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Pentane, 2-chloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil368.65KN/AGoering and McCarron, 1956Uncertainty assigned by TRC = 2. K; TRC
Tboil370.01KN/AWhitmore and Karnatz, 1938Uncertainty assigned by TRC = 0.3 K; TRC
Tboil369.85KN/AHass, McBee, et al., 1935Uncertainty assigned by TRC = 0.3 K; TRC
Tboil369.75KN/ATimmermans, 1921Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tfus135.KN/AWhitmore and Karnatz, 1938Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Deltavap36.02kJ/molCTekac, Majer, et al., 1981ALS
Deltavap36.0kJ/molCTekac, Majer, et al., 1981AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
36.2304.AStephenson and Malanowski, 1987Based on data from 289. - 409. K. See also Dykyj, 1972.; AC
35.2313.CTekac, Majer, et al., 1981AC
34.4328.CTekac, Majer, et al., 1981AC
33.5358.CTekac, Majer, et al., 1981AC
31.9368.CTekac, Majer, et al., 1981AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Pentane, 2-chloro- = Pentane, 3-chloro-

By formula: C5H11Cl = C5H11Cl

Quantity Value Units Method Reference Comment
Deltar-0.544kJ/molCisoRoganov, Kabo, et al., 1969liquid phase
Deltar8.79 ± 0.84kJ/molEqkKaraseva and Andreevskii, 1968gas phase

Pentane, 2-chloro- = 1-Pentene + Hydrogen chloride

By formula: C5H11Cl = C5H10 + HCl

Quantity Value Units Method Reference Comment
Deltar73.6kJ/molEqkKaraseva and Andreevskii, 1969gas phase

Pentane, 2-chloro- = 2-Pentene, (E)- + Hydrogen chloride

By formula: C5H11Cl = C5H10 + HCl

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molEqkKaraseva and Andreevskii, 1969gas phase

Pentane, 2-chloro- = 2-Pentene, (Z)- + Hydrogen chloride

By formula: C5H11Cl = C5H10 + HCl

Quantity Value Units Method Reference Comment
Deltar65.3kJ/molEqkKaraseva and Andreevskii, 1969gas phase

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin CONTINENTAL OIL CO., PONCA CITY, OKLAHOMA, USA
NIST MS number 58842

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goering and McCarron, 1956
Goering, H.L.; McCarron, F.H., J. Am. Chem. Soc., 1956, 78, 2270-4. [all data]

Whitmore and Karnatz, 1938
Whitmore, F.C.; Karnatz, F.A., Preparation and properties of 2- and 3-chloropentanes., J. Am. Chem. Soc., 1938, 60, 2536. [all data]

Hass, McBee, et al., 1935
Hass, H.B.; McBee, E.T.; Weber, P., Ind. Eng. Chem., 1935, 27, 1190. [all data]

Timmermans, 1921
Timmermans, J., The Freezing Points of Organic Substances IV. New Exp. Determinations, Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]

Tekac, Majer, et al., 1981
Tekac, V.; Majer, V.; Svoboda, V.; Hynek, V., Enthalpies of vaporization and cohesive energies for six monochlorinated alkanes, J. Chem. Thermodyn., 1981, 13, 659-662. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Roganov, Kabo, et al., 1969
Roganov, G.N.; Kabo, G.Ya.; Adreevskii, D.N., Additivity of thermochemical properties for isomers of secondary n-alkane chlorides (C5-C10), J. Org. Chem. USSR (Engl. Transl.), 1969, 5, 2037-2041. [all data]

Karaseva and Andreevskii, 1968
Karaseva, S.Ya.; Andreevskii, D.N., Equilibrium in pentenes isomerization, Neftekhimiya, 1968, 8, 504-509. [all data]

Karaseva and Andreevskii, 1969
Karaseva, S.Ya.; Andreevskii, D.N., Equilibrium in the isomerisation of secondary monochloropentanes and the dehydrochlorination of 2-chloropentane, Russ. J. Phys. Chem. (Engl. Transl.), 1969, 43, 1236-1238. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References