Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Stibine, triethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple153.9KN/AMaslova, Novoselova, et al., 1973Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap10.9kcal/molN/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
Deltavap10.4 ± 1.0kcal/molCC-SBBamford, Levi, et al., 1946MS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
11.4260.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
10.6320.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K.; AC
9.89360.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K. See also Bamford, Levi, et al., 1946, 2.; AC
9.15400.N/AFulem, Ruzicka, et al., 2006Based on data from 238. - 309. K. See also Bamford, Levi, et al., 1946, 2.; AC
9.54 ± 0.31306.N/ABaev, 2001Based on data from 193. - 333. K.; AC
9.99273. - 393.BGBamford, Levi, et al., 1946, 2AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.259153.9Maslova, Novoselova, et al., 1973, 2DH
2.26153.9Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
14.68153.9Maslova, Novoselova, et al., 1973, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B., Specific Heat and Phase Changes of Triethylindium, Triethylantimony, and Trimethylgallium, Tr. Khim. Khim. Tekhnol., 1973, 1973, 51. [all data]

Fulem, Ruzicka, et al., 2006
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Simecek, T.; Hulicius, E.; Pangrác, J., Vapour pressure measurement of metal organic precursors used for MOVPE, The Journal of Chemical Thermodynamics, 2006, 38, 3, 312-322, https://doi.org/10.1016/j.jct.2005.05.018 . [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

Bamford, Levi, et al., 1946, 2
Bamford, C.H.; Levi, D.L.; Newitt, D.M., 91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V, J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Maslova, Novoselova, et al., 1973, 2
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B., Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium, Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Phase change data, References