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Stibine, triethyl-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas49. ± 12.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid5. ± 11.kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacliquid-4864. ± 11.kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
242.25298.15Maslova, Novoselova, et al., 1973T = 60 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple153.9KN/AMaslova, Novoselova, et al., 1973, 2Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap45.6kJ/molN/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
Deltavap43.5 ± 4.2kJ/molCC-SBBamford, Levi, et al., 1946MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
47.6260.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
44.2320.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
41.4360.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K. See also Bamford, Levi, et al., 1946, 2.; AC
38.3400.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K. See also Bamford, Levi, et al., 1946, 2.; AC
39.9 ± 1.3306.N/ABaev, 2001Based on data from 193. - 333. K.; AC
41.8273. - 393.BGBamford, Levi, et al., 1946, 2AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.452153.9Maslova, Novoselova, et al., 1973DH
9.45153.9Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
61.42153.9Maslova, Novoselova, et al., 1973DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
13.0 ± 0.3EIBogolyubov, Grishin, et al., 1969RDSH
9.2 ± 0.3EIBogolyubov, Grishin, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3Sb+16.5 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
CH4Sb+17.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H4Sb+14.8 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H5Sb+12.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H6Sb+12.6 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H7Sb+12.6 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C4H10Sb+10.7 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C4H11Sb+10.0 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
SbH+18.3 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
SbH2+17.2 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
Sb+19.2 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 9605

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B., Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium, Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]

Maslova, Novoselova, et al., 1973, 2
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B., Specific Heat and Phase Changes of Triethylindium, Triethylantimony, and Trimethylgallium, Tr. Khim. Khim. Tekhnol., 1973, 1973, 51. [all data]

Fulem, Ruzicka, et al., 2006
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Simecek, T.; Hulicius, E.; Pangrác, J., Vapour pressure measurement of metal organic precursors used for MOVPE, The Journal of Chemical Thermodynamics, 2006, 38, 3, 312-322, https://doi.org/10.1016/j.jct.2005.05.018 . [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

Bamford, Levi, et al., 1946, 2
Bamford, C.H.; Levi, D.L.; Newitt, D.M., 91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V, J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. X. Mass spectra of tetraethyldistibine, diethyl diselenide, diethyl ditelluride, and the corresponding monoderivatives. Interpretation of mass-spectral intensities, Zh. Obshch. Khim., 1969, 39, 2244, In original 2190. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References