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Butane, 1-ethoxy-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil364.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil365.4KN/AMajer and Svoboda, 1985 
Tboil365.2KN/ASpurr and Zeitlin, 1950Uncertainty assigned by TRC = 0.6 K; TRC
Tboil365.5KN/ANorris and Rigby, 1932Uncertainty assigned by TRC = 0.4 K; TRC
Tboil365.9KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.15 K; TRC
Quantity Value Units Method Reference Comment
Tc531.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap36.41kJ/molN/AMajer and Svoboda, 1985 
Deltavap36.3 ± 0.1kJ/molCMajer, Wagner, et al., 1980AC
Deltavap36.5kJ/molN/AAmbrose, Ellender, et al., 1976Based on data from 311. - 365. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
31.63365.4N/AMajer and Svoboda, 1985 
35.2326.A,EBStephenson and Malanowski, 1987Based on data from 311. - 365. K. See also Ambrose, Ellender, et al., 1976, Cidlinský and Polák, 1969, and Dykyj, 1972.; AC
36.3229.15CMajer, Wagner, et al., 1980ALS
32.1365.N/AAmbrose, Ellender, et al., 1976Based on data from 311. - 365. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
298. - 358.54.670.2952531.Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
311.33 - 364.534.062571252.485-56.685Cidlinský and Polák, 1969

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Spurr and Zeitlin, 1950
Spurr, R.A.; Zeitlin, H., The dipole moments of some aliphatic ethers, J. Am. Chem. Soc., 1950, 72, 4832. [all data]

Norris and Rigby, 1932
Norris, J.F.; Rigby, G.W., Reactivity of Atoms and Groups in Organic Compounds XII. The Preparation and Properties of Mixed Aliphatic Ethers with Special Reference to those Containing the Tert-Butyl Radical, J. Am. Chem. Soc., 1932, 54, 2088. [all data]

Timmermans, 1922
Timmermans, J., Investigation of the Freezing Point of Organic Substances VII, Bull. Soc. Chim. Belg., 1922, 31, 389. [all data]

Majer, Wagner, et al., 1980
Majer, V.; Wagner, Z.; Svoboda, V.; Cadek, V., Enthalpies of vaporization and cohesive energies for a group of aliphatic ethers, J. Chem. Thermodyn., 1980, 12, 387-391. [all data]

Ambrose, Ellender, et al., 1976
Ambrose, D.; Ellender, J.H.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers, The Journal of Chemical Thermodynamics, 1976, 8, 2, 165-178, https://doi.org/10.1016/0021-9614(76)90090-2 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Cidlinský and Polák, 1969
Cidlinský, J.; Polák, J., Saturated vapour pressures of some ethers, Collect. Czech. Chem. Commun., 1969, 34, 4, 1317-1321, https://doi.org/10.1135/cccc19691317 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]


Notes

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