van der Poel, H.; Stufkens, D.J.; Oskam, A., Thermochim. Acta, 1979, 34, 69. [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Connor, Demain, et al., 1979
Connor, J.A.; Demain, C.P.; Skinner, H.A.; Zafarani-Moattar, M.T., J. Orgnometal. Chem., 1979, 170, 117. [all data]

Newton and Dodge, 1933
Newton, R.H.; Dodge, B.F., The equilibrium between carbon monoxide, hydrogen, formaldehyde and methanol. I. The reactions CO + H2 = HCOH and H2 + HCOH = CH3OH, J. Am. Chem. Soc., 1933, 55, 4747-4759. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Bauder and Gunthard, 1958
Bauder, A.; Gunthard, Hs.H., Thermodynamische Eigenschaften von Formamid, Helv. Chim. Acta, 1958, 41, 670-673. [all data]

Venkataraman, Hou, et al., 1990
Venkataraman, B.; Hou, H.; Zhang, Z.; Chen, S.; Bandukwalla, G.; Vernon, M., J. Chem. Phys., 1990, 92, 5338. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References