Hexanedioic acid, dimethyl ester
- Formula: C8H14O4
- Molecular weight: 174.1944
- IUPAC Standard InChIKey: UDSFAEKRVUSQDD-UHFFFAOYSA-N
- CAS Registry Number: 627-93-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Adipic acid, dimethyl ester; Dimethyl adipate; Dimethyl hexanedioate; Methyl adipate; 1,6-Dimethylhexanedioate; Dimethyl ester of hexanedioic acid; Hexanedioic acid, methyl ester
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 508. | K | N/A | Corish and Davison, 1958 | Uncertainty assigned by TRC = 4. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 283.5 | K | N/A | Palomaa and Mikkila, 1942 | Uncertainty assigned by TRC = 0.6 K; TRC |
Tfus | 283.5 | K | N/A | Verkade, Hartmann, et al., 1926 | Uncertainty assigned by TRC = 1. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 16.0 ± 0.07 | kcal/mol | GS | Vasiltsova, Verevkin, et al., 2006 | Based on data from 293. to 344. K. See also Verevkin, Kozlova, et al., 2006.; AC |
ΔvapH° | 16.5 ± 0.05 | kcal/mol | GS | Verevkin, Kozlova, et al., 2006 | Based on data from 294. to 373. K.; AC |
ΔvapH° | 17.5 | kcal/mol | N/A | Vlasov, Granzhan, et al., 1963 | Based on data from 428. to 498. K. See also Verevkin, Kozlova, et al., 2006.; AC |
Reduced pressure boiling point
Tboil (K) | Pressure (atm) | Reference | Comment |
---|---|---|---|
382.7 | 0.018 | Aldrich Chemical Company Inc., 1990 | BS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
17.8 | 368. | N/A | Lee, Lai, et al., 2007 | Based on data from 353. to 443. K.; AC |
14.1 | 397. | A | Stephenson and Malanowski, 1987 | Based on data from 382. to 500. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Corish and Davison, 1958
Corish, P.J.; Davison, W.H.T.,
Infrared Spectra and Crystallinity V. Dimethyl and Diethyl Esters of α,ω-Carboxylic Acids,
J. Chem. Soc., 1958, 1958, 927-34. [all data]
Palomaa and Mikkila, 1942
Palomaa, M.H.; Mikkila, I.,
Etherlike Compounds XXVII Turbid Phases in Compounds with Reactivity Minimums,
Chem. Ber., 1942, 75B, 1659-67. [all data]
Verkade, Hartmann, et al., 1926
Verkade, P.E.; Hartmann, H.; Coops, J.,
Recl. Trav. Chim. Pays-Bas, 1926, 45, 585. [all data]
Vasiltsova, Verevkin, et al., 2006
Vasiltsova, Tatiana V.; Verevkin, Sergey P.; Bich, Eckard; Heintz, Andreas; Bogel-Lukasik, Rafal; Domanska, Urszula,
Thermodynamic Properties of Mixtures Containing Ionic Liquids. 7. Activity Coefficients of Aliphatic and Aromatic Esters and Benzylamine in 1-Methyl-3-ethylimidazolium Bis(trifluoromethylsulfonyl) Imide Using the Transpiration Method,
J. Chem. Eng. Data, 2006, 51, 1, 213-218, https://doi.org/10.1021/je050334+
. [all data]
Verevkin, Kozlova, et al., 2006
Verevkin, Sergey P.; Kozlova, Svetlana A.; Emel'yanenko, Vladimir N.; Nikitin, Eugene D.; Popov, Alexander P.; Krasnykh, Eugen L.,
Vapor Pressures, Enthalpies of Vaporization, and Critical Parameters of a Series of Linear Aliphatic Dimethyl Esters of Dicarboxylic Acids,
J. Chem. Eng. Data, 2006, 51, 5, 1896-1905, https://doi.org/10.1021/je0602418
. [all data]
Vlasov, Granzhan, et al., 1963
Vlasov, O.N.; Granzhan, V.A.; Savenko, L.M.,
Zh. Prikl. Khim., 1963, 36, 2311. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Lee, Lai, et al., 2007
Lee, Ming-Jer; Lai, Cheng-Hai; Wang, Tzu-Bing; Lin, Ho-Mu,
Vapor-Liquid Equilibrium of Mixtures Containing Adipic Acid, Glutaric Acid, Dimethyl Adipate, Dimethyl Glutarate, Methanol, and Water,
J. Chem. Eng. Data, 2007, 52, 4, 1291-1296, https://doi.org/10.1021/je700027n
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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