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Tetradecanenitrile

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tfus292.4KN/ADorinson and Ralston, 1944Uncertainty assigned by TRC = 0.3 K; TRC
Tfus292.4KN/AHoerr, Binkerd, et al., 1944Uncertainty assigned by TRC = 0.3 K; TRC
Tfus292.15KN/AWhitmore, Sutherland, et al., 1942Uncertainty assigned by TRC = 1. K; TRC
Tfus292.35KN/AMerckx, Verhulst, et al., 1933Uncertainty assigned by TRC = 1. K; TRC
Tfus292.2KN/AKrafft and Stauffer, 1882Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltavap85.29kJ/molN/AMajer and Svoboda, 1985 
Deltavap84.2 ± 0.2kJ/molGSEmel'yanenko, Verevkin, et al., 2005Based on data from 327. - 369. K.; AC
Deltavap85.29 ± 0.51kJ/molCStridh, Sunner, et al., 1977ALS
Deltavap85.3kJ/molN/AStridh, Sunner, et al., 1977DRB
Deltavap85.3 ± 0.5kJ/molCStridh, Sunner, et al., 1977AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
499.70.133Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
71.4406.AStephenson and Malanowski, 1987Based on data from 391. - 580. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorinson and Ralston, 1944
Dorinson, A.; Ralston, A.W., Refractive Indices of the Normal Saturated Aliphatic Nitriles. ammonia, J. Am. Chem. Soc., 1944, 66, 361. [all data]

Hoerr, Binkerd, et al., 1944
Hoerr, C.W.; Binkerd, E.F.; Pool, W.O.; Ralston, A.W., Solubilities of High-Molecular-Weight Normal Aliphatic Nitriles., J. Org. Chem., 1944, 9, 68-80. [all data]

Whitmore, Sutherland, et al., 1942
Whitmore, F.C.; Sutherland, L.H.; Cosby, J.N., Higher Hydrocarbons. I. Seven Alkyl Substituted Docosanes., J. Am. Chem. Soc., 1942, 64, 1360. [all data]

Merckx, Verhulst, et al., 1933
Merckx, R.; Verhulst, J.; Bruylants, P., Refractometric Investigations of the Normal Saturated Nitriles., Bull. Soc. Chim. Belg., 1933, 42, 177. [all data]

Krafft and Stauffer, 1882
Krafft, F.; Stauffer, B., The nitriles c(n)h(2n+2)cn of the higher fatty acids, Ber. Dtsch. Chem. Ges., 1882, 15, 1728-31. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Emel'yanenko, Verevkin, et al., 2005
Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Koutek, Bohumir; Doubsky, Jan, Vapour pressures and enthalpies of vapourization of a series of the linear aliphatic nitriles, The Journal of Chemical Thermodynamics, 2005, 37, 1, 73-81, https://doi.org/10.1016/j.jct.2004.08.004 . [all data]

Stridh, Sunner, et al., 1977
Stridh, G.; Sunner, S.; Svensson, C., Enthalpies of combustion, vaporization, and formation of some alkanenitriles, and the CH2-increment in the alkanenitrile series, J. Chem. Thermodyn., 1977, 9, 1005-1010. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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