Ethanamine, N-ethyl-N-methyl-
- Formula: C5H13N
- Molecular weight: 87.1634
- IUPAC Standard InChIKey: GNVRJGIVDSQCOP-UHFFFAOYSA-N
- CAS Registry Number: 616-39-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Diethylamine, N-methyl-; Diethylmethylamine; Methyldiethylamine; N-Methyldiethylamine; N,N-Diethylmethylamine; (C2H5)2(CH3)N; N-Ethyl-N-methyl-ethanamine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C5H13N+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 232.1 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 224.7 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.5 ± 0.1 | PE | Aue and Bowers, 1979 | LLK |
7.4 ± 0.1 | PE | Aue, Webb, et al., 1976 | LLK |
8.32 | PE | Utsunomiya, Kobayashi, et al., 1976 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T.,
Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements
in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]
Aue, Webb, et al., 1976
Aue, D.H.; Webb, H.M.; Bowers, M.T.,
Quantitative proton affinities, ionization potentials, and hydrogen affinities of alkylamines,
J. Am. Chem. Soc., 1976, 98, 311. [all data]
Utsunomiya, Kobayashi, et al., 1976
Utsunomiya, C.; Kobayashi, T.; Nagakura, S.,
Photoelectron spectra of electron donor-acceptor complexes between bromine and alkylamines,
Chem. Phys. Lett., 1976, 39, 245. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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