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CCCN

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 27929.98 gas B-X 343 358 Hoshina and Endo, 2007


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 3 C-C stretch 869.7 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
Pi 4 trans-Bend 321.0 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
5 cis-Bend (S-) 188.6 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
5 cis-Bend (S+) 147.3 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 1844 ± 3 gas Hoshina and Endo, 2007


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 3 C-C stretch (w) 883 ± 4 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
Pi 5 cis-Bend (w) 121 ± 4 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 2303 Ar IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
1 2298 Kr IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
1 2280 Xe IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
2 2079 Ar IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
2 2076 Kr IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
2 2066 Xe IR MO Khriachtchev, Lignell, et al., 2006
Kolos, Gronowski, et al., 2008
3 C-C stretch (w) 1053 ± 3 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
Pi 4 trans-Bend (w) 404 ± 3 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006
5 cis-Bend (w) 131 ± 4 gas LF Hoshina and Endo, 2007
Khriachtchev, Lignell, et al., 2006

Additional references: Jacox, 1994, page 183; Jacox, 1998, page 247; Guelin, 1981; Gottlieb, Gottlieb, et al., 1983; Mikami, Yamamoto, et al., 1989; McCarthy, Gottlieb, et al., 1995; McCarthy, Fuchs, et al., 2003; Amano, 2010

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hoshina and Endo, 2007
Hoshina, K.; Endo, Y., Laser induced fluorescence spectroscopy of the C[sub 3]N radical, J. Chem. Phys., 2007, 127, 18, 184304, https://doi.org/10.1063/1.2783846 . [all data]

Khriachtchev, Lignell, et al., 2006
Khriachtchev, L.; Lignell, A.; Tanskanen, H.; Lundell, J.; Kiljunen, H.; Rasanen, M., Insertion of Noble Gas Atoms into Cyanoacetylene: An ab Initio and Matrix Isolation Study, J. Phys. Chem. A, 2006, 110, 42, 11876, https://doi.org/10.1021/jp063731f . [all data]

Kolos, Gronowski, et al., 2008
Kolos, R.; Gronowski, M.; Botschwina, P., Matrix isolation IR spectroscopic and ab initio studies of C[sub 3]N[sup -] and related species, J. Chem. Phys., 2008, 128, 15, 154305, https://doi.org/10.1063/1.2902289 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Guelin, 1981
Guelin, M., F. Friberg, 1981, an A. Mezaoui, Astron. Astrophys. 109, 23. [all data]

Gottlieb, Gottlieb, et al., 1983
Gottlieb, C.A.; Gottlieb, E.W.; Thaddeus, P.; Kawamura, H., Laboratory detection of the C3N an C4H free radicals, Astrophys. J., 1983, 275, 916, https://doi.org/10.1086/161585 . [all data]

Mikami, Yamamoto, et al., 1989
Mikami, H.; Yamamoto, S.; Saito, S.; Guelin, M., Astron. Astrophys., 1989, 217, L5. [all data]

McCarthy, Gottlieb, et al., 1995
McCarthy, M.C.; Gottlieb, C.A.; Thaddeus, P.; Horn, M.; Botschwina, P., Structure of the CCCN and CCCCH radicals: Isotopic substitution and ab initio theory, J. Chem. Phys., 1995, 103, 18, 7820, https://doi.org/10.1063/1.470198 . [all data]

McCarthy, Fuchs, et al., 2003
McCarthy, M.C.; Fuchs, G.W.; Kucera, J.; Winnewisser, G.; Thaddeus, P., Rotational spectra of C[sub 4]N, C[sub 6]N, and the isotopic species of C[sub 3]N, J. Chem. Phys., 2003, 118, 8, 3549, https://doi.org/10.1063/1.1534104 . [all data]

Amano, 2010
Amano, T., Submillimeter-wave spectrum of in the extended negative glow and hollow-anode discharges, J. Mol. Spectrosc., 2010, 259, 1, 16, https://doi.org/10.1016/j.jms.2009.10.004 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References