Dimethyl fumarate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil466.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus374.7KN/Ade Wolf and Van de Straete, 1935Uncertainty assigned by TRC = 0.6 K; TRC
Tfus375.KN/AWassermann, 1930Uncertainty assigned by TRC = 2. K; TRC
Tfus375.KN/APadoa, 1919Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
53.8376.AStephenson and Malanowski, 1987Based on data from 361. - 466. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
85. ± 2.283.VWolf and Weghofer, 1938ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
35.15375.Domalski and Hearing, 1996AC
35.150375.Wassermann, 1930, 2DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
94.375.Wassermann, 1930, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

de Wolf and Van de Straete, 1935
de Wolf, J.; Van de Straete, L., Maleonitrile and Fumaronitrole, Bull. Cl. Sci., Acad. R. Belg., 1935, 21, 216. [all data]

Wassermann, 1930
Wassermann, A., The Intermolecular Binding Stability of Fumaric and Maleic Acids and Their Dimethyl Esters, Z. Phys. Chem., Abt. A, 1930, 146, 418. [all data]

Padoa, 1919
Padoa, M., Atti Accad. Naz. Lincei, Cl. Sci. Fis., Mat. Nat., Rend., 1919, 28, 239. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Wassermann, 1930, 2
Wassermann, A., Die zwischenmolekularen Bindungsfestigkeiten der Fumar- und Maleinsäure and ihrer Dimethylester, Z. Physik. Chem., 1930, A146, 418-445. [all data]


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