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Tridecane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil507. ± 2.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus268. ± 1.KAVGN/AAverage of 19 out of 20 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple267.79 ± 0.01KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tc676. ± 1.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Pc16.6 ± 1.atmN/AAmbrose and Tsonopoulos, 1995 
Pc16.57atmN/ARosenthal and Teja, 1989Uncertainty assigned by TRC = 0.20 atm; TRC
Pc16.98atmN/ATeja, Lee, et al., 1989TRC
Pc17.02atmN/APak and Kay, 1972Uncertainty assigned by TRC = 0.3402 atm; corrected for vapor pressure of Hg, and extrapolated to zero to correct for decomposition; TRC
Quantity Value Units Method Reference Comment
Vc0.823l/molN/AAmbrose and Tsonopoulos, 1995 
Quantity Value Units Method Reference Comment
rhoc1.2 ± 0.1mol/lN/AAmbrose and Tsonopoulos, 1995 
rhoc1.22mol/lN/AAnselme, Gude, et al., 1990Uncertainty assigned by TRC = 0.03 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap15.88kcal/molN/AMajer and Svoboda, 1985 
Deltavap15.9kcal/molN/ARuzicka and Majer, 1994AC
Deltavap15.9 ± 0.05kcal/molCSunner and Svensson, 1979AC
Deltavap15.9 ± 0.07kcal/molCMorawetz, 1972AC
Deltavap15.8kcal/molN/AReid, 1972AC
Quantity Value Units Method Reference Comment
Deltasub21.8kcal/molBMorawetz, 1972, 2AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
15.6309.CViton, Chavret, et al., 1996AC
15.5314.CViton, Chavret, et al., 1996AC
15.3324.CViton, Chavret, et al., 1996AC
15.1334.CViton, Chavret, et al., 1996AC
14.9344.CViton, Chavret, et al., 1996AC
14.9349.CViton, Chavret, et al., 1996AC
13.0432.AStephenson and Malanowski, 1987Based on data from 417. - 511. K. See also Camin and Rossini, 1955.; AC
15.7308.CSunner and Svensson, 1979AC
15.4318.CSunner and Svensson, 1979AC
14.7348.CSunner and Svensson, 1979AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) beta Tc (K) Reference Comment
298. - 348.22.640.3468675.8Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference
412.5 - 509.214.122581689.093-98.866Camin and Rossini, 1955

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
6.91267.7DSCMondieig, Rajabalee, et al., 2004AC
6.809267.8N/ADomalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
7.180255.Domalski and Hearing, 1996CAL
25.399267.8

Enthalpy of phase transition

DeltaHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.831255.0crystaline, IIcrystaline, IFinke, Gross, et al., 1954DH
6.8119267.79crystaline, IliquidFinke, Gross, et al., 1954DH

Entropy of phase transition

DeltaStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
7.180255.0crystaline, IIcrystaline, IFinke, Gross, et al., 1954DH
25.437267.79crystaline, IliquidFinke, Gross, et al., 1954DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C., Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes, J. Chem. Eng. Data, 1995, 40, 531-546. [all data]

Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S., The Critical Properties of n-Alkanes Using a Low-Residence Time Flow Apparatus, AIChE J., 1989, 35, 1829. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Pak and Kay, 1972
Pak, S.C.; Kay, W.B., Gas-Liquid Critical Temperatures of Mixtures. Benzene + n-Alkanes and Hexafluorobenzene + n-Alkanes, Ind. Eng. Chem. Fundam., 1972, 11, 255. [all data]

Anselme, Gude, et al., 1990
Anselme, M.J.; Gude, M.; Teja, A.S., The Critical Temperatures and Densities of the n-Alkanes from Pentane to Octadecane, Fluid Phase Equilib., 1990, 57, 317-26. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ruzicka and Majer, 1994
Ruzicka, Kvetoslav; Majer, Vladimir, Simultaneous Treatment of Vapor Pressures and Related Thermal Data Between the Triple and Normal Boiling Temperatures for n-Alkanes C5--C20, J. Phys. Chem. Ref. Data, 1994, 23, 1, 1, https://doi.org/10.1063/1.555942 . [all data]

Sunner and Svensson, 1979
Sunner, Stig; Svensson, Christer, Twin calorimeter for the determination of enthalpies of vaporization of small samples from 300 to 420 K, J. Chem. Soc., Faraday Trans. 1, 1979, 75, 0, 2359, https://doi.org/10.1039/f19797502359 . [all data]

Morawetz, 1972
Morawetz, E., Enthalpies of vaporization of n-alkanes from C12 to C20, J. Chem. Thermodyn., 1972, 4, 139-144. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Morawetz, 1972, 2
Morawetz, Ernst, Correlation of sublimation enthalpies at 298.15 K with molecular structure for planar aromatic hydrocarbons, The Journal of Chemical Thermodynamics, 1972, 4, 3, 461-467, https://doi.org/10.1016/0021-9614(72)90030-4 . [all data]

Viton, Chavret, et al., 1996
Viton, C.; Chavret, M.; Jose, J., Enthalpies of vaporization of normal alkanes from nonane to pentadecane at temperatures from 298 to 359 K, ELDATA: Int. Electron. J. Phys. Chem. Data, 1996, 2, 3, 103. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Camin and Rossini, 1955
Camin, David L.; Rossini, Frederick D., Physical Properties of Fourteen API Research Hydrocarbons, C 9 to C 15, J. Phys. Chem., 1955, 59, 11, 1173-1179, https://doi.org/10.1021/j150533a014 . [all data]

Mondieig, Rajabalee, et al., 2004
Mondieig, D.; Rajabalee, F.; Metivaud, V.; Oonk, H.A.J.; Cuevas-Diarte, M.A., n -Alkane Binary Molecular Alloys, Chem. Mater., 2004, 16, 5, 786-798, https://doi.org/10.1021/cm031169p . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M., Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane, J. Am. Chem. Soc., 1954, 76, 333-341. [all data]


Notes

Go To: Top, Phase change data, References