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Cetene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-248.4 ± 2.5kJ/molCcrStridh, 1976Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -250.2 ± 3.0 kJ/mol; ALS
Deltafgas-247.2 ± 2.6kJ/molCcbLoeffler and Rossini, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -243.3 ± 3.3 kJ/mol; ALS
Deltafgas-249.3kJ/molN/AFraser and Prosen, 1955Value computed using «DELTA»fHliquid° value of -329.4±2.1 kj/mol from Fraser and Prosen, 1955 and «DELTA»vapH° value of 80.1 kj/mol from Loeffler and Rossini, 1960.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-330.5 ± 3.0kJ/molCcrStridh, 1976ALS
Deltafliquid-327.3 ± 2.5kJ/molCcbLoeffler and Rossini, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -323.4 ± 3.3 kJ/mol; ALS
Deltafliquid-329.4 ± 2.1kJ/molCcbFraser and Prosen, 1955ALS
Quantity Value Units Method Reference Comment
Deltacliquid-10539.0 ± 2.0kJ/molCcrStridh, 1976Corresponding «DELTA»fliquid = -330.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-10540. ± 2.kJ/molCcbFraser and Prosen, 1955Corresponding «DELTA»fliquid = -329.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid613.88J/mol*KN/AMesserly, Todd, et al., 1990DH
liquid587.90J/mol*KN/AMcCullough, Finke, et al., 1957Does not include S0.; DH
Quantity Value Units Method Reference Comment
Deltacsolid-10546.0 ± 3.1kJ/molCcbLoeffler and Rossini, 1960Corresponding «DELTA»fsolid = -323.43 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
485.83298.15Messerly, Todd, et al., 1990T = 10 to 400 K.; DH
488.88298.15McCullough, Finke, et al., 1957T = 11 to 360 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Cetene = Hexadecane

By formula: H2 + C16H32 = C16H34

Quantity Value Units Method Reference Comment
Deltar-123.8 ± 1.8kJ/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stridh, 1976
Stridh, G., Enthalpies of formation of 1-dodecene and 1-hexadecene and the CH2-increment in the 1-alkene series, J. Chem. Thermodyn., 1976, 8, 895-899. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Loeffler and Rossini, 1960
Loeffler, S.M.C.; Rossini, F.D., Heats of combustion and formation of the higher normal alkyl cyclopentanes, cyclohexanes, benzenes and 1-alkenes in the liquid state at 25°, J. Phys. Chem., 1960, 64, 1530-1533. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Fraser and Prosen, 1955
Fraser, F.M.; Prosen, E.J., Heats of combustion of liquid n-hexadecane, 1-hexadecene, n-decylbenzene, n-decylcyclohexane, n-decylcyclopentane, and the variation of heat of combustion with chain length, J. Res. NBS, 1955, 55, 329-333. [all data]

Messerly, Todd, et al., 1990
Messerly, J.F.; Todd, S.S.; Finke, H.L.; Lee-Bechtold, S.H.; Guthrie, G.B.; Steele, W.V.; Chirico, R.D., Heat capacities of pent-1-ene (10K to 320K), cis-hex-2-ene (10K to 330K), non-1-ene (10K to 400K), and hexadec-1-ene (10K to 400K), J. Chem. Thermodynam., 1990, 22, 1107-1128. [all data]

McCullough, Finke, et al., 1957
McCullough, J.P.; Finke, H.L.; Gross, M.E.; Messerly, J.F.; Waddington, G., Low temperature calorimetric studies of seven 1-olefins: effect of orientational disorder in the solid state, J. Phys. Chem., 1957, 61, 289-301. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]


Notes

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