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Glycerol, 1,2-dinitrate


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Glycerol-2-nitrate + Nitric acid = Glycerol, 1,2-dinitrate + Water

By formula: C3H7NO5 + HNO3 = C3H6N2O7 + H2O

Quantity Value Units Method Reference Comment
Deltar-15. ± 3.kJ/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration

Glycerol, 1,2-dinitrate + Water = 1,2,3-Propanetriol, 1-nitrate + Nitric acid

By formula: C3H6N2O7 + H2O = C3H7NO5 + HNO3

Quantity Value Units Method Reference Comment
Deltar7. ± 3.kJ/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration

Glycerol, 1,2-dinitrate + Nitric acid = Nitroglycerin + Water

By formula: C3H6N2O7 + HNO3 = C3H5N3O9 + H2O

Quantity Value Units Method Reference Comment
Deltar-10. ± 1.kJ/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kazakov, Kirpichev, et al., 1990
Kazakov, A.I.; Kirpichev, E.P.; Lagodzinskaya, G.V.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Rubstov, Yu.I.; Manelis, G.B.; Eremenko, L.T., Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in «DELTA»H and «DELTA»S in the nitration reaction, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 1565-1570. [all data]


Notes

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