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2-Dodecanone

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil519.65KN/AClement and Selwitz, 1964Uncertainty assigned by TRC = 2. K; TRC
Tboil518.15KN/ABirch and Robinson, 1942Uncertainty assigned by TRC = 2. K; TRC
Tboil519.65KN/AKrafft, 1882Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tc702.1KN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 2.7 K; TRC
Quantity Value Units Method Reference Comment
rhoc1.33mol/lN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 0.04 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap71.83kJ/molN/AMajer and Svoboda, 1985 
Deltavap71.83 ± 0.64kJ/molCSellers, 1977ALS
Deltavap71.8 ± 0.6kJ/molCSellers, 1977AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
61.1365.AStephenson and Malanowski, 1987Based on data from 350. - 520. K. See also Stull, 1947.; AC
60.8401.AStephenson and Malanowski, 1987Based on data from 386. - 609. K. See also Ambrose, Ellender, et al., 1975.; AC
48.1524.N/AAmbrose, Ellender, et al., 1975Based on data from 386. - 609. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clement and Selwitz, 1964
Clement, W.H.; Selwitz, C.M., Improved procedures for converting higher alpha-olefins to methyl ketones with palladium chloride, J. Org. Chem., 1964, 29, 241. [all data]

Birch and Robinson, 1942
Birch, A.J.; Robinson, R., Long-chain acids containing a quaternary carbon atom: I, J. Chem. Soc., 1942, 1942, 488. [all data]

Krafft, 1882
Krafft, F., On Nineteen Higher Normal Paraffins and a Simple Volume Law for Liquids that form Drops I., Ber. Dtsch. Chem. Ges., 1882, 15, 1687-711. [all data]

Pulliam, Gude, et al., 1995
Pulliam, M.K.; Gude, M.T.; Teja, A.S., Critical Temperatures and Densities of n-Alkanones, J. Chem. Eng. Data, 1995, 40, 455-8. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Sellers, 1977
Sellers, P., Enthalpies of combustion and formation of 2-nonanone and 2-dodecanone, J. Chem. Thermodyn., 1977, 9, 139-142. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Ambrose, Ellender, et al., 1975
Ambrose, D.; Ellender, J.H.; Lees, E.B.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XXXVIII. Vapour pressures of some aliphatic ketones, The Journal of Chemical Thermodynamics, 1975, 7, 5, 453-472, https://doi.org/10.1016/0021-9614(75)90275-X . [all data]


Notes

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