Glycerol-2-nitrate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-135.7 ± 0.9kcal/molEqkKazakov, Kirpichev, et al., 1990Heat of nitration

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Glycerol-2-nitrate + Nitric acid = Glycerol, 1,2-dinitrate + Water

By formula: C3H7NO5 + HNO3 = C3H6N2O7 + H2O

Quantity Value Units Method Reference Comment
Δr-3.7 ± 0.7kcal/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration

Glycerin + Nitric acid = Glycerol-2-nitrate + Water

By formula: C3H8O3 + HNO3 = C3H7NO5 + H2O

Quantity Value Units Method Reference Comment
Δr-2.5 ± 0.6kcal/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kazakov, Kirpichev, et al., 1990
Kazakov, A.I.; Kirpichev, E.P.; Lagodzinskaya, G.V.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Rubstov, Yu.I.; Manelis, G.B.; Eremenko, L.T., Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in ΔH and ΔS in the nitration reaction, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 1565-1570. [all data]


Notes

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