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Bromotrifluoromethane anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-738. ± 19.kJ/molR-EACompton, Reinhardt, et al., 1978G2MP2 calculations indicate an EA of ca. 0.6 eV

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CF stretch 918 s Ar IR Prochaska and Andrews, 1978
Prochaska and Andrews, 1978, 2
CF stretch 914 s Ar IR Prochaska and Andrews, 1978
Prochaska and Andrews, 1978, 2
CF3 deform. 662 m Ar IR Prochaska and Andrews, 1978
Prochaska and Andrews, 1978, 2

Additional references: Jacox, 1994, page 303

Notes

mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D., Collisional ionization between alkali atoms and some methane derivatives: Electron affinities for CH3NO2, CF3I, and CF3Br, J. Chem. Phys., 1978, 68, 4360. [all data]

Prochaska and Andrews, 1978
Prochaska, F.T.; Andrews, L., Matrix photoionization studies of trifluoromethyl halide systems. Infrared spectra of the CF3+, CF2X+, and CF3X+ cations in solid argon, J. Am. Chem. Soc., 1978, 100, 7, 2102, https://doi.org/10.1021/ja00475a021 . [all data]

Prochaska and Andrews, 1978, 2
Prochaska, F.T.; Andrews, L., Matrix photoionization and radiolysis of the fluorobromomethanes. Infrared spectra and photochemistry of dibromofluoromethyl(1+), bromodifluoromethyl(1+), trifluoromethyl(1+), and the parent cations, J. Phys. Chem., 1978, 82, 15, 1731, https://doi.org/10.1021/j100504a015 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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