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Silane, triethyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen anion + Silane, triethyl- = (Hydrogen anion bullet Silane, triethyl-)

By formula: H- + C6H16Si = (H- bullet C6H16Si)

Quantity Value Units Method Reference Comment
Deltar84. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; affinity order: Et3SiH<=Et2SiH2<=nPnSiH3<=SiH4. nPnSiH3 is 0.4±0.2 kcal/mol > Et3SiH in «DELTA»G. Et3SiH dHf(77PR) is wrong.
Deltar43. ± 23.kJ/molIMRBHajdasz and Squires, 1986gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hajdasz, Ho, et al., 1994
Hajdasz, D.J.; Ho, Y.; Squires, R.R., Gas-Phase Chemistry of Pentacoordinate Silicon Hydrides, J. Am. Chem. Soc., 1994, 116, 23, 10751, https://doi.org/10.1021/ja00102a045 . [all data]

Hajdasz and Squires, 1986
Hajdasz, D.J.; Squires, R.R., Hypervalent silicon hydrides: SiH5-, J. Am. Chem. Soc., 1986, 108, 3139. [all data]


Notes

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