(E) Ethyl-1-propenylsulfide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

3-Ethylthio-1-propene = (E) Ethyl-1-propenylsulfide

By formula: C5H10S = C5H10S

Quantity Value Units Method Reference Comment
Δr-11.8 ± 1.0kJ/molEqkKimmelma, 1988liquid phase; solvent: DMSO; NMR

(E) Ethyl-1-propenylsulfide = 1-Propene, 1-(ethylthio)-, (Z)-

By formula: C5H10S = C5H10S

Quantity Value Units Method Reference Comment
Δr0.0 ± 0.3kJ/molEqkVirtanen, 1986liquid phase; solvent: THF; NMR

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kimmelma, 1988
Kimmelma, R., Structure-stability relationships in vinyl sulfides. III. Stabilization caused by different alkylthio and phenylthio groups attached to an olefinic double bond, Acta Chem. Scand., 1988, 42, 550-555. [all data]

Virtanen, 1986
Virtanen, R., Structure-stability relationships in vinyl sulfides. I. On the stable conformations of vinyl sulfides, Acta Chem. Scand., 1986, 40, 313-327. [all data]


Notes

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