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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil386.7KN/AWeast and Grasselli, 1989BS
Tboil387.KN/AAmerican Tokyo Kasei, 1988BS
Tboil385.4KN/ABrace, 1955Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap50.8 ± 0.0kJ/molCGCVélez, Quijano, et al., 2005Based on data from 343. to 393. K.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
50.9 ± 0.1313.CUlbig, Klüppel, et al., 1996AC
48.8 ± 0.1328.CUlbig, Klüppel, et al., 1996AC
46.7 ± 0.1343.CUlbig, Klüppel, et al., 1996AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Brace, 1955
Brace, N.O., The uncatalyzed thermal addition of formaldehyde to olefins, J. Am. Chem. Soc., 1955, 77, 4666. [all data]

Vélez, Quijano, et al., 2005
Vélez, Ederley; Quijano, Jairo; Gaviria, Jair; Roux, María Victoria; Jiménez, Pilar; Temprado, Manuel; Martín-Valcárcel, Gloria; Pérez-Parajón, Juan; Notario, Rafael, Calorimetric and Computational Study of 3-Buten-1-ol and 3-Butyn-1-ol. Estimation of the Enthalpies of Formation of 1-Alkenols and 1-Alkynols, J. Phys. Chem. A, 2005, 109, 34, 7832-7838, https://doi.org/10.1021/jp051161y . [all data]

Ulbig, Klüppel, et al., 1996
Ulbig, P.; Klüppel, M.; Schulz, S., Extension of the UNIVAP group contribution method: enthalpies of vaporization of special alcohols in the temperature range from 313 to 358 K, Thermochimica Acta, 1996, 271, 9-21, https://doi.org/10.1016/0040-6031(95)02595-2 . [all data]


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