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Aniline

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid7.47 ± 0.20kcal/molCcbHatton, Hildenbrand, et al., 1962ALS
Deltafliquid7.1kcal/molCcbVriens and Hill, 1952ALS
Deltafliquid7.37kcal/molCmCole and Gilbert, 1951ALS
Deltafliquid8.0kcal/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
Deltacliquid-810.96 ± 0.24kcal/molCcbHatton, Hildenbrand, et al., 1962ALS
Deltacliquid-810.7kcal/molCcbVriens and Hill, 1952ALS
Deltacliquid-810.79kcal/molCmCole and Gilbert, 1951ALS
Deltacliquid-810.6 ± 3.0kcal/molCcbAnderson and Gilbert, 1942%hf calculated possible error by author; ALS
Deltacliquid-815.3kcal/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
liquid45.722cal/mol*KN/AHatton, Hildenbrand, et al., 1962DH
liquid45.79cal/mol*KN/AParks, Huffman, et al., 1933Extrapolation below 90 K, 45.27 J/mol*K.; DH
Quantity Value Units Method Reference Comment
Deltacsolid-810.4kcal/molCcbWillis, 1947ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
46.39298.Lesbats and Lichanot, 1987T = 200 to 300 K.; DH
45.652298.15Nichols and Wads, 1975DH
46.30298.Deshpande and Bhatagadde, 1971T = 298 to 318 K.; DH
45.901298.15Hatton, Hildenbrand, et al., 1962T = 15 to 300 K. Cp(liq, cal/mol·K) = 33.71 + 0.0409T (15 to 300 K).; DH
45.89293.Crtzen, Jost, et al., 1957DH
47.20323.Hough, Mason, et al., 1950T = 323 to 453 K.; DH
26.099267.3Ziegler and Andrews, 1942T = 40.84 K.; DH
43.91288.Radulescu and Jula, 1934DH
42.73298.15Ferguson and Miller, 1933T = 293 to 323 K. Data calculated from equation.; DH
45.631298.2Parks, Huffman, et al., 1933T = 94 to 298 K. Value is unsmoothed experimental datum.; DH
46.219298.2Lang, 1928T = 5 to 60°C.; DH
46.01298.von Reis, 1881T = 290 to 465 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hatton, Hildenbrand, et al., 1962
Hatton, W.E.; Hildenbrand, D.L.; Sinke, G.C.; Stull, D.R., Chemical thermodynamic properties of aniline, J. Chem. Eng. Data, 1962, 7, 229-231. [all data]

Vriens and Hill, 1952
Vriens, G.N.; Hill, A.G., Equilibria of several reactions of aromatic amines, Ind. Eng. Chem., 1952, 44, 2732-27. [all data]

Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C., The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond, J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]

Lemoult, 1907
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1907, 12, 395-432. [all data]

Anderson and Gilbert, 1942
Anderson, C.M.; Gilbert, E.C., The apparent energy of the N-N bond as calculated from heats of combustion, J. Am. Chem. Soc., 1942, 64, 2369-2372. [all data]

Parks, Huffman, et al., 1933
Parks, G.S.; Huffman, H.M.; Barmore, M., Thermal data on organic compounds. XI. The heat capacities, entropies and free energies of ten compounds containing oxygen or nitrogen. J. Am. Chem. Soc., 1933, 55, 2733-2740. [all data]

Willis, 1947
Willis, J.B., The heats of combustion of some organic bases and their salts. The resonance energies of acridine and phenazine, Trans. Faraday Soc., 1947, 43, 97-102. [all data]

Lesbats and Lichanot, 1987
Lesbats, C.; Lichanot, A., Capacites calorifiques de durcisseurs amines et resines epoxydes, Thermochim. Acta, 1987, 109, 317-329. [all data]

Nichols and Wads, 1975
Nichols, N.; Wads, I., Thermochemistry of solutions of biochemical model compounds. 3. Some benzene derivatives in aqueous solution, J. Chem. Thermodynam., 1975, 7, 329-336. [all data]

Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G., Heat capacities at constant volume, free volumes, and rotational freedom in some liquids, Aust. J. Chem., 1971, 24, 1817-1822. [all data]

Crtzen, Jost, et al., 1957
Crtzen, J.L.; Jost, W.; Sieg, L., Gleichgewichtsmessungen im System Anilin-N-Methylanilin, N-N-Dimethylanilin, 1,2-Äthandiol, Z. Elektrochem., 1957, 61, 230-246. [all data]

Hough, Mason, et al., 1950
Hough, E.W.; Mason, D.M.; Sage, B.H., Heat capacities of several organic liquids, J. Am. Chem. Soc., 1950, 72, 5775-5777. [all data]

Ziegler and Andrews, 1942
Ziegler, W.T.; Andrews, D.H., The heat capacity of benzene-d6, J. Am. Chem. Soc., 1942, 64, 2482-2485. [all data]

Radulescu and Jula, 1934
Radulescu, D.; Jula, O., Beiträge zur Bestimmung der Abstufung der Polarität des Aminstickstoffes in den organischen Verbindungen, Z. Phys. Chem., 1934, B26, 390-393. [all data]

Ferguson and Miller, 1933
Ferguson, A.; Miller, J.T., A method for the determination of the specific heats of liquids, and a determination of the specific heats of aniline and benzene over the approximate range 20°C to 50°C, Proc. Phys. Soc. London, 1933, 45, 194-207. [all data]

Lang, 1928
Lang, H.R., On the measurement of the variation of the specific heat of aniline with temperature, using the continuous flow electric method, Proc. Roy. Soc. (London), 1928, A118, 138-156. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

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