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Mercury, diethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.5 ± 0.1EIGowenlock, Haynes, et al., 1962RDSH
8.9PECreber and Bancroft, 1980Vertical value; LLK
8.45PEFehlner, Ulman, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H5+10.3 ± 0.1?EIGowenlock, Haynes, et al., 1962RDSH
C2H5Hg+9.7 ± 0.1C2H5EIGowenlock, Haynes, et al., 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R., Electron impact measurement on some organomercury compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]

Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K., Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds, Inorg. Chem., 1976, 15, 2544. [all data]


Notes

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