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Nonadecane

Data at NIST subscription sites:

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil602.9KN/AWeast and Grasselli, 1989BS
Tboil601.7KN/AIvanov, Ivanov, et al., 1954Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus304. ± 3.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Tc755. ± 8.KN/AAmbrose and Tsonopoulos, 1995 
Tc755.3KN/ANikitin, Pavlov, et al., 1994Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Pc12. ± 2.barN/AAmbrose and Tsonopoulos, 1995 
Pc11.60barN/ANikitin, Pavlov, et al., 1994Uncertainty assigned by TRC = 0.40 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap96.4kJ/molN/ARuzicka and Majer, 1994AC
Deltavap95.8kJ/molN/AReid, 1972AC
Quantity Value Units Method Reference Comment
Deltasub143.6kJ/molCMorawetz, 1972AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
76.2438.N/AMorgan and Kobayashi, 1994Based on data from 423. - 588. K.; AC
73.0471.AStephenson and Malanowski, 1987Based on data from 456. - 606. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
306. - 328.30.4281628197.488452.785Morecroft, 1964Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Reference Comment
136.6296.Morecroft, 1964Based on data from 288. - 303. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
42.7304.4DSCMondieig, Rajabalee, et al., 2004AC
47.4305.3N/ADomalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
46.2296.0Domalski and Hearing, 1996CAL
155.9304.

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
13.750296.1crystaline, IIcrystaline, IBarbillon, Schuffenecker, et al., 1991DH
43.750305.1crystaline, IliquidBarbillon, Schuffenecker, et al., 1991DH
13.665295.95crystaline, IIcrystaline, IClaudy, Letoffe, et al., 1979DH
47.395303.95crystaline, IliquidClaudy, Letoffe, et al., 1979DH
13.807295.95crystaline, IIcrystaline, ISchaerer, Busso, et al., 1955DH
45.815305.15crystaline, IliquidSchaerer, Busso, et al., 1955DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
46.2295.95crystaline, IIcrystaline, IClaudy, Letoffe, et al., 1979DH
155.9303.95crystaline, IliquidClaudy, Letoffe, et al., 1979DH
46.7295.95crystaline, IIcrystaline, ISchaerer, Busso, et al., 1955DH
150.1305.15crystaline, IliquidSchaerer, Busso, et al., 1955DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Ivanov, Ivanov, et al., 1954
Ivanov, D.; Ivanov, Ch.; Stoianova-Ivanova, B., Composistion of Stearoptene from Bulgarian Rose Oil. II. Saturated Hydrocarbons Other Than Eicosane, Dokl. Bolg. Akad. Nauk, 1954, 7, 17-20. [all data]

Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C., Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes, J. Chem. Eng. Data, 1995, 40, 531-546. [all data]

Nikitin, Pavlov, et al., 1994
Nikitin, E.D.; Pavlov, P.A.; Bessonova, N.V., Critical constants of n-alkanes with from 17 to 24 carbon atoms, J. Chem. Thermodyn., 1994, 26, 177-82. [all data]

Ruzicka and Majer, 1994
Ruzicka, Kvetoslav; Majer, Vladimir, Simultaneous Treatment of Vapor Pressures and Related Thermal Data Between the Triple and Normal Boiling Temperatures for n-Alkanes C5--C20, J. Phys. Chem. Ref. Data, 1994, 23, 1, 1, https://doi.org/10.1063/1.555942 . [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Morawetz, 1972
Morawetz, Ernst, Correlation of sublimation enthalpies at 298.15 K with molecular structure for planar aromatic hydrocarbons, The Journal of Chemical Thermodynamics, 1972, 4, 3, 461-467, https://doi.org/10.1016/0021-9614(72)90030-4 . [all data]

Morgan and Kobayashi, 1994
Morgan, David L.; Kobayashi, Riki, Direct vapor pressure measurements of ten n-alkanes m the 10-C28 range, Fluid Phase Equilibria, 1994, 97, 211-242, https://doi.org/10.1016/0378-3812(94)85017-8 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Morecroft, 1964
Morecroft, D.W., Vapor Pressures of Some High Molecular Weight Hydrocarbons., J. Chem. Eng. Data, 1964, 9, 4, 488-490, https://doi.org/10.1021/je60023a003 . [all data]

Mondieig, Rajabalee, et al., 2004
Mondieig, D.; Rajabalee, F.; Metivaud, V.; Oonk, H.A.J.; Cuevas-Diarte, M.A., n -Alkane Binary Molecular Alloys, Chem. Mater., 2004, 16, 5, 786-798, https://doi.org/10.1021/cm031169p . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Barbillon, Schuffenecker, et al., 1991
Barbillon, P.; Schuffenecker, L.; Dellacherie, J.; Balesdent, D.; Dirande, M., Variation d'enthalpie subie de 260 K a 340 K par les n-paraffines, comprises entrel'octadecane et l'hexacosane, J. Chim. Phys. Phys.-Chim. Biol., 1991, 88, 91-113. [all data]

Claudy, Letoffe, et al., 1979
Claudy, P.; Letoffe, J.M.; Bousquet, J., Use of a transitory-state flow calorimeter for determining transition enthalpies and calorific capacities, Journ. Calorim. Anal. Therm.(Prepr.), 1979, 10, AD. [all data]

Schaerer, Busso, et al., 1955
Schaerer, A.A.; Busso, C.J.; Smith, A.E.; Skinner, L.B., Properties of pure normal alkanes in the C17 to C36 range, J. Am. Chem. Soc., 1955, 77, 2017-2019. [all data]


Notes

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