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Phenol, 3-ethyl-

Data at NIST subscription sites:

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil489. ± 10.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus269.1 ± 0.3KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tc716.45KN/AAmbrose, 1963Uncertainty assigned by TRC = 0.15 K; TRC
Quantity Value Units Method Reference Comment
Deltavap16.30 ± 0.03kcal/molVBiddiscombe, Handley, et al., 1963ALS
Deltavap16.3kcal/molN/ABiddiscombe, Handley, et al., 1963DRB

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
382.20.020Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
12.7460.A,GS,EBStephenson and Malanowski, 1987Based on data from 445. - 503. K. See also Biddiscombe, Handley, et al., 1963, 2.; AC
16.3292.A,GS,EBStephenson and Malanowski, 1987Based on data from 277. - 323. K. See also Biddiscombe, Handley, et al., 1963, 2.; AC
13.9348.N/AStage, Müller, et al., 1953Based on data from 334. - 501. K.; AC
13.5373.N/AStage, Müller, et al., 1953Based on data from 334. - 501. K.; AC
13.2398.N/AStage, Müller, et al., 1953Based on data from 334. - 501. K.; AC
12.8423.N/AStage, Müller, et al., 1953Based on data from 334. - 501. K.; AC
11.7473.N/AStage, Müller, et al., 1953Based on data from 334. - 501. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
445.22 - 502.744.158261570.423-113.901Biddiscombe, Handley, et al., 1963Coefficents calculated by NIST from author's data.
370.3 - 491.42.77645849.051-189.088von Terres, Gebert, et al., 1955Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ambrose, 1963
Ambrose, D., Critical Temperatures of Some Phenols and Other Organic Compounds, Trans. Faraday Soc., 1963, 59, 1988. [all data]

Biddiscombe, Handley, et al., 1963
Biddiscombe, D.P.; Handley, R.; Harrop, D.; Head, A.J.; Lewis, G.B.; Martin, J.F.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds. Part XIII. Preparation and physical properties of pure ethylphenols, J. Chem. Soc., 1963, 5764-5768. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Biddiscombe, Handley, et al., 1963, 2
Biddiscombe, D.P.; Handley, R.; Harrop, D.; Head, A.J.; Lewis, G.B.; Martin, J.F.; Sprake, C.H.S., 1099. Thermodynamic properties of organic oxygen compounds. Part XIII. Preparation and physical properties of pure ethylphenols, J. Chem. Soc., 1963, 5764, https://doi.org/10.1039/jr9630005764 . [all data]

Stage, Müller, et al., 1953
Stage, H.; Müller, E.; Faldix, P., Erdol u Kohle, 1953, 6, 375. [all data]

von Terres, Gebert, et al., 1955
von Terres, E.; Gebert, F.; Hulsemann, H.; Petereit, H.; Toepsch, H.; Ruppert, W., Zur Kenntnis der physikalisch-chemischen Grundlagen der Gewinnung und Zerlegung der Phenolfraktionen von Steinkohlenteer und Braunkohlenschwelteer. IV. Mitteilung Die Dampfdrucke von Phenol und Phenolderivaten, Brennst.-Chem., 1955, 36, 272-274. [all data]


Notes

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