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Methyl valerate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil410. ± 40.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus182.5KN/AAdriaanse, Dekker, et al., 1964Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Tc556.7KN/ADe Heen, 1888Uncertainty assigned by TRC = 20. K; TRC
Tc566.9KN/ANadezhdin, 1887Uncertainty assigned by TRC = 20. K; TRC
Quantity Value Units Method Reference Comment
Pc31.90barN/ANadezhdin, 1887Uncertainty assigned by TRC = 2.0265 bar; TRC
Quantity Value Units Method Reference Comment
rhoc2.40mol/lN/ANadezhdin, 1887Uncertainty assigned by TRC = 0.17 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap43. ± 2.kJ/molAVGN/AAverage of 12 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
44.1 ± 0.1350. - 415.EBCamacho, Moll, et al., 2007AC
44.4296.N/ACamacho, Mariano, et al., 2006Based on data from 281. - 547. K. See also Camacho, 2006.; AC
39.2379.N/AOrtega, Espiau, et al., 2003Based on data from 364. - 417. K.; AC
41.3350.N/Avan Genderen, van Miltenburg, et al., 2002AC
42.5312.AStephenson and Malanowski, 1987Based on data from 297. - 411. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adriaanse, Dekker, et al., 1964
Adriaanse, N.; Dekker, H.; Coops, J., Some Physical Constants of Normal, Saturated Fatty Acids and Their Methyl Esters, Recl. Trav. Chim. Pays-Bas, 1964, 83, 557. [all data]

De Heen, 1888
De Heen, P., Research on Physics and Theory of Liquids, Experimental Part Paris, 1888. [all data]

Nadezhdin, 1887
Nadezhdin, A., Rep. Phys., 1887, 23, 708. [all data]

Camacho, Moll, et al., 2007
Camacho, Alberto G.; Moll, Juan M.; Canzonieri, Salvador; Postigo, Miguel A., Vapor-Liquid Equilibrium Data for the Binary Methyl Esters (Butyrate, Pentanoate, and Hexanoate) (1) + Propanenitrile (2) Systems at 93.32 kPa, J. Chem. Eng. Data, 2007, 52, 3, 871-875, https://doi.org/10.1021/je060469v . [all data]

Camacho, Mariano, et al., 2006
Camacho, Alberto G.; Mariano, Alejandra; Mussari, Lelia; Postigo, Miguel A., Vapor-Liquid Equilibrium Data for the Binary Methyl Esters (Butyrate, Pentanoate, and Hexanoate) (1) + Acetonitrile (2) Systems at 93.32 kPa, J. Chem. Eng. Data, 2006, 51, 5, 1536-1540, https://doi.org/10.1021/je060001s . [all data]

Camacho, 2006
Camacho, A.G., , Ph.D. Thesis, Universidad Nacional de Tucuman, 2006. [all data]

Ortega, Espiau, et al., 2003
Ortega, Juan; Espiau, Fernando; Tojo, José; Canosa, José; Rodríguez, Ana, Isobaric Vapor-Liquid Equilibria and Excess Properties for the Binary Systems of Methyl Esters + Heptane, J. Chem. Eng. Data, 2003, 48, 5, 1183-1190, https://doi.org/10.1021/je030117d . [all data]

van Genderen, van Miltenburg, et al., 2002
van Genderen, Aad C.G.; van Miltenburg, J. Cees; Blok, Jacobus G.; van Bommel, Mark J.; van Ekeren, Paul J.; van den Berg, Gerrit J.K.; Oonk, Harry A.J., Liquid--vapour equilibria of the methyl esters of alkanoic acids: vapour pressures as a function of temperature and standard thermodynamic function changes, Fluid Phase Equilibria, 2002, 202, 1, 109-120, https://doi.org/10.1016/S0378-3812(02)00097-3 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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