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Cetene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-330.5 ± 3.0kJ/molCcrStridh, 1976ALS
Deltafliquid-327.3 ± 2.5kJ/molCcbLoeffler and Rossini, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -323.4 ± 3.3 kJ/mol; ALS
Deltafliquid-329.4 ± 2.1kJ/molCcbFraser and Prosen, 1955ALS
Quantity Value Units Method Reference Comment
Deltacliquid-10539.0 ± 2.0kJ/molCcrStridh, 1976Corresponding «DELTA»fliquid = -330.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-10540. ± 2.kJ/molCcbFraser and Prosen, 1955Corresponding «DELTA»fliquid = -329.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid613.88J/mol*KN/AMesserly, Todd, et al., 1990DH
liquid587.90J/mol*KN/AMcCullough, Finke, et al., 1957Does not include S0.; DH
Quantity Value Units Method Reference Comment
Deltacsolid-10546.0 ± 3.1kJ/molCcbLoeffler and Rossini, 1960Corresponding «DELTA»fsolid = -323.43 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
485.83298.15Messerly, Todd, et al., 1990T = 10 to 400 K.; DH
488.88298.15McCullough, Finke, et al., 1957T = 11 to 360 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stridh, 1976
Stridh, G., Enthalpies of formation of 1-dodecene and 1-hexadecene and the CH2-increment in the 1-alkene series, J. Chem. Thermodyn., 1976, 8, 895-899. [all data]

Loeffler and Rossini, 1960
Loeffler, S.M.C.; Rossini, F.D., Heats of combustion and formation of the higher normal alkyl cyclopentanes, cyclohexanes, benzenes and 1-alkenes in the liquid state at 25°, J. Phys. Chem., 1960, 64, 1530-1533. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Fraser and Prosen, 1955
Fraser, F.M.; Prosen, E.J., Heats of combustion of liquid n-hexadecane, 1-hexadecene, n-decylbenzene, n-decylcyclohexane, n-decylcyclopentane, and the variation of heat of combustion with chain length, J. Res. NBS, 1955, 55, 329-333. [all data]

Messerly, Todd, et al., 1990
Messerly, J.F.; Todd, S.S.; Finke, H.L.; Lee-Bechtold, S.H.; Guthrie, G.B.; Steele, W.V.; Chirico, R.D., Heat capacities of pent-1-ene (10K to 320K), cis-hex-2-ene (10K to 330K), non-1-ene (10K to 400K), and hexadec-1-ene (10K to 400K), J. Chem. Thermodynam., 1990, 22, 1107-1128. [all data]

McCullough, Finke, et al., 1957
McCullough, J.P.; Finke, H.L.; Gross, M.E.; Messerly, J.F.; Waddington, G., Low temperature calorimetric studies of seven 1-olefins: effect of orientational disorder in the solid state, J. Phys. Chem., 1957, 61, 289-301. [all data]


Notes

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